具有光栅输出镜的高功率半导体激光器输出性能模拟分析

高功率半导体激光器(LD)是广泛应用于固体激光泵浦、材料加工等方面的重要器件。数值模拟了一种自行设计的光栅输出镜结构的高功率半导体激光器的输出特性,分析了具有光栅输出镜的LD波长随温度的变化情况,以及光栅输出镜对输出功率的影响。     

Thermodynamic stability and phase behaviour of a liquid crystalline material: a theoretical model at molecular level

This article describes the thermodynamic stability and phase behaviour of a liquid crystalline material p-n-hexyloxybenzylidene-p-toluidine (6OBT) at a molecular level. The atomic net charge and dipole moment at each atomic centre have been evaluated using the complete neglect differential overlap (CNDO/2) method. The modified Rayleigh–Schrodinger perturbation method along with multicentred-multipole expansion method has been employed to evaluate the long-range intermolecular interactions, while a ‘6-exp’ potential function has been assumed for the short-range interactions. The total interaction energy values obtained through these computations have been used to calculate the probability of each configuration at room temperature (300?K), nematic–isotropic transition temperature (346.9?K) and above transition temperature (400?K) using the Maxwell–Boltzmann formula. Further, the Helmholtz free energy and entropy of each configuration has been computed during the different modes of interactions. An attempt has been made to understand the phase behaviour and stability of the molecule based on thermodynamic parameters introduced in this article.     

Application of the sequential gradient-restoration algorithm to thermal convective instability problems

The problem of the thermal stability of a horizontal incompressible fluid layer with linear and nonlinear temperature distributions is solved by using the sequential gradient-restoration algorithm developed for optimal control problems. The hydrodynamic boundary conditions for the layer include a rigid or free upper surface and a rigid lower surface. The resulting disturbing equations are solved as a Bolza problem in the calculus of variations. The results of the study are compared with the existing works in the literature.The authors acknowledge valuable discussions with Dr. A. Miele.     

大型固体激光器光束定位稳定性分析

根据 ICF驱动器系统工程的要求 ,建立光学元件运动量与靶点光束定位之间关系 ,对稳定性进行初估。运用 B类评定方法、光线追迹方法和有限元数值模拟方法进行检验和校正 ,使其更具有可行性。并从结构随机振动理论出发 ,将结构用单自由度线性系统的平稳随机振动模拟 ,实现稳定性值激励源的重分。     

On the Rayleigh-Plateau instability

In this paper,we study the surface instability of a cylindrical pore in the absence of stress. This instability is called the Rayleigh-Plateau instabilty. We consider the model developed by Spencer et ...     

界面缓蚀剂的吸附稳定性

研究表明：在一定条件下,阳极脱附电位可作为评价缓蚀剂吸附稳定性的一个经验参数：缓蚀剂吸脱附诱导的电化学振荡是缓蚀体系的一种特殊失稳状态,即缓蚀剂吸附过程与电极反应中间吸附态产物耦合的结果;卤素离子的协同作用不仅可以提高某些有机缓蚀剂的吸附复盖度,而且可以增强其吸附稳定性;微分极化曲线是研究吸附稳定性的有效方法。     

Thermal stability and crystal structure of potassium fluoride monoperoxosolvate KF·H2O2

Potassium fluoride peroxosolvate KF-H₂O₂ was obtained upon action of a 30% aqueous solution of hydrogen peroxide on solid potassium fluoride dihydrate. As compared to other peroxosolvates, KF-H₂O₂ is characterized by the highest thermal stability: the decomposition rate constantk ₁, at 120°C is 1.4 10^–3 min^–1, the enthalpy of H₂O₂ addition to KF is 8.1 kcal/ mol. The correlation between the high stability of KF-H₂O₂ and the absence of catalytic properties of KF towards H₂O₂, and the formation of strong intermolecular O-H...F and intramolecular O-H...O hydrogen bonds in the crystal is discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 38–44, January, 1993.     

Thermal stability of poly(mono-n-alkylitaconates) and mono-n-alkylitaconate-co-vinylpyrrolidone copolymers I

Poly(monoitaconates) containing octyl, decyl and dodecyl groups and random monoalkylitaconate-co-vinylpyrrolidone copolymers were studied by thermogravimetric analysis. Copolymers of mono-n-octylitaconate (MOI), mono-n-decylitaconate (MDI), and mono-n-dodecylitaconate (MDoI), respectively, with N-vinyl-2-pyrrolidone (VP) of different compositions were studied by dynamic thermogravimetric analysis. The thermal stability of the copolymers depends on the structure of the monoitaconate comonomer and on the composition of the copolymer The kinetic analysis of the degradation data shows that the thermal decomposition of these copolymers can be described by several kinetic orders depending on the copolymer and on the composition. The relative thermal stability of the copolymers increases as the VP content increases and as the length of the side chain of the itaconate increases, following the same trend as the flexibility of the copolymers in solution.