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The thermal properties and thermal stability of diaspore-corundum (AlOOH-Al2O3), from Goian (Pontevedra, Spain) were studied by means of differential thermal analysis (DTA), thermogravimetry (TG), high temperature X-ray diffraction (HTXRD) and thermally stimulated luminescence (TL) techniques. The samples were annealed to link the combined effect of (i) dehydroxylation, (ii) oxidation-reduction of chromophores (Mn 0.5%, Fe2O3 0.12%, TiO2 0.021% and Cr 80 ppm) determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) and (iii) phase transitions whilst sample heating (i.e. α-AlOOH→α′-Al2P3→α-Al2O3). The blue colour of diaspore, attributed to the Ti4+-Fe2+ intervalence-charge-transfer mechanism, turns to white (circa 500 °C) in good agreement with the DTA endothermic peak (dehydroxylation). The coexistence of α-AlOOH and α′-Al2P3 phases has been detected by in situ HTXRD and could be correlated to the thermoluminescence tests performed on preheated aliquots (up to 500 °C). 相似文献
114.
不确定性是复杂工程系统的内在属性,在决策依赖不确定条件下对工程系统的投资决策需考虑不确定性与决策过程之间的交互作用,使得投资决策问题的求解非常困难.提出了决策依赖不确定条件下复合实物期权估值的最小二乘模拟算法,方法较好地解决了在决策依赖不确定条件下由于不同期权价值相互耦合所带来的计算复杂性,进一步拓展了最小二乘模拟算法在期权估值中的应用,基于该方法,可以比较方便地解决决策依赖不确定条件下工程系统投资决策问题. 相似文献
115.
L.M. da Silva M.C. de Melo A.N. Medina F.G. Gandra 《Physica B: Condensed Matter》2009,404(19):3018-3020
We report on results of X-ray powder diffraction, magnetization and specific heat measurements of the pseudo-ternary (Ce1−xLax)PdIn2 system with x=0; 0.2; 0.4 and 0.6. The results show a linear increase of the unit cell volume and a reduction of the ferromagnetic transition as La content increases. The Debye temperature, Sommerfeld coefficient and crystal field parameters were estimated from specific heat data, and are found to be weakly dependent of the Ce concentration. Also, the variation of magnetic entropy at TC is only weakly dependent on x (ΔS≅0.92Rln2) indicating that TK/TC is approximately constant along the series. The TC and TK behaviors are explained by the variation of the exchange parameter due to the volume change when Ce is replaced by La. Our results indicate that the chemical pressure is the dominant effect rather than the chemical disorder for determining the physical proprieties of the (Ce1−xLax)PdIn2 system. 相似文献
116.
From a new magnetically diluted spinel oxide with composition Fe0.6Mg1.6Ni0.1Ti0.7O4 an as-prepared sample and one after reheating three times have been investigated with Mössbauer spectroscopy. The spectra of the as-prepared sample clearly show a typical superparamagnetic behaviour of magnetic clusters with diverging sizes. On the other hand, the reheated sample exhibits a sharp magnetic transition at 16 K. External-field Mössbauer measurements of the latter reveal spin canting to be exclusively present on the octahedral sites which disappears at the magnetic transition temperature. These results show that this spinel compound exhibits a transition to a spin-glass for which the random freezing only occurs on the octahedral sites. 相似文献
117.
讨论了一种食饵增长为Gilpin-Ayala型的比率依赖的食饵捕食者模型,利用第二加性复合矩阵原理证明线性化系统正轨道解的稳定性,结合系统在凸集中存在唯一的局部正平衡点,证明了正平衡点的全局渐近稳定性.结合数值模拟验证了所得结论的合理性,同时指出定理结论仅为充分条件,丰富完善了模型的动力学性质. 相似文献
118.
建立了爆炸残留物中无机阴离子的毛细管离子色谱检测方法.分离柱为Dionex IonPac AS19Capillary柱,通过考察阴离子保留情况,选择以10μL·min-1流速的KOH梯度洗脱,进样量为0.4μL,对爆炸残留物中常见无机阴离子进行了分析.在上述条件下,Cl-,NO2-,ClO3-,NO3-,SO24-,SCN-,ClO4-能很好地分离,并在质量浓度为0.01~5.00μg·mL-1时与对应色谱峰面积之间的线性关系良好,检出限分别为0.36、0.46、1.25、0.92、1.06、1.61、2.65ng·mL-1,回收率为95.84%~102.40%.该方法简便、快速、准确,可用于实际样品的测定. 相似文献
119.
Stepanka Kuckova Jiri Santrucek Martin Adamec Radovan Hynek Antonin Zeman 《液相色谱法及相关技术杂志》2016,39(16):739-744
In this paper, a Gothic mortar originating from the remains of a bridge pier in Roudnice nad Labem (Czech Republic) was analyzed. The inorganic composition of the mortar showing special mechanical properties was studied using polarizing light microscopy, scanning electron microscopy coupled with energy dispersive X-ray spectrometry, and X-ray diffraction, while the protein content was analyzed by peptide mass mapping using matrix-assisted laser desorption/ionization—time of flight mass spectrometry and nanoliquid chromatography coupled to tandem mass spectrometry. Two types of inorganic binders having a composition similar to mineral wollastonite and hydraulic lime and milk protein additive were detected. We believe that organic and inorganic binders added together to the mortar increase its hardness and firmness in the aquatic environment. 相似文献
120.
A novel mixed‐tribridged dimolybdenum(I) compound [Bn4N][Mo2(μ‐SPh)2(μ‐Cl)(CO)6] (1) has been synthesized from the reaction of Mo2(CO)3(SPh)2 with BU4NCl. Compound 1 was characterized by IR, UV‐Vis and 1H, 13C, 95Mo NMR spectroscopic analyses. The electrochemical behavior was measured by cyclic voltammetry, indicating a quasi‐reversible two‐electron transfer in one step. The crystal structure determined by X‐ray crystallography shows that 1 contains a [Mo2(μ‐S)2(μ‐Cl)]? core with a planar Mo2S2unit and a Cl bridge. The Mo? Mo distance is 0.28709(7) nm, and the Mo‐Cl‐Mo angle is 66.44(4)°. A newface‐sharing bioctahedral structure is discussed. 相似文献