背部支撑主反射镜的面形分析与支撑点优化

应用有限元方法对背部支撑的主反射镜进行静力学分析.分别对三点支撑和九点支撑进行计算,得到主镜反射面的变形值.以齐次坐标变换法和最小二乘法为理论依据求解反射面变形的PV/RMS值.利用有限元分析软件提供的二次开发功能,编写计算程序,在软件内部调用该程序直接获得PV/RMS值,利用该值作为优化分析的目标函数,寻求背部支撑的最佳支撑点位置.     

Raman spectroscopic study of the magnesium carbonate mineral hydromagnesite (Mg5[(CO3)4(OH)2]· 4H2O)

Magnesium minerals are important for understanding the concept of geosequestration. One method of studying the hydrated hydroxy magnesium carbonate minerals is through vibrational spectroscopy. A combination of Raman and infrared spectroscopy has been used to study the mineral hydromagnesite. An intense band is observed at 1121 cm⁻¹, attributed to the CO₃²⁻ν₁ symmetric stretching mode. A series of infrared bands at 1387, 1413 and 1474 cm⁻¹ are assigned to the CO₃²⁻ν₃ antisymmetric stretching modes. The CO₃²⁻ν₃ antisymmetric stretching vibrations are extremely weak in the Raman spectrum and are observed at 1404, 1451, 1490 and 1520 cm⁻¹. A series of Raman bands at 708, 716, 728 and 758 cm⁻¹ are assigned to the CO₃²⁻ν₂ in‐plane bending mode. The Raman spectrum in the OH stretching region is characterized by bands at 3416, 3516 and 3447 cm⁻¹. In the infrared spectrum, a broad band is found at 2940 cm⁻¹, which is assigned to water stretching vibrations. Infrared bands at 3430, 3446, 3511, 2648 and 3685 cm⁻¹ are attributed to MgOH stretching modes. Copyright © 2011 John Wiley & Sons, Ltd.     

Theoretical study on the Rocksalt structured positron annihilation in magnesium oxide

Based on the atomic superposition approximation （ATSUP） and first-principles pseudopotential plane-wave methods, the bulk and Mg mono-vacancy positron lifetime of magnesium oxide were calculated using Arponen-Pajamme and Borofiski-Nieminen positron-annihilation-rate interpolation formula respectively. The calculated values are in good agreement with experimental values and the first-principles method gives more convincing results. The positron annihilation density spectra analysis reveals that positrons mainly annihilate with valence electrons of oxygen atoms when the magnesium-vacancy appears within magnesium oxide.     

Universal fluctuations in the support of the random walk

A random walk starts from the origin of ad-dimensional lattice. The occupation numbern(x,t) equals unity if aftert steps site x has been visited by the walk, and zero otherwise. We study translationally invariant sumsM(t) of observables defined locally on the field of occupation numbers. Examples are the numberS(t) of visited sites, the areaE(t) of the (appropriately defined) surface of the set of visited sites, and, in dimension d=3, the Euler index of this surface. Ind≤ 3, theaverages - M(t) all increase linearly witht ast ® ∞. We show that in d=3, to leading order in an asymptotic expansion int, thedeviations from average ΔM(t) = M(t) -M(t) are, up to a normalization, allidentical to a single “universal” random variable. This result resembles an earlier one in dimensiond=2; we show that this universality breaks down ford>3.     

Ring opening cross-metathesis on solid support: a combinatorial library synthesis of highly functionalized cyclopentanes

Ruthenium catalyzed ring opening cross-metathesis of resin-bound bicyclic alkenes with terminal aryl olefins was utilized for the construction of a combinatorial library containing highly functionalized cyclopentane derivatives. The technology described herein represents a convergent method for the diastereospecific synthesis of unique cyclopentane molecular scaffolds useful for exploratory medicinal chemistry. This revised version was published online in August 2006 with corrections to the Cover Date.     

Reactivity of mixed organozinc and mixed organocopper reagents. Part 4: a kinetic study of group transfer selectivity in C?C coupling of mixed diorganocuprates

The competitive rate data and Taft relationships for the coupling of bromomagnesium n‐butyl (substituted phenyl) cuprates with alkyl bromides show that selective n‐butyl transfer can be explained by an oxidative addition mechanism. Taft reaction constants also show that the residual group FG‐C₆H₄ in the mixed cuprate n‐Bu(FG‐C₆H₄)CuMgBr changes the ability of the copper nucleophile to react with the electrophile RBr. These results provide support for the commonly accepted hypothesis regarding the dependence of the R¹ group transfer ability on the strength of R²? Cu bond in reactions of R¹R²CuMgBr reagents. Copyright © 2009 John Wiley & Sons, Ltd.     

一维热传导方程热源反问题基于最小二乘法的正则化方法

研究一维热传导方程热源反问题.给出基于最小二乘支持向量机（LS-SVM）求解的半解析表达式,此外还给出一种参数调节方法以及算法稳定性的证明.数值实验表明该方法具有较高的数值精度和稳定性.     

Density functional theory study on Ni-doped MgnNi (n=1-7) clusters

The possible geometrical and the electronic structures of small MgnNi(n = 1-7) clusters are optimised by the density functional theory with a LANL2DZ basis set.The binding energy,the energy gap,the electron affinity,the dissociation energy and the second difference in energy are calculated and discussed.The properties of Mg n Ni clusters are also discussed when the number of Mg atom increases.     

强脉冲激光在AZ31B镁合金中诱导冲击波的实验研究

为了研究强脉冲激光在镁合金中诱导冲击波的衰减,采用Nd:Glass脉冲激光(1054 nm,23 ns)对AZ31B变形镁合金试样表面进行冲击,并利用响应快、测量范围大的PVDF压电膜传感器以及示波器实时测量了强脉冲激光在镁合金靶中诱导激光冲击波的相对压力.根据冲击波每次在靶材背面反射时,所经过距离的不同得到激光冲击波在镁合金中的衰减规律.结果表明,在激光能量为5J的强脉冲激光作用下,镁合金中冲击波衰减的平均速度为5.83×10³ m/s,与镁合金中应力波纵波的传播速度相符;强脉冲激光诱导冲击波在镁合金中是以指数规律衰减的.试验所得分析结果对激光冲击强化镁合金的应用具有重要意义. 关键词： 激光 镁合金 压电膜传感器 衰减规律     

空间相机中主镜及其支撑方案设计与分析方法

叙述了现代空间相机对主镜的特殊要求。总结了主镜对空间相机性能具有重要影响的主要因素,即形状、材料、轻量化形式、支撑方式、微重力的影响和热尺寸稳定性等,并说明了在设计时应考虑的问题。重点论述了在对主镜进行分析时的多学科集成仿真方法、一般分析过程和迭代仿真分析策略,以及有限元法的工程分析的误差和光学元件面形评价方法。实践证明,该研究方法在空间相机设计与制造中是切实可行的。