1,1‐Organoboration of bis(trimethylstannyl)ethyne with trimethylsilyl‐ and dimethylsilyl‐dialkylboryl‐substituted alkenes: organometallic‐substituted allenes

The reactions of bis(trimethylstannyl)ethyne, Me₃Sn–C?C–SnMe₃ ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by ²⁹Si and ¹¹⁹Sn NMR, and the products were characterized by an extensive NMR data set (¹H, ¹¹B, ¹³C, ²⁹Si, ¹¹⁹Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd.     

Synthesis and orientation study of a magnetically aligned liquid‐crystalline chitin/poly(acrylic acid) composite

A high magnetic field of 5 T was used to fabricate a magnetically aligned, optically anisotropic, liquid‐crystalline chitin/poly(acrylic acid) composite. The aligned mesophase was fixed by photoinitiated free‐radical polymerization. From an examination of polarized optical micrographs and an X‐ray diffraction study, a high degree of orientation of 0.70 was observed for the composite with a higher liquid‐crystalline chitin concentration (10.70 wt %); the orientation was reduced with a decreased chitin concentration at a given acrylic acid concentration. The X‐ray data for the developed composite showed a uniplanar orientation for the chitin crystallites, with its molecular long axes perpendicular to the direction of the magnetic field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 711–714, 2003     

定轴转动带电体的远区磁场分布

类比定轴转动刚体转动惯量以及电偶极子电场的计算方法，得出定轴转动带电体的磁矩及其远区磁场分布。     

A field-sensitivity analysis of the relativistic motion of a single electron submitted to a perpendicular magnetic field

Sensitivity of the velocity of a single electron, in the relativistic case, to a perpendicular magnetic field is evaluated by defining a parameter which becomes useful in a number of cases related to dynamical systems. In particular, the ultrarelativistic case is examined.     

轴线起爆式螺线管型爆磁压缩发生器理论模型

 对轴线起爆式螺线管型爆磁压缩发生器进行了理论模型研究，建立了爆炸管的一维爆轰驱动模型、螺线管内空间磁场强度分布模型、爆炸管外表面磁压力模型和发生器系统的等效电路模型等，对此类发生器的物理过程进行系统描述。在此基础上，编制了相应的零维数值模拟程序CEMG 1.0，利用该程序分别对四种不同模型参数的发生器进行了理论计算和参数优化，并对其中一模型发生器爆炸管外表面的磁压力及其引起的剩余电感进行了计算，给出了剩余电感与初始输入条件及负载电感的关系，从而得到该模型的输出性能极限。对理论模型的正确性进行了实例验算证明。     

Asymptotic Regimes of Magnetic Bianchi Cosmologies

We consider the asymptotic dynamics of the Einstein-Maxwell field equations for the class of non-tilted Bianchi cosmologies with a barotropic perfect fluid and a pure homogeneous source-free magnetic field, with emphasis on models of Bianchi type VII₀, which have not been previously studied. Using the orthonormal frame formalism and Hubble-normalized variables, we show that, as is the case for the previously studied class A magnetic Bianchi models, the magnetic Bianchi VII₀ cosmologies also exhibit an oscillatory approach to the initial singularity. However, in contrast to the other magnetic Bianchi models, we rigorously establish that typical magnetic Bianchi VII₀ cosmologies exhibit the phenomena of asymptotic self-similarity breaking and Weyl curvature dominance in the late-time regime.     

Measurement of Hartmann-Hahn cross-polarization dynamics with quenching of proton T1ρ relaxation dependence

A simple modification of the standard cross-polarization method designed for quenching the proton T_1ρ dependence when studying polarization transfer is presented. It is demonstrated that by using this simple procedure, new and subtle details of cross-polarization dynamics, previously hidden by the T_1ρ(¹H) effect, can be observed in dipolar-coupled spin systems.     

On a certain two-sided symmetric condition in magnetic field analysis and computations

A special two-sided condition for the incremental magnetic reluctivity is introduced which guarantees the unique existence of both the weak and the approximate solutions of the nonlinear stationary magnetic field distributed on a region composed of different media, as well as a certain estimate of the error between the two solutions. The condition, being discussed from the physical as well as the mathematical point of view, can be easily verified and is fulfilled for various magnetic reluctivity models used in electrotechnical practice.     

Mn-site doping induced CMR properties in calcium rich manganites Pr1‒xCaxMnO3(0.6 ≤ x ≤ 0.7)

Doping of Mn-site by chromium, cobalt and nickel has been investigated in the calcium rich manganites and . Whatever the nature of the doping element, a rapid disappearance of the charge ordered (CO) state is observed, decreasing as the doping rate increases. But the most important result concerns the Cr-doped compounds for which a re-entrant insulator to metal transition at 90-120 K is observed for x =0.10-0.12, in a zero magnetic field. The possibility to induce colossal magnetoresistance (CMR) properties for high (IV) contents ((IV)/) for x =0.07-0.12 is shown for the first time, the resistance ratios reaching at 30 K. This study also shows differently that the small size of the A-site cation (Pr, Ca) is not a redhibitory obstacle to the appearance of CMR properties in manganites, in contrast with previously established phase diagrams. Received: 18 June 1997 / Revised: 4 August 1997 / Accepted: 10 November 1997