An improved method for the large-scale preparation of 4,6-dihydroxyisophthalic acid and 2,3-dihydroxyterephthalic acid has been developed.Compared to the previous procedures,this new process-requires much lower CO2 pressure of 0.3 Mpa and shorter reaction time.thus providing a convenient access for large-scale synthesis.The yield is high (93% and 65%,respectively), and the oxidation of phenol is nearly inhibited,neither decolorization nor further chromatographic purification is required. 相似文献
In this paper, we discuss the decision optimization of tourism projects in Hebei Province, China. To improve the process of analyzing tourism projects, we introduce a model that includes multiple decision makers as subjects based on a standard four-dimensional evaluation system. In order to improve the effectiveness of decision-making results, we will increase the number of decision makers to 40. A novel large-scale group decision-making (LSGDM) algorithm that incorporates the trust–distrust asymmetric relationships between decision makers is proposed. This model contains three main innovations: firstly, in the evaluation of decision makers’ social network relations, the trust–distrust value is introduced as a new carrier, and a weighted directed network and data integration operator are constructed based on the evaluation between decision makers; secondly, an extended Girvan-Newman (GN) algorithm is constructed to cluster the decision makers from this weighted network; thirdly, the interval-valued intuitionistic fuzzy number (IVIFN) is used to evaluate the alternatives, studying the IVIFN’s geometric significance by placing in a rectangular coordinate system. Finally, a new LSGDM model is proposed. Using the development of a cultural tourism project in a township as an example, the effectiveness of the proposed model is illustrated. By comparing the results of our method to those of a LSGDM algorithm that does not incorporate trust relationships, we assess the performance of the new model. 相似文献
In this article we investigate turbulent flow of air through compound rectangular channels to experimentally investigate the turbulence phenomena in compound channels. Detailed experimental data of axial mean velocity, wall shear stresses, five of six Reynolds stresses, auto- and cross-spectral densities, and two-point space correlations were measured by hot-wire anemometry in 18 geometrical configurations.
The symmetry of the present flow appears to be better than that of previous measurements and the range of measurments is more extensive. The most interesting result is the existence of a quasi-periodic large-scale turbulence structure in most of the geometries investigated. This structure is stationary and independent of the axial position in the channel. It exists in any longitudinal slot or groove in a wall or a connecting gap between two flow channels, provided its depth is more than approximately twice its width. The frequency of this flow oscillation is determined by the geometry of the slot and is linearly dependent on the bulk velocity. 相似文献