Application of a Bayesian Approach to the Tomographic Analysis of Hopper Flow

This paper presents a new approach to the analysis of data on powder flow from electrical capacitance tomography (ECT) using probability modelling and Bayesian statistics. The methodology is illustrated for powder flow in a hopper. The purpose, and special features, of this approach is that ‘high‐level’ statistical Bayesian modelling combined with a Markov chain Monte Carlo (MCMC) sampling algorithm allows direct estimation of control parameters of industrial processes in contrast to usually applied ‘low‐level’, pixel‐based methods of data analysis. This enables reliable recognition of key process features in a quantitative manner. The main difficulty when investigating hopper flow with ECT is due to the need to measure small differences in particle packing density. The MCMC protocol enables more robust identification of the responses of such complex systems. This paper demonstrates the feasibility of the approach for a simple case of particulate material flow during discharging of a hopper. It is concluded that these approaches can offer significant advantages for the analysis and control of some industrial powder and other multi‐phase flow processes.     

Application of fibre-optic rotational seismometer in investigation of seismic rotational waves

Application of a fibre-optic Sagnac interferometer as a rotational seismometer is presented in this paper. It is a new device which parameters (sensitivity equal to 4.3×10⁻⁸ rad/s for 2σ) are comparable with the parameters of typical mechanical rotational seismometers. However, a direct measurement of rotation without influence of linear motions for fibre-optic rotational seismometer designed it for a direct measurement of a ground rotation component. Experimental data obtained during simultaneous application of the above two types of sensors are also presented. Research of near-field seismic events, the amplitude of which has been identified in the range of 1.5×10⁻⁶ rad/s to 2×10⁻⁷ rad/s, shows directly that, so-called, seismic rotational waves exist independently of typical seismic waves generated during earthquakes.     

传热传质分离的绝热吸收过程实验研究

根据传热传质分离的吸收形式,设计加工了一台溴化锂绝热降膜吸收的实验装置,对溴化锂水溶液在倾斜平板上对水蒸气的吸收特性进行了实验研究,分析了预冷却温差、溶液流量及平板倾角对吸收过程的影响。实验结果表明:预冷却温差、溶液流量及平板倾角越大,溴化锂溶液对水蒸气的吸收效果越好,并认为吸收过程可以分成三个步骤,另外就热质分离吸收器的设计过程中的溴化锂溶液的最小速度提出建议。     

多元对应分析在抽样调查分析中的应用

本文应用多元对应分析、聚类分析等数理统计方法 ,对抽样调查问卷进行分析 ,从而得出各类读者群的特征及它们之间的差异     

风机蜗壳内部旋涡流动的数值分析

本文求解Ｒｅｙｎｏｌｄｓ时均Ｎ－Ｓ方程和ｋ－ε湍流模式,使用任意曲线坐标下张量形式的非交错网格Ｓｉｍｐｌｅ算法和ＴＭ网格生成技术,数值分析风机矩形蜗壳内的二次流及其沿周向不同横截面上旋涡的生成演化细节,讨论了蜗壳宽度与粘性效果的作用机制和影响。     

V型布风板流化床煤气化试验研究及工业应用

在一沸腾段内径为６００ ｍｍ的Ｖ型布风板流化床煤气发生炉内对低热值动力烟煤的气化过程进行了系统的试验研究。测量了煤气发生炉内炉膛温度沿高度的分布。研究了气化温度和煤气组分随给煤量、流化风量、中心喷动风量和水蒸气喷入量的变化规律。得到了以空气和水蒸气作为气化剂的煤气发生炉的气化适宜床温在９４０～９８０℃,合理的给煤量和总空气量之比在 ０．７～０．８ｋｇ／Ｎｍ３之间。研究结果对Ｖ型布风板流化床煤气发生炉的运行和放大设计、改造现有燃煤设备并降低对环境的污染具有指导意义。     

充液圆柱壳轴向冲击屈曲的实验研究与计算机数值模拟

借助落锤装置实现冲击加载,完成了一组充满水的金属薄壁圆柱壳试件轴向冲击屈曲过程的实验研究,同时利用LS－DYNA大型动力软件对冲击屈曲的全过程进行了计算机模拟,对于屈曲模态发展过程以及冲击力和液压的动态时程曲线,实验观察和数值结果均表现出较好的一致性,研究表明,在撞击过程中壳内形成很大的液体压力,在此内压和轴向压缩的联合作用下,壳壁发生轴对称塑性屈曲,屈曲模态为一系列依次发展的环带波纹。     

新型同分异构芘基查尔酮的理论研究和超快三阶非线性光学响应

合成了3个新型同分异构芘基查尔酮:1-(芘-1-基)-3-(吡啶-2-基)-2-丙烯-1-酮(3a)、1-(芘-1-基)-3-(吡啶-3-基)-2-丙烯-1-酮(3b)和1-(芘-1-基)-3-(吡啶-4-基)-2-丙烯-1-酮(3c)。 通过核磁共振波谱仪(NMR)、傅里叶变换红外光谱仪(FTIR)和液-质联用仪(LC-MS)等技术手段表征3个化合物的结构、热稳定性和线性光学性质和三阶非线性光学吸收性能。 结果表明,在532 nm和180 fs条件下,化合物3a-3c均表现出超快三阶非线性光学响应,化合物3c的非线性吸收系数分别是化合物3b和3a的1.14和2.67倍。 运用密度泛函理论方法计算了化合物3a-3c的非线性光学性质及其电子性质,结果表明,化合物3c分子具有最大的静态第一超极化率(β₀)(2830.9 a.u.),并具有最小的最高占据分子轨道(HOMO)-最低空分子轨道(LUMO)之间的能隙(3.11 eV)和最小的跃迁能(ΔE)(2.67 eV),这与N原子在吡啶环上的位置有关;分子内部均存在电荷转移现象。 3个化合物的紫外-可见光谱在450 nm以上无吸收,有良好的热稳定性,在激光防护方面有应用前景。     

两个查尔酮衍生物的合成及超快三阶非线性光学响应

合成了两个二茂铁基查尔酮衍生物:1-二茂铁基-3-(4,5-苯并噻吩-3-基)丙烯酮(FBTAK)和1-二茂铁基-3-(5-苯基噻吩-2-基)丙烯酮(FPTAK),经核磁共振氢谱、碳谱和高分辨质谱对其结构进行表征。采用Z-扫描技术测定了化合物的三阶非线性光学吸收系数(β)、折射系数(n2)和分子超极化率(γ),采用密度泛函理论方法计算了它们的几何结构、分子轨道电子云图和相关能量,同时也测定了其紫外-可见吸收光谱和DSC曲线。FPTAK的分子超极化率(γ)分别是FBTAK、1-二茂铁基-3-(4-叔丁基苯基)丙烯酮(a)和1-二茂铁基-3-联苯基丙烯酮(b)的6. 04倍、4. 3倍和3. 7倍。从构效关系看,苯联噻吩基比苯并噻吩基和联苯基的贡献大,也就是噻吩环比苯环的贡献大。结果表明,电荷转移可以在分子内发生,表现出超快三阶非线性光学响应。     

Zn-Co oxide electrodes with excellent capacitive behavior for using supercapacitor application

In the present study, super-capacitive behavior of spinel Zn-Co oxides (with different Zn⁺²/Co⁺² mol ratio) has been thoroughly investigated. The spinel of transition metal oxides with different morphologies has been synthesized with hydrothermal method on Ni foam as substrate layer. The specific capacitance of the Zn-Co oxide electrode prepared at 180 °C for 5 h with different Zn⁺²/Co⁺² mol ratios of 1:0, 2:1, 1:1, 1:2, 0:1 were investigated and measured 405, 842, 726, 1237, 705 F g^?1, respectively at 50 mV s^?1 scan rate. Zn-Co oxide with Zn⁺²/Co⁺² mol ratio of 1:2 was also synthesized at two different temperatures of 120 and 150 °C for 5 h with the specific capacitance of 1147, 917 F g^?1 at 50 mV s^?1 scan rate, respectively. Among the obtained data, the sample with Zn⁺²/Co⁺² mol ratio of 1:2 prepared at 180 °C for 5 h possessed highest specific capacitance. The cyclic life of this electrode showed 92% capacitance retention after 1000 cycle of charge-discharge. All results revealed that Zn-Co oxides had excellent supercapacitive properties due to multiple oxidation states and fast ion/electron transfer at the surface of electrode which could be offered as suitable devices for energy storage applications.