The Crystallization and Morphology of Isotactic Polypropylene Nucleated by Magnesium Sulfate Whiskers Surface Modified by Pimelic Acid

Pimelic acid (PA) was used to modify the surface of magnesium sulfate whiskers (M-HOS). The treated M-HOS and its effects as a function of concentration on the crystallization and morphology of isotactic polypropylene (iPP) were investigated. Scanning electron microscopy (SEM), wide-angle X-ray diffraction (WAXD), thermogravimetic analysis (TGA), and Fourier transform infrared spectroscopy (FTIR) revealed that PA reacted with M-HOS and formed magnesium pimelate on the surface after the reaction. The results of differential scanning calorimetry (DSC) and polarized light microscopy (PLM) showed that the treated M-HOS had the ability to induce β-spherulites, increase the crystallization temperature and decrease the size of spherulites in iPP. It was the most effective to form β-spherulites when the content of PA treated M-HOS was 5 wt%.     

EPR and optical spectra of cupric ions doped in powder strontium maleate tetrahydrate and magnesium Bis (hydrogen maleate) hexahydrate

Abstract

EPR spectra of Cu²⁺ ions doped in a strontium maleate tetrahydrate and magnesium bis (hydrogen maleate) hexahydrate have been studied in X-band at room temperature and at liquid nitrogen temperature. Spin-Hamiltonian parameters have been calculated. Molecular orbital coefficients are obtained by correlating optical absorption data with EPR results.     

The corrosion properties of phosphate coating on AZ31 magnesium alloy: The effect of sodium dodecyl sulfate (SDS) as an eco-friendly accelerating agent

Sodium nitrite has been used as an accelerating agent in phosphating bath to improve its properties. However, it is well known that sodium nitrite is a carcinogenic component in phosphating sludge. In this study, it has been aimed to replace sodium nitrite by an environmentally friendly accelerating agent. To this end, sodium dodecyl sulfate (SDS) was used in phosphating bath to improve the phosphate coating formation on an AZ31 magnesium alloy. The effect of SDS/sodium nitrite ratio on the phosphated samples properties was also studied. Using field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), direct current (DC) polarization and electrochemical impedance spectroscopy (EIS) the properties of phosphated magnesium samples were studied.Results showed uniform phosphate coating formation on the magnesium sample mostly in hopeite phase composition. In addition, a denser and less permeable coating can be obtained at these conditions. The corrosion resistance of the phosphated samples was superiorly improved using higher SDS concentration in the phosphating bath.     

金属燃料电池

属燃料电池 (MFC)是一类特殊的燃料电池 ,具有成本低、无毒、无污染、比功率高、比能量高等优点 .文章讨论了金属燃料电池的基本特性、结构和原理 ,综述了Al、Zn、Mg、Ca、Fe和Li燃料电池的研究进展 ,总结了它们各自存在的问题和今后进一步发展的研究方向 .     

Nondestructive testing of external defects on Nanguo pear

In view of the common pests and diseases and irregularly shaped fruits of Nanguo pear, this paper fused the spectral information and image features to realize the rapid nondestructive testing and recognition of the external defects on Nanguo pear by hyperspectral imaging technology. Backpropagation neural network and support vector machine model was established to identify external defects, which are commonly used in classification and pattern recognition. The testing results show that recognition effect of support vector machine is better than backpropagation neural network. Among them, the recognition accuracy of fruits damaged by insects and rotten fruits of Nanguo pears reaches 100%. This study provides a theoretical basis for developing online grading system and quality detection of Nanguo pear based on multispectral imaging technique.     

Universal fluctuations in the support of the random walk

A random walk starts from the origin of ad-dimensional lattice. The occupation numbern(x,t) equals unity if aftert steps site x has been visited by the walk, and zero otherwise. We study translationally invariant sumsM(t) of observables defined locally on the field of occupation numbers. Examples are the numberS(t) of visited sites, the areaE(t) of the (appropriately defined) surface of the set of visited sites, and, in dimension d=3, the Euler index of this surface. Ind≤ 3, theaverages - M(t) all increase linearly witht ast ® ∞. We show that in d=3, to leading order in an asymptotic expansion int, thedeviations from average ΔM(t) = M(t) -M(t) are, up to a normalization, allidentical to a single “universal” random variable. This result resembles an earlier one in dimensiond=2; we show that this universality breaks down ford>3.     

Ring opening cross-metathesis on solid support: a combinatorial library synthesis of highly functionalized cyclopentanes

Ruthenium catalyzed ring opening cross-metathesis of resin-bound bicyclic alkenes with terminal aryl olefins was utilized for the construction of a combinatorial library containing highly functionalized cyclopentane derivatives. The technology described herein represents a convergent method for the diastereospecific synthesis of unique cyclopentane molecular scaffolds useful for exploratory medicinal chemistry. This revised version was published online in August 2006 with corrections to the Cover Date.     

还原态Mo-Ni-K/C催化剂上CO加氢合成低碳混合醇

ＣＯ加氢合成低碳混合醇已成为Ｃ１化学的一个重要分支．目前用于这一过程的催化剂大都是改性的甲醇合成、ＦＴ合成或二者组合的催化剂．自从８０年代中期美国Ｄｏｗ化学品公司和联合碳化物公司首先发现ＭｏＳ２基催化剂具有优良的催化合成醇反应性能和良好的抗硫中毒能...     

Pt-Sn/MgAl2O4催化剂的TPR和H2-TPD研究

Pt Sn/MgAl 2O 4 catalysts prepared by co impregnation with nominal 0 35% platinum and varying content of tin (0～2 5%) were characterized by temperature programmed reduction (TPR) and temperature programmed desorption of hydrogen (H 2 TPD). TPR results showed that platinum catalyzed the reduction of tin. However, the average oxidation state of tin after reduction depended upon the concentration of tin on the catalysts. H 2 TPD data indicated that tin addition inhibited the inactivated adsorption of hydrogen but promoted the activated adsorption, implying that tin modified both the ensembles of platinum and metal support interface, thus increasing hydrogen mobility and promoting hydrogen spillover.     

Ca8Mg(SiO4)4Cl2中Ce3+和Eu2+的光谱性质和能量传递

首次合成了Ｃｅ＾３＋和Ｅｕ＾２＋共激活氯硅酸镁钙Ｃａ８Ｍｇ（ＳｉＯ４）４Ｃｌ２：Ｃｅ＾３＋,Ｅｕ＾２＋高效绿色荧光粉,报道了它们的漫反射光谱、激发和发射光,观察到氯硅酸镁钙中Ｃｅ＾３＋ Ｅｕ＾２＋