首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3854篇
  免费   508篇
  国内免费   319篇
化学   953篇
晶体学   32篇
力学   510篇
综合类   52篇
数学   967篇
物理学   2167篇
  2024年   6篇
  2023年   35篇
  2022年   102篇
  2021年   81篇
  2020年   97篇
  2019年   81篇
  2018年   96篇
  2017年   107篇
  2016年   140篇
  2015年   99篇
  2014年   216篇
  2013年   315篇
  2012年   210篇
  2011年   260篇
  2010年   168篇
  2009年   244篇
  2008年   245篇
  2007年   270篇
  2006年   233篇
  2005年   173篇
  2004年   157篇
  2003年   167篇
  2002年   126篇
  2001年   127篇
  2000年   108篇
  1999年   118篇
  1998年   139篇
  1997年   72篇
  1996年   84篇
  1995年   63篇
  1994年   63篇
  1993年   40篇
  1992年   38篇
  1991年   31篇
  1990年   20篇
  1989年   18篇
  1988年   17篇
  1987年   17篇
  1986年   16篇
  1985年   14篇
  1984年   17篇
  1983年   6篇
  1982年   14篇
  1981年   13篇
  1980年   3篇
  1979年   3篇
  1978年   3篇
  1977年   2篇
  1976年   3篇
  1936年   1篇
排序方式: 共有4681条查询结果,搜索用时 15 毫秒
61.
Lattice QCD predicts a phase transition between hadronic matter and a system of deconfined quarks and gluons (the Quark Gluon Plasma) at high energy densities. Our current understanding of this new state of matter will be discussed with two key results from the Relativistic Heavy Ion Collider (RHIC).  相似文献   
62.
In this paper, we discuss some analytic properties of hyperbolic tangent function and estimate some approximation errors of neural network operators with the hyperbolic tangent activation functionFirstly, an equation of partitions of unity for the hyperbolic tangent function is givenThen, two kinds of quasi-interpolation type neural network operators are constructed to approximate univariate and bivariate functions, respectivelyAlso, the errors of the approximation are estimated by means of the modulus of continuity of functionMoreover, for approximated functions with high order derivatives, the approximation errors of the constructed operators are estimated.  相似文献   
63.
We present a new method to investigate the two-dimensional free-boundary groundwater seepage from symmetric soil channels into a homogeneous isotropic porous medium. We use Levi–Civitá’s function to construct an integral representation for the conformal mapping of the complex potential domain onto the physical flow domain. A genetic algorithm (GA) is used to calculate the coefficients of the Maclaurin series expansion of Levi–Civitá’s function. The coordinates of the points from the channel contour, calculated by means of the integral representation, must satisfy the analytic equation of the contour. We use this condition to define the objective function of the genetic algorithm. Levi–Civitá’s function is afterwards used to calculate the seepage loss, the free lines, the streamlines, the equipotential lines, the isobars and the velocity field. Some examples illustrate the method.  相似文献   
64.

Super high modulus polyethylene fibers can be created by converting high molecular weight flexible PE chains into highly oriented and extended chain conformations. However, unlike polyethylene, aliphatic polyamides have very high cohesive energy and therefore cannot be easily drawn and highly oriented. This review addresses this fundamental problem by analyzing various novel approaches that can be used to suppress hydrogen bonding in these types of polyamides. Plasticization of such polymers with ammonia, iodine, salts, and Lewis acids, as well as dry spinning, wet spinning, and gel spinning, are discussed. Specialized techniques that involve vibrational zone drawing and annealing as well as laser heating zone drawing and annealing are also reviewed. Some of these methods definitely lead to remarkable improvements in initial modulus and other mechanical properties. The development of recombinant spider silk proteins as well progress in spinning these materials is also reported. The advantages and disadvantages of all of these processes are then summarized.  相似文献   
65.
The effect of octadecanol on dilational properties of 4,5-diheptyl-2-propylbenzene sulfonate and partly hydrolyzed polyacrylamide at the decane-water interface has been examined by means of longitudinal method. The octadecanol plays different roles in influencing the structure of adsorbed layers at different bulk concentration. A small quantity of octadecanol may enhance the dilational modulus by forming densely packed mixed-adsorption layer with surfactant molecules through hydrophobic interaction, which leads to the increase of dilational modulus. However, due to the weakening of the “entanglement” among long alkyl chains in surfactant molecules by the intercalation of octadecanol, the superfluous addition of octadecanol could decrease the dilational modulus. In the case of polymer/octadecanol system, the addition of the polymer may enhance the dilational modulus due to the slow diffusion-exchange process of the polymer.  相似文献   
66.
The inhibition effect of cetyl trimethyl ammonium bromide (CTAB) on the corrosion of mild steel in 1.0 mol L?1 hydrochloric acid (HCl) has been studied at different temperatures (25–60°C) by weight loss and potentiodynamic polarization methods. The results reveal that CTAB behaves as an effective inhibitor in 1.0 mol L?1 HCl, and the inhibition efficiency increases with the inhibitor concentration. Polarization curves show that CTAB is a mixed-type inhibitor in hydrochloric acid. The results obtained from weight loss and polarizations are in good agreement. The effect of immersion time on corrosion inhibition has also been examined and is discussed. The adsorption of inhibitor on mild steel surface obeys the Langmuir adsorption isotherm equation. Thermodynamic parameters have been obtained by adsorption theory. The inhibition effect is satisfactorily explained by the parameters.  相似文献   
67.

This work aims at presenting the viscoelastic behavior of bio‐mimetic monoglycerides used as emulsifier in a mixture made of two non‐miscible liquids, squalene and water. The measurement of the interfacial tension, carried out by the “pendant drop” method in “dynamic” mode, made it possible to characterize these amphiphilic molecules according to the value of their elastic modulus, ?, as well as their relaxation time, τR.

The analysis of these parameters, as well as those developed in the previous publication [L. Blasco et al. (2006) Skin constituents as cosmetic ingredients. Part I: A Study of bio‐mimetic monoglyceride behavior at the squalene‐water interface by the “pendant drop” method in a static mode. J. Dispers. Sci. Technol., 27(6).] shows that the hydrocarbon chain structure, such as its length, the presence of one or more unsaturations, hydroxyl function, affects the behavior of surfactant molecules at the squalene/water interface.  相似文献   
68.
69.
To systematically evaluate the quality of SiNx films in multi-stacked structures, we investigated the effects of post-deposition annealing (PDA) on the film properties of SiNx within the SiO2/SiNx/SiO2/Si stacked structure by performing X-ray photoelectron spectroscopy (XPS), X-ray reflectivity (XRR), Fourier transform infrared (FT-IR) spectroscopy, and scanning transmission electron microscope–electron energy loss spectroscopy (STEM-EELS) analyses. The XPS results showed that PDA induces the oxidation of the SiNx layer. In particular, new finding is that Si-rich SiNx in the SiNx layer is preferentially oxidized by PDA even in multi-stacked structure. The XRR results showed that the SiNx layer becomes thinner, whereas the interface layer between the SiNx layer and Si becomes thicker. It is concluded by STEM-EELS and XPS that this interface layer is SiON layer. The density of N–H and Si–H bonding within the stacked structure strongly depends on the PDA temperature. Our study helps elucidate the properties of SiNx films in stacked structures from various perspectives.  相似文献   
70.
Reflection electron energy loss spectroscopy (REELS) spectra were measured for seven insulating organic compounds (DNA, Irganox 1010, Kapton, polyethylene [PE], poly(methyl methacrylate) [PMMA], polystyrene [PS] and polytetrafluoroethylene [PTFE]). Optical constants and energy band gaps were extracted from the measured REELS spectra after elimination of multiple electron scattering via a deconvolution and fitting the normalised single scattering energy loss spectra to Drude and Drude–Lindhard model dielectric functions, constrained by the Kramers–Kronig sum and f-sum rules. Satisfactory agreement is found for those optical constants for which literature data exists. For PTFE, the observed features in the optical data correspond to its electronic structure.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号