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21.
22.
We describe the construction and operation of a variable temperature (VT) system for a high field fast magic angle spinning (MAS) probe. The probe is used in NMR investigations of biological macromolecules, where stable setting and continuous measurement of the temperature over periods of several days are required in order to prevent sample overheating and degradation. The VT system described is used at and below room temperature. A vortex tube is used to provide cooling in the temperature range of -20 to 20 degrees C, while a liquid nitrogen-cooled heat exchanger is used below -20 degrees C. Using this arrangement, the lowest temperature that is practically achievable is -140 degrees C. Measurement of the air temperature near the spinning rotor is accomplished using a fiber optic thermometer that utilizes the temperature dependence of the absorption edge of GaAs. The absorption edge of GaAs also has a magnetic field dependence that we have measured and corrected for. This dependence was calibrated at several field strengths using the well-known temperature dependence of the (1)H chemical shift difference of the protons in methanol. 相似文献
23.
The mid-infrared (1500-3800 cm−1) absorption spectrum of gaseous nitric oxide has been studied at low temperature (99 K) with a long absorption path (160 m) in order to observe weak combination, difference, and overtone bands of the NO dimer. About ten new bands were assigned with greater or lesser certainty. Combined with previous results, they lead to a set of 12 secure and 7 tentative vibrational term values for (NO)2, essentially doubling our knowledge of NO dimer vibrational states. The strongest non-fundamental bands in this region, other than the ν1 (symmetric N-O stretch) + ν5 (asymmetric N-O stretch) overtone, involve combinations of ν5 with ν3 (intermolecular stretch). Excitation of ν5 results in increased frequencies for the intermolecular modes ν2, ν3, and ν4. A new value of 155.5 cm−1 was obtained for ν4, the elusive infrared-inactive out-of-plane fundamental vibration. 相似文献
24.
S. Iijima F. Mizutani O. Niwa N. Matsumoto Y. Sunatsuki M. Kojima 《Hyperfine Interactions》2005,166(1-4):397-402
The spin-crossover behaviors of mixed-valence iron compounds [FeIIH3L][FeIIIL](NO3)2 (1) and [FeIIH3LMe][FeIIILMe](NO3)2 (2) have been investigated by 57Fe Mössbauer spectroscopy, where H3L is a hexadentate N6 tripod ligand containing three imidazole groups and H3LMe is its 2-methylimidazole derivative. Deconvolution analyses of the Mössbauer spectra revealed that a two-step SCO (LS FeII–LS FeIII→HS FeII–LS FeIII→HS FeII–HS FeIII) proceeds in each compound on elevating the temperature. Compound 2 exhibited lower spin-transition temperatures than 1. “Frozen-in effect” was observed below 120 and 50 K for 1 and 2, respectively. 相似文献
25.
L. Krupnik A. Alonso E. Ascasibar T. Estrada C. Hidalgo B. van Milligen M. Ochando M. Pedrosa J. L. de Pablos V. Tribaldos A. Chmyga N. Dreval G. Deshko S. Khrebtov A. Komarov A. Kozachok V. Tereshin L. Eliseev A. Melnikov C. Silva 《Czechoslovak Journal of Physics》2005,55(3):317-339
Radial plasma potential profiles have been obtained in the TJ-II by the Heavy Ion Beam Probing (HIBP) diagnostics. Results show that the potential increases up to 1 kV near the magnetic axis in ECRH low-density plasmas. The secondary ion current profiles, which directly reflect the plasma density, are hollow. In low-density ECRH operation, radial electric fields are found to be positive in the plasma core, however, a reduction in these fields is observed with increasing density. Radial plasma potential profiles show evidence of structures in configurations with low-order rational surfaces. In particular, HIBP measurements have permitted characterization of the plasma potential profile during e-ITB formation. Experiments in TJ-II have shown that it is possible to modify the global confinement and edge plasma parameters with limiter biasing, illustrating the direct impact of radial electric fields on confinement properties. Plasma potential measurements by the HIBP diagnostic show a strong impact of heating method (ECRH versus NBI) on radial electric fields.Presented at the Workshop Electric Fields Structures and Relaxation in Edge Plasmas, Nice, France, October 26–27, 2004. 相似文献
26.
L.?Herrera G.?Magli D.?MalafarinaEmail author 《General Relativity and Gravitation》2005,37(8):1371-1383
A new, globally regular model describing a static, non spherical gravitating object in General Relativity is presented. The model is composed by a vacuum Weyl–Levi-Civita special field – the so called gamma metric – generated by a regular static distribution of mass-energy. Standard requirements of physical reasonableness such as, energy, matching and regularity conditions are satisfied. The model is used as a toy in investigating various issues related to the directional behavior of naked singularities in static spacetimes and the black hole (Schwarzschild) limit. 相似文献
27.
A. V. Mudryi A. V. Ivanyukovich M. V. Yakushev R. Martin A. Saad 《Journal of Applied Spectroscopy》2007,74(3):415-420
The effect of a strong magnetic field (induction up to 10 T) on free and bound excitons in CuInS2 single crystals is studied. A diamagnetic shift to higher energies is observed in the luminescence and reflectance spectra
for free-exciton lines ALPB ≈ 1.5348 eV, AUPB ≈ 1.5361 eV, and BC ≈ 1.557 eV. The diamagnetic shifts of free-exciton lines ALPB, AUPB, and BC provide a basis for estimating the exciton reduced masses
= 0.131m0,
= 0.13 4m0, and μBC = 0.111m0, respectively. Bound-exciton lines in luminescence spectra are split under the influence of the magnetic field. The magnitude
of the Zeeman effect (g-factor of the magnetic splitting) is estimated.
__________
Translated from Zhurnal Prikladnoi Spektroskopii Vol. 74, No. 3, pp. 373–377, May–June, 2007. 相似文献
28.
After the nontrivial quantum parameters Ω n and quantum potentials V n obtained in our previous research, the circumstance of a real scalar wave in the bulk is studied with the similar method of Brevik and Simonsen (Gen. Rel. Grav. 33:1839, 2001). The equation of a massless scalar field is solved numerically under the boundary conditions near the inner horizon r e and the outer horizon r c . Unlike the usual wave function Ψωl in 4D, quantum number n introduces a new functions Ψωl n , whose potentials are higher and wider with bigger n. Using the tangent approximation, a full boundary value problem about the Schrödinger-like equation is solved. With a convenient replacement of the 5D continuous potential by square barrier, the reflection and transmission coefficients are obtained. If extra dimension does exist and is visible at the neighborhood of black holes, the unique wave function Ψωl n may say something to it. 相似文献
29.
《Photonics and Nanostructures》2014,12(1):2-8
In this work we describe an ultraviolet subwavelength focusing in plasmonic nanostructures. A system which provides a 20–25 times local field enhancement at a wavelength of 350 nm is proposed. This system represents a metalized V-shaped groove in a surface of a dielectric medium. Subwavelength focusing is achieved by a plasmon wave propagation along the surface of metal film and by the transfer of electromagnetic field through the dielectric medium. The influence of system parameters on a local field enhancement is investigated. A simplified model that allows for determining the geometric parameters of an optimized resonator is proposed. 相似文献
30.
In this study, both the intersubband optical absorption coefficients and the refractive index changes as dependent on the magnetic field are calculated in square and graded quantum wells. Our results show that the position and the magnitude of the linear and total absorption coefficients and refractive index changes depend on the magnetic field strength and the shape of potential. The incident optical intensity has a great effect on the total absorption and refractive index changes. 相似文献