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481.
同分异构体的同时测定一直是分析化学领域的热点和难点问题,本文将化学计量学中的多元校正方法,如偏最小二乘法和人工神经网络法与紫外分光光度法相结合,同时测定了紫外吸收光谱严重重叠的甲基苯甲醛的三种同分异构体混合体系中各组分的含量。确定了测定的最佳波长范围为230~304 nm;测得48个混合标样的吸光度值用于建立模型,其中,邻、间、对甲基苯甲醛的浓度范围分别为6.0~15.0、7.0~16.0和8.0~19.0 μg·mL-1。7个模拟样品作为监测集用于检验所建立模型的预测性能。本文还讨论了三种组分浓度比例对所建立模型预测性能的影响并确定了可以准确测定的浓度比例范围。所建立的方法用于模拟样品的测定,其回收率在84.00%与109.60%之间。与偏最小二乘法的测定结果比较,经成对t检验表明,两种方法对邻、间甲基苯甲醛测定结果无显著性差异;而对甲基苯甲醛的测定,人工神经网络法的测定结果优于偏最小二乘法。 相似文献
482.
Isomeric oligosaccharides γ‐cyclodextrin (γ‐CD), glucosyl‐βCD (Glc1‐βCD) and maltosyl‐αCD (Glc2‐αCD) were analyzed by traveling‐wave ion mobility (twIM) mass spectrometry (MS). Their formation of multicharged multimers differed from each other. The ion mobility‐mass spectrometry was useful in the self‐assembling and complex formation analyses of CD isomers. The drift times of the isomers and their product ions with the same mass were almost the same in collision‐induced dissociation (CID) MS/MS. In contrast, the ion mobility peak widths were sensitive to structural differences of the isomeric product ions. The twIM peak width (ms ‐ µs) of the product ions [M ? Glcn + H]+ (n = 0 ~ 6) of γ‐CD correlated linearly with their masses (Da); the large and/or long chain product ions had wider peak widths, which were much wider than those from the general diffusion effect. This was a novel and useful ‘trend line’ to discriminate between the three isomers. Plots of [M ? Glc2 ~ 6 + H]+ of Glc1‐βCD and [M ? Glc3 ~ 6 + H]+ of Glc2‐αCD product ions' plots were on the same trend line as γ‐CD. The plots of [M ? Glc1 + H]+ of Glc1‐βCD and [M ? Glc1, 2 + H]+ of Glc2‐αCD strayed from the γ‐CD line; their peak widths were narrower than those of γ‐CD. These results indicated that product ions from the chemical species of Glc1‐β CD and Glc2‐αCD retained their CD structure. Analyses of the IM peak widths enable us to elucidate the structures of the product ions. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
483.
Ying Liu Jiuming He Ruiping Zhang Jiangong Shi Zeper Abliz 《Journal of mass spectrometry : JMS》2009,44(8):1182-1187
The fragmentation behavior of hydroquinone glycosides involving one or two sugar groups from Fraxinus sieboldiana and their analogue arbutin was investigated systematically by electrospray ionization tandem mass spectrometry in negative ion mode. The characteristic fragmentation reaction of these compounds was through the homolytic and heterolytic cleavage of the O‐glycosidic bond to produce radical aglycone ion ([Y0 ? H]??) and aglycone ion (Y0?), respectively. Unambiguous differentiation between the mono‐O‐glycoside isomers which differ in glycosylation position was achieved by comparing the relative abundance of [Y0 ? H]?? and Y0? ions with the optimized collision energy. In the fragmentation of 1, 4‐di‐O‐glycosides, only the Y0? ion was produced when the first glucosyl residue was expelled. However, both the [Y0 ? H]?? and Y0? ions were present when the second glucosyl residue was eliminated. In addition, an interesting [Y0‐2H]? ion was present in the product ion spectra of hydroquinone glycosides with methoxy group(s) substituted at C‐3 or/and C‐5 positions of the benzene ring. The results of this study can facilitate the rapid determination of hydroquinone glycosides in crude plant extracts and also reveal that the systematic investigation and optimization of collision energy play an important role in the differentiation of isomers which have subtle differences in structures. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
484.
本文计算了甲基(-CH3),羟基(-OH)对1-丁氮烯和2-丁氮烯的取代基效应.1-丁氮烯引入取代基后.N=N双键的键长变短,而N-N单键的键长增长.异构体2-丁氮烯的键长变化较小.引入甲基或羟基后,N原子的孤对电子会与相应的N-C(N-O)键之间发生相互作用,使整个分子的超共轭作用增强.随着取代基数目的增多,总能量和生成热就会降低,取代基数目与分子能量(生成热)之间具有很好的相关性. 相似文献
485.
Molecular dynamics is used to study the kinetic stability of a classical fullerene C46 and its non-classical analog with a square. The lifetimes of both clusters till the moments of their isomerization are directly calculated as functions of temperature. The activation energies Ea of isomerization processes are determined from the fits of the results obtained to the Arrhenius law. For the non-classical fullerene, the value of Ea=3.1±0.2 eV is found to be considerably below that for the classical one, Ea=4.5±0.3 eV. In view of rather low kinetic stability of non-classical C46, its experimental registration in a gas phase seems to be problematic. 相似文献