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41.
HPLC-MS/MS技术在中华绒螯蟹硝基呋喃类代谢物残留量检测中的应用 总被引:3,自引:0,他引:3
建立了中华绒螯蟹中硝基呋喃类代谢物残留量的液相色谱-串联质谱检测方法.取均质后的中华绒螯蟹可食部分样品,用盐酸水解组织中蛋白结合代谢物,经2-硝基苯甲醛37℃过夜衍生化,调节pH值至约7.0~7.4后,用乙酸乙酯提取,正己烷净化.选用电喷雾离子源,在正离子、多反应监测方式模式下进行定性,以同位素内标法进行定量.方法的检出限为0.5 μg·kg-1,工作曲线的线性范围为1.25~50.0 μg·L-1.在添加浓度为0.5~10.0 μg·kg-1的范围内,AMOZ、SEM、AHD和AOZ的回收率分别在92.8%~106%、84.5%~94.6%、80.6%~98.6%和88.4%~105%之间,相对标准偏差均小于10%. 相似文献
42.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
43.
44.
简析"静止液体内部压强公式验证"实验的设计策略 总被引:1,自引:1,他引:0
“静止液体内部压强公式验证”在现行教材中有两种实验方法。通过分析实验的设计策略,说明其作用、效果及操作上的困难,指出合理的与不合理诸因素,从而提出改进实验的方法,化难为易,提高实验教学效果。 相似文献
45.
The stationary and the time-dependent homogeneous ordered states in convection may both become unstable against localized perturbations. Defects are then created and they may contribute to the disorganization of the homogeneous state. We present an experimental study of defects in some homogeneous stationary structures as well as in the traveling-wave states of convection of a nematic liquid crystal. We show that the core of the defects is a germ of the unstable state and it can become unstable under the external stress. Then, either fully homogeneous states with the symmetry of the core, or complex disordered states can develop from the local instability of defects in processes quite similar to displacive transitions in solids. Some of the main features are qualitatively similar to numerical simulations of an appropriate Landau-Ginzburg equation. 相似文献
46.
利用有效液滴模型计算了偶偶超重核的α衰变半衰期,计算过程中采用了保持碎片体积守恒的不对称形状描述以及有效惯性系数计算Gamow势垒穿透因子.首先在质子数Z为88—98的区域检验了有效液滴模型,发现计算结果与实验符合得比较好.随后将此模型推广到Z≥100的情况,虽然只用了两个模型参数,计算结果与实验数据符合,说明有效液滴模型是计算偶偶超重核素α衰变半衰期的一个成功模型. 相似文献
47.
Tunable properties of light propagation in photonic crystal fibers filled with liquid crystals, called photonic liquid crystal
fibers (PLCFs) are presented. The propagation properties of PLCFs strongly depend on contrast between refractive indices of
the solid core (pure silica glass) and liquid crystals (LCs) filing the holes of the fiber. Due to relatively strong thermo-optical
effect, we can change the refractive index of the LC by changing its temperature. Numerical analysis of light propagation
in PLCF, based on two simulation methods, such as finite difference (FD) and multipole method (MM) is presented. The numerical
results obtained are in good agreement with our earlier experimental results presented elsewhere [1]. 相似文献
48.
G. Gargaro F. Gasparrini D. Misiti G. Palmieri M. Pierini C. Villani 《Chromatographia》1987,24(1):505-509
Summary Enantiomers of several sulfoxides and some selenoxides can be easily separated by using a new chiral stationary phase (CSP-DACH-DNB)
containing the 3,5-dinitrobenzoyl derivative of R,R-(-)1,2-diamino-cyclohexane as selector, covalently bonded to the siliceous
matrix. The easy operative conditions and the high enantioselectivity values (α) allow a direct transfer of the analytical
separations to a semi-preparative and preparative scale. 相似文献
49.
Curved Ferroelectric Liquid Crystal Matrix Displays Driven by Field-Sequential-Color and Active-Matrix Techniques 总被引:1,自引:0,他引:1
Hideo Fujikake Hiroto Sato Takeshi Murashige Yoshihide Fujisaki Taiichiro Kurita Tadahiro Furukawa Fumio Sato 《Optical Review》2006,13(1):14-19
This paper describes a curved field-sequential-color matrix display using fast-response ferroelectric liquid crystal. Black
matrix and transparent electrode patterns were formed on a thin plastic substrate by a transfer method from a glass substrate.
While a composite film of liquid crystal and micro-polymers of walls and fibers was formed between the flexible substrates
by printing, laminating and curing processes of a solution of monomers and liquid crystal, the mechanical stability was enhanced
by use of multi-functional monomers to form large display panels. The image pixels of the matrix panel were driven by an active
matrix scheme using an external switch transistor array at a frequency of 180 Hz for intermittent three-primary-color backlight
illumination. The flexible A4-paper-sized color display with 24 × 16 pixels and 60 Hz field frequency was demonstrated by
illuminating it with sequential three-primary-color lights from light-emitting diodes of the backlight. Our display system
is useful in various information displays because of its freedom of setting and location. 相似文献
50.