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51.
M. T. Agedilova A. Zh. Turmukhambetov A. V. Kazantsev E. E. Shul'ts M. M. Shakirov S. M. Adekenov 《Chemistry of Natural Compounds》2004,40(3):273-275
Vasicinone and peganine were isolated from Peganum harmala L. Vasicinone 2,4-dinitrophenylhydrazone and vasicinone ketal were prepared. 相似文献
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M. P. Sobolevskaya V. A. Denisenko S. Fotso H. Laach N. I. Menzorova Yu. T. Sibirtsev T. A. Kuznetsova 《Russian Chemical Bulletin》2008,57(3):665-668
A new cyclic dipeptide, 3-a[(4-hydroxybenzyl)methyl]hexahydropyrrolo[1,2-a]pyrazine-1,4-dione (1) together with the known compounds, 2,3-dihydroxybenzoic acid (2), and 6-(3-methylbut-2-enyl)isatin (3) were isolated from the actinobacterium Streptomyces sp. GW 33/1593. Compounds 1 and 2 possessed cytotoxic activity against the sea urchin Strongylocentrotus intermedius embryos.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 652–655, March, 2008. 相似文献
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Keshri Nath Tiwari Darshana Bora Garima Chauhan Deepika Yadav Kavita Sharma Ashima Thakur 《合成通讯》2016,46(7):620-625
An efficient and greener protocol for easy access to 3-susbstituted-3-hydroxy-2-oxindoles by the reaction with various substituted isatins and acetophenones is described. This protocol is widely applicable for a variety of isatins and acetophenones using water as a reaction media and 1,4-diazabicyclo[2.2.2]octane (DABCO) as catalyst with shorter reaction time and good to excellent yield of products. 相似文献
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Ying Ding Lianbo Zhao Ying Fu Lei Hao Yupeng Fu Yuan Yuan Peng Yu Yuou Teng 《Molecules (Basel, Switzerland)》2021,26(1)
A series of multi-substituted isatin derivatives were synthesized using the powerful Sandmeyer reaction. The structures of these derivatives were confirmed by 1H-NMR, 13C-NMR, and HR-MS. Inhibition of proliferation activities of these derivatives against human leukemia cells (K562), human hepatocellular carcinoma cells (HepG2) and human colon carcinoma cells (HT-29) were evaluated in vitro using the MTT assay. Among the series, compound 4l exhibited strong antiproliferatory activities against K562, HepG2 and HT-29 cells with IC50 values of 1.75, 3.20, and 4.17 μM, respectively. The morphological, growth inhibitory and apoptosic effects of compound 4l in K562 cells, wound healing effect in HepG2 cells, and tube formating effect in matrix gel of HUVEC cells were evaluated consequently. All results indicated that compound 4l could be used as a potential antitumor agent in further investigations. 相似文献
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Organocatalytic Asymmetric Addition of Naphthols and Electron‐Rich Phenols to Isatin‐Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters
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Marc Montesinos‐Magraner Dr. Carlos Vila Rubén Cantón Prof. Dr. Gonzalo Blay Dr. Isabel Fernández Prof. Dr. M. Carmen Muñoz Prof. Dr. José R. Pedro 《Angewandte Chemie (International ed. in English)》2015,54(21):6320-6324
A quinine‐derived thiourea organocatalyst promoted the highly enantioselective addition of naphthols and activated phenols to ketimines derived from isatins. The reaction afforded chiral 3‐amino‐2‐oxindoles with a quaternary stereocenter in high yields (up to 99 %) with excellent enantioselectivity (up to 99 % ee). To the best of our knowledge, this transformation is the first highly enantioselective addition of naphthols to ketimines. 相似文献
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以SBA-15和氨基功能改性的SBA-15/NH2为载体,采用浸渍法制备了固载磷钨酸催化剂,通过FT—IR光谱,Raman光谱,XRD衍射分析,N2-吸附脱附实验,TEM和NH3-TPD等手段对催化剂进行表征.结果表明,磷钨酸在两种载体上均保持Keggin结构,载体的介孔结构没有明显破坏.在高固载量情况下,磷钨酸在SBA-15载体上发生晶相聚集,介孔孔道发生堵塞使比表面积、孔容和孔径明显减小.在SBA-15/NH2载体上,磷钨酸与载体发生酸碱作用,能够均匀分散于SBA-15/NH2的孔道中,但催化剂酸性有所降低.考察了相同固载量的两种催化剂对苹果酯合成反应的催化活性,结果表明,以SBA-15/NH2为载体的催化剂具有良好的重复使用性能. 相似文献