串联质谱法快速分析皮革中五氯酚残留

建立了皮革样品中五氯酚的串联质谱分析方法,以ｍ／ｚ２６６为母离子,碰撞电压为０．８Ｖ,以子离子ｎ／ｚ２３０为定量离子,外标法定量。线性范围为０．１￣１０．０ｍｇ／Ｌ,检出限为０．００５ｍｇ／ｋｇ,回收率为８５．４％￣１０２．５％,相对标准偏差为２．５５％￣３．５５％。方法具有快速、准确的特点。     

计算机控制的轻质大型反射镜坯钻铣加工技术

轻质大型反射镜的制造是大型光学系统必须要解决的关键技术之一。采用计算机控制的钻铣法可以获得更高轻量化程度及几何精度的镜坯 ,并能得到较高的加工效率。在大量工艺设计与实验的基础上 ,现已完成了一些高精度轻质反射镜镜坯加工以及镜面抛光工作。结果表明 ,此方法可达到 70 %左右的减重率 ,并且可以加工出较高精度的反射镜。     

The Research on the Principles of Component of Magnetorheological Fluid Selecting and Its Mechanism

Because of its extensive applying prospect, magnetorheological fluid and its device have been concerned by many domain,but the lack of good magnetorheological fluid that can be used in real engineering is hindering the developing of this technology. Firstly, from the direction of the mechanism of rheologic and its performance objective, the principles of components of magnetorheological fluid selecting and their affects on fluid’s performance are studied. Secondly, the technology of disperse is researched. At last, the performance of a kind of magnetorheological fluid that made by the above principles is introduced.     

超声萃取/气相色谱-质谱联用法同时测定皮革及其制品中21种有害有机溶剂的残留量

建立了气相色谱-质谱/选择离子监测方法,对皮革及其制品中21种有害有机溶剂的残留量进行了同时测定。该方法以乙酸乙酯为萃取溶剂,45℃下超声萃取皮革及其制品中残留的有害有机溶剂,萃取液经固相萃取柱净化后进行气相色谱-质谱/选择离子监测法分析,外标法定量。结果表明,在信噪比(S/N)为10的条件下,乙二醇二丁醚(EGDBE)、三乙二醇二甲醚(TEGDME)、二乙二醇单丁醚(DEGBE)和三乙二醇单乙醚(TEGEE)的定量下限均为50μg/kg,N-甲基乙酰胺(MA)和N-甲基甲酰胺(MF)的定量下限均为150μg/kg,甲酰胺的定量下限为300μg/kg,其余14种组分的定量下限均为100μg/kg。在3个不同加标水平下,方法的平均加标回收率为82.1%~94.9%,相对标准偏差(RSD,n=9)为1.6%~4.8%。该方法简单快捷,灵敏度高,可用于皮革及其制品中有害有机溶剂残留量的测定。     

微波辅助萃取/气相色谱-串联质谱法同时测定皮革及其制品中5种限用酰胺类溶剂的残留量

建立了同时测定皮革及其制品中5种限用酰胺类溶剂残留量的气相色谱-串联质谱分析方法。以甲醇为萃取溶剂,微波萃取皮革及其制品中残留的限用酰胺类溶剂,萃取物经固相萃取柱净化后,进行气相色谱-串联质谱分析,外标法定量。在优化条件下,甲酰胺、N-甲基甲酰胺、N,N-二甲基甲酰胺、N-甲基乙酰胺、N,N-二甲基乙酰胺的定量下限(LOQ,S/N=10)分别为20,10,1,20,3μg/kg。在3个不同加标水平下,方法的平均加标回收率为81.4%~86.9%,相对标准偏差(RSD,n=9)为4.5%~8.7%。该方法简便快速,灵敏度高,定量下限远小于REACH法规的限量要求,可完全满足皮革及其制品中限用酰胺类溶剂残留量检测工作的要求。     

MCY-1A型脉冲电路实验仪的研发

阐述了MCY-1A型脉冲电路实验仪的设计原理和制作要领。     

氨基聚硅氧烷的合成

通过八甲基环四硅氧烷,Ｎ－β－氨乙基－γ－氨丙基甲基二甲氧基硅烷等原料氢化钾催化和促进剂作用下,低温开环共聚得到一系列不同氨值不同粘度的氨基聚硅氧烷,利用ＩＲ、＾１Ｈ－ＮＭＲ对其结构进行表征。对影响反应的因素进行了较详细的研究,得到较佳的合成工艺。     

MECHANICAL BEHAVIOUR OF NATURAL COW LEATHER IN TENSION

We study experimentally the microstructure and mechanical behavior of natural cow leather. Tensile tests are performed using leather strips to observe their deformation, creep and failure. It is found that the microstructure of cow leather is a layered, complicated network of fibers of different sizes from a few to a few hundreds of nanometers in diameter. They show nonlinear stress-strain relations and viscoelastic behavior. The effect of humidity is also examined. A simple theoretical model of a multilayered beam is proposed to describe the most basic behavior in tension.     

数显温控计的设计与制作

用集成电路温度传感器AD590及A／D转换器7107等器件,制作了高精度数显温控计。     

The Sensitivity of Residual Stresses of Cross-Ply Laminates to Manufacturing and Material Parameters

By using a finite-element model elaborated, the sensitivity of residual stresses of polyester/glass cross-ply laminates to manufacturing and material parameters is investigated. The development of residual stresses in the laminates and the significance of the parameters for the problem are discussed. It is found that the main attention in calculating residual stresses should be focused on the properties of resin, which must be measured with care. The most important parameters related to the resin are, of course, its stiffness, thermal expansion, and chemical shrinkage, while the properties of fibers can be obtained from material handbooks with a sufficient accuracy. In curing a thin laminate in an autoclave, the simulation of chemical reactions and the parameters needed in thermal analysis are quite insignificant, because, in practice, the autoclave temperature and the properties of the mold determine the laminate temperature history.