层状有机膦酸铜配合物Cu(O3PC6H4COOH)

本文报道了一个新的有机膦酸铜化合物:Cu(O3PC6H4COOH)(1).该化合物具有新型层状结构,由扭曲平面结构的{CuO4}共边形成的二核单元通过{CPO3}四面体连接起来,形成一个含有4-,8-,和14-元环的无机层.苯甲酸基团通过中等强度的氢键连接起来.并填充在层与层之间.磁性表征显示铜离子之间存在反铁磁性相互作用.化合物1的晶体属单斜晶系,C2/c空间群.     

SHPB冲击作用下层状千枚岩多尺度破坏机理研究

通过分离式霍普金森杆对层状千枚岩施加动态载荷,得到不同层理倾角下层状千枚岩的动态抗压强度与宏观破坏模式。采用三维激光仪获得断裂面细观形貌,引入分形几何定量计算断口面粗糙度;结合SEM观察到的微观尺度下不同层理倾角断口破坏机理,分析了不同层理倾角下层状岩石的动态破坏机制。研究结果表明:动态压缩下层理弱面对岩石的抗压强度影响较大;不同层理倾角千枚岩的断口形貌分形维数随层理倾角增大呈U型变化;从强度与裂纹扩展两方面考虑层理弱面对层状岩石破坏特征的影响,对于层理倾角为0°的试样,强度由岩石基质控制,但层理弱面仍对岩石破坏的裂纹分布与走向产生较大影响;对于层理倾角为22.5°的试样,强度与裂纹走向受岩石基质与层理弱面共同控制;对于层理倾角为45°~67.5°的试样,强度与裂纹走向受层理弱面控制;而对于层理倾角为90°的试样,动态抗压强度受岩石基质的影响较大,在层理弱面较早形成纵向宏观裂纹,导致该层理弱面角度下裂纹受层理弱面的影响较大。     

柱状分层固体媒质的声散射

本文评述了各向同性和横向各向同性柱状分层固体声散射理论和实验研究进展 ,介绍了描述圆柱状界面薄层特性的弹簧模型 ,也讨论了该领域中有待进一步研究的一些问题。     

Study on the denoising method for the electromagnetic ultrasonic echoes from multiple interfaces

The electromagnetic ultrasound is used in the detection of interfaces of the adhesive multilayer structures to solve the unstable coupling problem in ultrasonic testing by traditional piezoelectric transducers. Based on the analysis of the transforming mechanism of electromag-netic ultrasound energy and the resultant dead zone from mutual inductance of the transducer, the wavelet filtering by soft-thresholding and adaptive noise canceling methods are used simul-taneously to the detected electromagnetic ultrasonic signals to overcome the drawbacks of the low signal to noise ratio （SNR） and the wide intrinsic dead zone of the transducer. Processed results in the interface detection of a three layered adhesive sample of steel and rubber materials demonstrate that the wavelet filtering enhances the SNR about 12dB while the adaptive noise canceling narrows the dead zone effectively.     

Mg-LDH Nanoclays Intercalated Fennel and Green Tea Active Ingredient: Field and Laboratory Evaluation of Insecticidal Activities against Culex pipiens and Their Non-Target Organisms

(1) Background: Mosquito control with essential oils is a growing demand. This work evaluated the novel larvicidal and adulticidal activity of fennel and green tea oils and their Layered double hydroxides (LDHs) nanohybrid against Culex pipiens (Cx. pipiens) in both laboratory and field conditions and evaluated their effect against non-target organisms; (2) Methods: Two types of nanoclays, MgAl-LDH and NiAl-LDH were synthesized and characterized using PXRD, TEM and SEM, whereas their elemental analysis was accomplished by SEM-EDX; (3) Results: Mg and Ni LDHs were synthesized by the co-precipitation method. The adsorption and desorption of active ingredients were conducted using LC MS/MS, with reference to the SEM-EXD analysis. The desorption process of MgAl-LDH intercalated green tea oil was conducted using ethanol, and reveled significant peaks related to polyphenols and flavonoids like Vanillin, Catechin, Daidzein, Ellagic acid, Naringenin, Myricetin and Syringic acid with concentrations of 0.76, 0.73, 0.67, 0.59, 0.52, 0.44 and 0.42 μg/g, respectively. The larvicidal LC₅₀ values of fennel oil, Mg-LDH-F, and Ni-LDH-F were 843.88, 451.95, 550.12 ppm, respectively, whereas the corresponding values of green tea were 938.93, 530.46, and 769.94 ppm. The larval reduction percentage of fennel oil and Mg-LDH-F reached 90.1 and 96.2%, 24 h PT and their persistence reached five and seven days PT, respectively. The reduction percentage of green tea oil and Mg-LDH-GT reached 88.00 and 92.01%, 24 h PT and their persistence reached five and six days PT, respectively. Against adults, Mg-LDH-GT and Ni-LDH-GT were less effective than green tea oil as their LC₉₅ values were 5.45, 25.90, and 35.39%, respectively. The reduction in adult density PT with fennel oil, Mg-LDH-F, green tea oil, and Mg-LDH-GT reached 83.1, 100, 77.0, and 99.0%, respectively, 24 h PT and were effective for three days. Mg-LDH-GT and Mg-LDH-F increased the predation Cybister tripunctatus (71% and 69%), respectively; (4) Conclusions: For the first time, Mg-LDH-GT and Mg-LDH-F was the best system loaded with relatively good desorption release to its active ingredients and significantly affected Cx. pipiens larvae and adults in both laboratory and field circumstances, and it could be included in mosquito control.     

XNBR/LDH nanocomposites: Effect of vulcanization and organic modifier on nanofiller dispersion and strain‐induced crystallization

In elastomer/organo clay nanocomposites, the morphological characteristics, and hence the mechanical properties, of the vulcanizates are strongly influenced by the organic modifier and the vulcanization process. When the elastomer itself undergoes strain‐induced crystallization, both the organic modifier and the dispersed filler particles could significantly influence the crystallization process. These phenomena are very common in case of natural rubber‐based vulcanizates. In this study, the similar effects have been demonstrated with carboxylated nitrile rubber (XNBR) and organically modified layered double hydroxide (O‐LDH)‐based nanocomposites. The effect of size of the organic modifier was obviously visible on the interlayer distance of O‐LDH and also on the morphological reorganization of the dispersed O‐LDH particles during vulcanization process. The strain‐induced crystallization of the XNBR was found to be strongly dependent on the morphological change that occurs during vulcanization process. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010     

Trivalent Cation Substitution Effect into Layered Double Hydroxides Co2Fey Al1−y(OH)6Cl·nH2O: Study of the Local Order: Ionic Conductivity and Magnetic Properties

A series of layered double hydroxide materials of composition Co₂Fe_yAl_1−y(OH)₆Cl·nH₂O (0≤y≤1) was prepared via chimie douce. The crystalline parameter related to the cation to cation distance obeys the expected variation, showing that the substitution is effective over the entire range. Local order around Co and Fe cations is studied by X-ray absorption spectroscopy. Moduli of the Fourier transform at the Fe K-edge are superimposable, in agreement with an ordered model, although present in small domains since no superlattice is depicted. The ionic resistivity of the samples is highly dependent on the water molecule content. The conductivity is found to be thermally assisted, and the variation of the slope in the Arrhenius diagram is explained by a Vogel-Tamman-Fulcher-type behavior. Magnetic susceptibility measurements support the proposed cation composition and indicate the onset of local magnetic order at low temperature (below 10 K). The inter-sheet distance influences the magnetic response at low temperature, showing the presence of weak interactions between lamellae.     

Continual approximations of displacements in thick layered plates upon decomposition of thermomechanical loads into bilateral symmetric and antisymmetric components

Continual models of deformation of thick layered plates, where the general order of resolving equations does not depend on the number of layers, are constructed with account of the specific character of the unflexural and flexural deformation caused by the symmetric and antisymmetric components of bilateral loads and temperature. Account of the load decomposition during the process of refining a certain reasonable initial solution, consisting in the analytical iterative integration, makes it possible to obtain rather precise continual approximations of stresses and displacements over the transverse coordinate and thus to revise the known continual models.Ukrainian State Academy of Water Management, Rovno, the Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 6, pp. 743–756, November–December, 1999.     

THE EFFECT OF BILINEAR BEHAVIOUR ON THE DIRECTION AND MAGNITUDE OF THE PEELING MOMENT IN A BI-MATERIAL BEAM

In this work a bi-material beam exhibiting partly bilinear behaviour under a uniform temperature change is analyzed. The essence of solution is based on the approach of Timoshenko’s mechanics of materials. The main aim of the present analysis is to understand the effect of the bilinear behaviour on the peeling moment. This theoretical mechanics model mentioned here can give us useful insights to improve the resistance against the delamination.