计算氢同位素水分子汽化焓的比较法

本文首次提出计算氢同位素水分子汽化焓的比较法,得到0～374℃时H2O,D2O,DTO和T2O的汽化焓,并提出用D2从含氚重水中分离出DT气的适宜温度.     

Submillimeter-wave spectrum of carbonyl sulfide: rare isotopic species

Rotational spectra of four rare isotopic species of OCS were observed in the 110-690 GHz region with a source-modulated submillimeter-wave spectrometer. Spectral lines of ¹⁸O¹³CS, O¹³C³⁶S, ¹⁸OC³⁶S, and ¹⁸O¹³C³⁴S were measured in their natural abundances, 21.4, 1.51, 0.29, and 0.95 ppm, respectively. The rotational constants and centrifugal distortion constants were precisely determined from observed line frequencies by least squares methods. In order to facilitate sensitivity examination in the submillimeter-wave region, transition frequencies and peak absorption coefficients were calculated and tabulated for the spectral lines of the four species up to the 1000 GHz region.     

Superposition of special non-abelian potentials

The superposition of the non-abelian potentials of the formA′^μ=Aα^μ+aβ ^μ andB′^μ=Bγ^μ+bη^μ are considered and the necessary as well as the sufficient conditions are obtained. The significance of the conditions is discussed and the constrained isotopic spins of the perturbation potentials (aβ ^μ,bη^μ) are shown to be necessary for the superposition of these potenitals. Work under the projecthcs/dst/1081/81     

Normal co-ordinates through coriolis coupling constants

Normal co-ordinates, force fields and isotopic frequencies have been calculated for someXY ₃ andXY ₄-type molecules using coriolis coupling constants.     

Ne原子与H2分子碰撞的同位素替代效应研究

使用密耦近似（Close-Coupling）方法、采用Tang-Toennies势模型计算了惰性气体原子Ne与H₂分子及同位素D₂分子在碰撞能量为83.8 meV时的微分散射截面及分波截面, 并与实验值和文献值进行比较.计算得到的微分散射截面值与实验值符合得较好,分波截面值与文献值也相符合.使用同样的方法和模型,文中对Ne-H₂(D₂,T₂)三个体系的微分截面和分波截面进行了系统计算和比较分析,得出对称同位素替代碰撞体系的散射截面规律.     

Primary result of ^236U measurement with accelerator mass spectrometry at CIAE

The rare isotope ^236U has a half-life of 2.342（3）×107 years, and is produced principally by thermal neutron capture on ^235U. The isotopic atom ratio of ^236U/^238U depends on the integral thermal neutron flux received by the material of interest. ^236U is potentially useful as a ＂fingerprint＂ for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity. By extracting negative molecular ion UO^- from the uranium oxide target, simulating the ^236U^16O^- beam transport with ^238U^16O^- and ^208Pb2^16O^- pilot molecular ion beam, transporting the ^236U-containing ion beam with a high resolution injection magnet analyzer and electrostatic analyzer system, and finally identifying and detecting ^236U with a time-of-flight detector （TOF）, a method for AMS （Accelerator Mass Spectrometry） measurement of ^236U was established on the HI-13 Accelerator AMS system at China Institute of Atomic Energy.     

Primary result of ~(236)U measurement with accelerator mass spectrometry at CIAE

The rare isotope 236U has a half-life of 2.342(3)×107 years,and is produced principally by thermal neutron capture on 235U.The isotopic atom ratio of 236U/238U depends on the integral thermal neutron flux received by the material of interest.236U is potentially useful as a fingerprint for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity.By extracting negative molecular ion UO- from the uranium oxide target,simulating the 236U16O- beam transport with 238U16O- an...     

Fractionation of Oxygen and Hydrogen Isotopes at the Hydrate Gas forming in the Sea Sediments

The paper gives data on isotope composition of interstitial and near-bottom waters sampled in a region of gas-hydrate formation in the Sea of Okhotsk. The studies shows that heavy isotope of oxygen and hydrogen is used in gas-hydrate formation, with the result that isotope composition of its constitution water constitutes δ¹⁸O = +1.99‰, δD = +23‰ relatively to SMOW. Formation of autogenic carbonates leads to isotope exchange with interstitial water wich, in turn, changes its primary isotope composition in the direction of increasing of O-18 content. The near-bottom waters are isotope-light relatively to the SMOW standard and to the mean isotope composition of interstitial water in the studied region of gas-hydrate spreading.     

Radiophotosynthesis of some 14C-labelled Amino Acids using the Unicellular Green Alga Scenedesmus acutus

Radiophotosynthesis has been carried out using the unicellular green algea Scenedesmus acutus grown, as a substrate for preparing some carbon-14 labelled amino acids. Gaseous ¹⁴CO₂, in an air tight photosynthesis chamber or NaH¹⁴CO₃ solution, in an ordinary photosynthesis chamber, were used as radioactive carbon sources. The yields, radiochemical yields and specific activities of the formed radioactive products are reported in both cases. The results obtained clearly showed the advantages of using the NaH¹⁴CO₃ method. In that case the process was by far less tedious. Moreover, the chemical and radiochemical yields of the formed amino acids were relatively much more higher than the values obtained on using ¹⁴CO₂ in the tight photosynthesis chamber.