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11.
Tsutomu KumagaiMasaaki Tomura Jun-ichi NishidaYoshiro Yamashita 《Tetrahedron letters》2003,44(36):6845-6848
1,3-Dithiol-2-ylidene derivatives containing bis(ethynylpyridine) units were synthesized using a Pd-catalyzed reaction of the corresponding dibromide. X-Ray crystal analysis revealed unique crystal structures depending on the aromatic groups. The absorption spectra and redox properties indicated intramolecular charge-transfer interactions between the 1,3-dithiole unit and the pyridyl parts. 相似文献
12.
Mrio J. Edmundo 《Mathematical Logic Quarterly》2005,51(6):639-641
We show that if G is a definably compact, definably connected definable group defined in an arbitrary o‐minimal structure, then G is divisible. Furthermore, if G is defined in an o‐minimal expansion of a field, k ∈ ? and pk : G → G is the definable map given by pk (x ) = xk for all x ∈ G , then we have |(pk )–1(x )| ≥ kr for all x ∈ G , where r > 0 is the maximal dimension of abelian definable subgroups of G . (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
13.
Kazuaki Okamoto Suprakas Sinha Ray Masami Okamoto 《Journal of polymer science. Part A, Polymer chemistry》2003,41(24):3160-3172
A series of new poly(butylene succinate) (PBS)/layered silicate nanocomposites were prepared successfully by simple melt extrusion of PBS and organically modified layered silicates (OMLS). Three different types of OMLS were used for the preparation of nanocomposites: two functionalized ammonium salts modified montmorillonite and a phosphonium salt modified saponite. The structure of the nanocomposites in the nanometer scale was characterized with wide-angle X-ray diffraction and transmission electron microscopic observations. With three different types of layered silicates modified with three different types of surfactants, the effect of OMLS in nanocomposites was investigated by focusing on four major aspects: structural analysis, materials properties, melt rheological behavior, and biodegradability. Interestingly, all these nanocomposites exhibited concurrent improvements of material properties when compared with pure PBS. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 3160–3172, 2003 相似文献
14.
Jaedong Cho John Blackwell Sergei N. Chvalun Morton Litt Yuan Wang 《Journal of Polymer Science.Polymer Physics》2004,42(13):2576-2585
As‐cast films of poly(2,5‐benzimidazole) exhibit uniplanar orientation in which the planes of the aromatic rings lie parallel to the film surface. Upon doping with phosphoric acid, the original crystalline order is lost, but the doped film can be stretched to produce films with uniaxial orientation. After thermal annealing at 540 °C, nine Bragg reflections are resolved in the fiber diagram, and these are indexed by an orthorhombic unit cell with the dimensions a = 18.1 Å, b = 3.5 Å, and c = 11.4 Å, containing four monomer units of two chains. The absence of odd‐order 00l reflections points to a 21 chain conformation, which is probably planar so that the aromatic units can be stacked along the b axis. The water and phosphoric acid contents of the crystalline structure cannot be determined exactly because of the presence of extensive amorphous regions that probably have different solvation. The best agreement between the observed and calculated intensities is for an idealized structure containing two phosphoric acids and two water molecules per unit cell. However, the phosphoric acid is probably present mainly in the form of pyrophosphoric acid and its higher oligomers. In addition, the X‐ray data are consistent with a more disordered structure containing chains with random (up and down) polarity and a lack of c‐axis registry. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2576–2585, 2004 相似文献
15.
S. Aravinda N. Shamala Rituparna S. Roy P Balaram 《Journal of Chemical Sciences》2003,115(5-6):373-400
An overview of the use of non-protein amino acids in the design of conformationally well-defined peptides, based on work from
the author’s laboratory, is discussed. The crystal structures of several designed oligopeptides illustrate the useα-aminoisobutyric acid (Aib) in the construction of helices, D-amino acids in the design of helix termination segments andDPro-Xxx segments for nucleating ofβ-hairpin structures.β- andγ-amino acid residues have been used to expand the range of designed polypeptide structures.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献
16.
17.
B. Amaziane M. Goncharenko L. Pankratov 《Mathematical Methods in the Applied Sciences》2005,28(15):1847-1865
We study the asymptotic behaviour of the solution of a stationary quasilinear elliptic problem posed in a domain Ω(ε) of asymptotically degenerating measure, i.e. meas Ω(ε) → 0 as ε → 0, where ε is the parameter that characterizes the scale of the microstructure. We obtain the convergence of the solution and the homogenized model of the problem is constructed using the notion of convergence in domains of degenerating measure. Proofs are given using the method of local characteristics of the medium Ω(ε) associated with our problem in a variational form. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
18.
Changes in thin zinc-sulfide films under the action of the γ-radiation of Co60 are studied by investigating electroluminescence spectra of terbium embedded in these films as a luminescent probe. It is
shown that changes in the relation of the intensities of bands, a decrease in their halfwidth and the background component,
and simplification of the spectrum are observed in a short-wave region of the Tb radiation spectrum that corresponds to5D3→7Fj transitions. The same modification of the radiation spectrum is characteristic of ZnS films whose crystalline structure is
ordered in the course of thermal annealing at a temperature of 350°C. Based on the analysis of the data obtained it is inferred
that irradiating the ZnS films with small radiation doses of 104–105 rad leads to the ordering of their crystalline structure due to the elimination of one of the types of structural defects.
Institute of Physics of Semiconductors, National Academy of Sciences of Ukraine, 45, Nauka Ave., Kiev-28, 252650. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 3, pp. 338–341, May–June, 1997. 相似文献
19.
Houman Borouchaki Abdelhakim Cherouat Patrick Laug Khemais Saanouni 《Comptes Rendus Mecanique》2002,330(10):709-716
The analysis of mechanical structures using the Finite Element Method in the framework of large elastoplastic strain, needs frequent remeshing of the deformed domain during computation. Indeed, the remeshing is due to the large geometrical distortion of finite elements and the adaptation to the physical behavior of the solution. This paper gives the necessary steps to remesh a mechanical structure during large elastoplastic deformations with damage. An important part of this process is constituted by geometrical and physical error estimates. The proposed method is integrated in a computational environment using the ABAQUS/Explicit solver and the BL2D-V2 adaptive mesher. To cite this article: H. Borouchaki et al., C. R. Mecanique 330 (2002) 709–716. 相似文献
20.
R. Gerbaldo G. Ghigo G. Giunchi L. Gozzelino F. Laviano E. Mezzetti 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):297-300
We present results from an extended magneto-optical (MO) analysis of two samples cut from high-density pellets of MgB2. The first sample was studied in order to show that no matter how large the sample is and despite the bulk granularity, the
material enters into a critical state in a crystal-like fashion. The second sample was chosen for the quantitative analysis.
A numerical approach based on an inverted 2D Biot-Savart model was used to calculate the current paths across the homogeneous
polycrystalline bulk, as well as in the vicinity and across some morphological defects. Local current densities in the homogeneous
part were estimated as a function of the applied magnetic field at different temperatures, in three regimes: below full penetration,
at full penetration and above full penetration, respectively. A hypothesis of interpretation of the apparent absence of magnetic
granularity inside the polycrystalline microstructure is presented. It is related to a critical state likely reached by a
network of strongly coupled Josephson junctions.
Received 31 May 2001 and Received in final form 5 December 2001 相似文献