Reductive Ring Opening of Ephedrine and Pseudo-Ephedrine-Derived Oxazolidinium Methiodides by Sodium Borohydride. A Direct Access to New Chiral Amine-Borane Adducts

Sodiun borohydride reacts with oxazolidinium methiodides derived from ephedrine and pseudoephedrine, in ethereal solvents, cleaving regioselectively the C-N bond of the ring and leading, in good yields, to chiral amine-borane adducts of know absolute configuration. The ¹HNMR data allow to predict the most stable conformation.     

Evolution of long-period stacking order (LPSO) in Mg97Zn1Gd2 cast alloys viewed by HAADF-STEM multi-scale electron tomography

We have studied three-dimensional (3D) structures and growth processes of 14H-type long-period stacking order (LPSO) formed in Mg₉₇Zn₁Gd₂ cast alloys by single tilt-axis electron tomography (ET) using high-angle annular dark-field scanning transmission electron microscopy. Evolution of the solute-enriched stacking faults (SFs) and the 14H LPSO by ageing were visualised in 3D with a high spatial resolution in multi-scale fields of views from a few nanometres to ~10 μm. Lateral growth of the solute-enriched SFs and the LPSO in the (0?0?0?1)_Mg plane is notable compared to the out-of-plane growth in the [0?0?0?1]_Mg direction. The 14H LPSO grows at the cost of decomposition of the (Mg, Zn)₃Gd-type precipitates, and accompany a change of in-plane edge angles from 30 to 60°. We have updated the Time–Temperature–Transformation diagram for precipitation in Mg₉₇Zn₁Gd₂ alloys: starting temperatures of both solute-enriched SFs and LPSO formation shifted to a shorter time side than those in the previous diagram.     

高中化学创新实验课程的设计与实施*

将学生所学的化学理论知识与生活实际和学科最前沿的研究热点相结合,开发并实施了 “氢氧化镁纳米材料的制备及其在处理重金属废水中的应用” 创新实验课程。该课程通过文献调研、方案设计、实验操作、结果与讨论以及论文撰写等环节,激发学生的创新潜能,系统培养学生的创新综合素质和责任意识,这有助于更好地达成化学学科核心素养。     

Development of chiral heteroleptic magnesium amides; asymmetric deprotonations mediated by six-membered metallocyclic amidomagnesium naphtholates

A series of enantioenriched six-membered metallocyclic amidomagnesium naphtholates were prepared and used to probe the structure–reactivity/selectivity relationships of heteroleptic magnesium base complexes within asymmetric deprotonation reactions. An effective complex was identified and applied within enantioselective enolisation processes, delivering good levels of enantioselectivity and also revealing key structural requirements for achieving such selectivity.     

Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate and of its Manganese Analogue

Abstract

The infrared (IR) and Raman spectra of MgHPO₄. 3H₂O and of a series of partially deuterated analogues as well as the IR spectra of MnHPO₄. 3H₂O have been recorded and interpreted. The analysis of the IR spectra in the HOD bending region rules out the possibility of existence of H₃OC⁺ ions in the structure.     

210Pb in magnesium dietary supplements

The idea behind this study was to investigate the most popular magnesium dietary supplements as a potential additional source of ²¹⁰Pb in the human diet. The paper presents the results of ²¹⁰Pb activities determined in different magnesium supplements, as well as an estimation of the annual effective radiation doses from ²¹⁰Pb decay. The results showed that the highest value of ²¹⁰Pb activity was found in a magnesium supplement of natural origin (dolomite) with a value of 2.97?±?0.18 mBq g^–1. The highest annual radiation dose from ²¹⁰Pb obtained from the magnesium daily recommended value (0.4 g of pure Mg) was calculated for dolomite tablets as 3.71?±?0.02 µSv·year^–1.     

Color centers in irradiated MgF2

Abstract

Color centers in rutile-structured MgF₂ single crystals irradiated at 20K/360K by reactor neutrons are investigated spectroscopically at LNT. Four different types of the F-F vacancy bond in MgF₂ are possibly identified to the observed absorption bands as due to the F₂ centers; instead of previous assignments, the 300nm band to the F₂(D_2h), the 325nm band to the F₂(C₁), the 355nm band to the F₂(C_2v), and the 400nm band to the F₂(C_2h) centers.