全文获取类型
收费全文 | 5185篇 |
免费 | 222篇 |
国内免费 | 939篇 |
专业分类
化学 | 5577篇 |
晶体学 | 114篇 |
力学 | 28篇 |
综合类 | 50篇 |
数学 | 56篇 |
物理学 | 521篇 |
出版年
2024年 | 8篇 |
2023年 | 36篇 |
2022年 | 86篇 |
2021年 | 100篇 |
2020年 | 111篇 |
2019年 | 112篇 |
2018年 | 117篇 |
2017年 | 153篇 |
2016年 | 148篇 |
2015年 | 128篇 |
2014年 | 182篇 |
2013年 | 589篇 |
2012年 | 252篇 |
2011年 | 260篇 |
2010年 | 213篇 |
2009年 | 269篇 |
2008年 | 274篇 |
2007年 | 354篇 |
2006年 | 330篇 |
2005年 | 328篇 |
2004年 | 323篇 |
2003年 | 258篇 |
2002年 | 216篇 |
2001年 | 180篇 |
2000年 | 162篇 |
1999年 | 139篇 |
1998年 | 116篇 |
1997年 | 108篇 |
1996年 | 107篇 |
1995年 | 109篇 |
1994年 | 105篇 |
1993年 | 90篇 |
1992年 | 79篇 |
1991年 | 47篇 |
1990年 | 35篇 |
1989年 | 35篇 |
1988年 | 36篇 |
1987年 | 16篇 |
1986年 | 28篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 12篇 |
1980年 | 15篇 |
1979年 | 15篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1972年 | 3篇 |
排序方式: 共有6346条查询结果,搜索用时 15 毫秒
1.
Prof. Dr. Frank Glorius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8047-8051
A general and efficient methodology for the direct transition metal free trifluoromethylthiolation of a broad range of biologically relevant N‐heteroarenes is reported employing abundant sodium chloride as the catalyst. This method is operationally simple, exhibits high functional group tolerance, and does not require protecting groups. 相似文献
2.
Yu. M. Smirnov 《Journal of Applied Spectroscopy》2006,73(6):785-791
Dissociative excitation of the lead atom in e-PbI2 collisions has been studied experimentally. 27 excitation cross sections were measured for an energy of the exciting electrons
equal to 100 eV. Nine optical excitation functions were recorded with variation of the electron energy in the range 0–100
eV. The most probable reaction channels for low electron energies are discussed, as well as the ratio of the dissociative
excitation cross sections for the lead atom in e-PbI2 and e-PbCl2 collisions.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 6, pp. 701–706, November–December, 2006. 相似文献
3.
Guido Wauters Jacques Dewaele Carlo Vandecasteele Richard Dams 《Mikrochimica acta》1989,98(4-6):157-162
Proton activation analysis was used for the determination of cadmium and lead in three sediment reference materials. The method is based on the111,112Cd(p, xn)111 In and the206,207,208Pb(p, xn)206Bi reactions.111In and206Bi were chemically separated by anion exchange. The results obtained were taken into account for the certification of the materials and are in the excellent agreement with the certified values. 相似文献
4.
H. Kaczmarek J. Kowalonek Z. Klusek S. Pierzgalski S. Datta 《Journal of Polymer Science.Polymer Physics》2004,42(4):585-602
The photooxidative degradation of blends (in a full range of compositions) of amorphous poly(vinyl chloride) (PVC) with semicrystalline poly(ethylene oxide) (PEO) in the form of thin films is investigated using absorption spectroscopy (UV–visible and Fourier transform infrared) and atomic force microscopy (AFM). The amount of insoluble gel formed as a result of photocrosslinking is estimated gravimetrically. It is found that the PVC/PEO blendsí susceptibility to photooxidative degradation differs from that pure of the components and depends on the blend composition and morphology. Photoreactions such as degradation and oxidation are accelerated whereas dehydrochlorination is retarded in blends. The photocrosslinking efficiency in PVC/PEO blends is higher than in PVC; moreover, PEO is also involved in this process. AFM images showing the lamellar structure of semicrystalline PEO in the blend lead to the conclusion that the presence of PVC does not disturb the crystallization process of PEO. The changes induced by UV irradiation allow the observation of more of the distinct PEO crystallites. This is probably caused by recrystallization of short, more mobile chains in degraded PEO or by partial removal of the less stable amorphous phase from the film surface. These results confirm previous information on the miscibility of PVC with PEO. The mechanism of the interactions between the components and the blend photodegradation are discussed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 585–602, 2004 相似文献
5.
PinHuaLI LeiWANG MinWANG JinCanYAN 《中国化学快报》2004,15(11):1295-1298
A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields. 相似文献
7.
T. Peprnicek A. Kalendova J. Simonik J.F. Gerard 《Polymer Degradation and Stability》2006,91(12):3322-3329
The paper concentrates on poly(vinyl chloride) - PVC - from the point of nanocomposite characterisation through thermal degradation of samples, evolution of the changes caused by elevating temperature using TGA, FTIR and Congo Red methods combined with morphological characterisation by XRD and TEM analyses. A novel method of PVC-paste/nanocomposite preparation while processing was used. During preparation, PVC plasticizer was mixed with clay, both natural and organophilic, and the suspension was then compounded with the other components. Two factors were followed: effect of shearing alone, and in combination with temperature. As is presented, the type of nano-filler and its chemical modifier have obvious influence on final properties either thermal or morphological. Presented contribution follows previous part of investigation and brings further information from PVC-paste/nanocomposite field. 相似文献
8.
The stannous chloride dihydrate-mediated deprotection-bicyclisation of a range of amides possessing a pendant acetal group is reported. These mild reaction conditions have been used to prepare a number of ring-fused heterocyclic compounds, some in enantiomerically pure form, which should be of interest both in their own right and as building blocks for the production of more complex target molecules. 相似文献
9.
L. Villa P. D' Agati C. Mansueto C. Pellerito M. Scopelliti T. Fiore L. Nagy L. Pellerito 《应用有机金属化学》2003,17(2):106-112
Ascidia malaca gametes before fertilization incubated in 10?5 or 10?7 M solutions of tributyltin(IV) chloride, TBTCl, for 3 h appear highly damaged under transmission electron microscopy observation. Also, the fertilization process is affected by the compound: the damaged spermatozoa are present in the vitelline coat and the egg does not cleave. An increase of microbodies, structurally similar to peroxisomes, have been detected in the egg peripheral cytoplasm, probably in relation to their role in alleviating damage to some cellular components. The results have shown that the reproduction of ascidians under unfavourable environmental conditions is prevented. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
10.
氯柱硼镁石在氯化镁水溶液中相转化平衡液相的红外光谱分析 总被引:5,自引:0,他引:5
采用差示FTIR光谱技术,研究了氯柱硼镁石在30℃下浓度为0.5,12和18%MgCl_2水溶液中溶解及相转化平衡饱和水溶液中硼氧配阴离子的FTIR光谱。给出了溶液中硼氧配阴离子的FTIR光谱振动频率的归属,515cm~(-1)为单和二硼氧配阴离子特征峰,630cm~(-1)为三硼氧配阴离子特征峰,550cm~(-1)为四硼氧配阴离子特征峰。对饱和水溶液中硼氧配阴离子的存在形式及其相互作用以及与相转化析出固相的关系进行了讨论。 相似文献