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21.
《Physics and Chemistry of Liquids》2012,50(1):8-17
ABSTRACTThe effect of water hardness causing ions on the critical micelle concentration (cmc) of surfactants was studied using conductivity measurement. Spectrophotometric and conductometric studies of dye and surfactant interaction under the influence of water hardness causing ions were also investigated. It was found that with increasing hardness in water, cmc of the surfactants tends to decrease. The change in the colour of the solution was observed as the degree of hardness increases. Hardness of water can consider as a major contributor of fading or change in colour during washing and cleaning of dyed material. Dye in a surfactant solution containing varying amount of hardness causing ions undergoes a blue shift in the visible region and red shift in ultraviolet region. The comparison between sodium dodecylsulphate (SDS) and saponin natural surfactant showed that turbidity was observed only in the aqueous solution of SDS in the presence of very hard water. 相似文献
22.
K. F. Hulme 《Optics & Laser Technology》1982,14(4):213-215
Factors affecting the design of compact heterodyne- and direct-detection systems are contrasted. Recent UK achievements are placed in context: a TEA laser direct-detection rangefinder and a chirp-pulse-comparison rangefinder-velocimeter are described. 相似文献
23.
An infra-red reflectance microscope accessory and several of its analytical applications including Chromatographic fractions and in-situ thin films are described. 相似文献
24.
A micro liquid chromatograph-interfaced Fourier transform infrared spectrophotometer system (LC/FTIR) for on line analysis of liquid chromatography effluents is described. About 2 μg of injected diethylphthalate can be detected using a 0.025 mm pathlength flow cell. Several examples of a micro LC/FTIR are demonstrated. 相似文献
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The two continuous wave lasers normally used for Raman spectroscopy are the argon and krypton ion lasers. These routinely provide step tuning between 459.9 and 676.4 nm. However, it is possible, using suitably coated mirrors, to obtain far red lines from the Kr+ laser at 752.5 and 799.3 nm.This additional capability offers advantages for Raman spectroscopy in the areas of fluorescence rejection, sample decomposition and resonance Raman spectroscopy. 相似文献
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薛光荣 《分析测试技术与仪器》2004,10(3):176-179
运用了N2O-C2H2火焰原子吸收光谱法进行羰基镍粉钼含量的测定。介绍了钼最佳测定条件及呈良好线性范围的浓度.同时对样品消化处理条件及在测定中样品的干扰因素进行了综合考虑.该方法的相对标准偏差均小于1.0%(n=6),回收率均在97.0%～102.0%(n=6)之间.达到了实验室分析质量控制的要求. 相似文献
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Ahmed H. Bakheit Rashad Al-Salahi Abdulrahman A. Al-Majed 《Molecules (Basel, Switzerland)》2022,27(19)
This study describes the non-covalent interactions of the charge transfer complex (CT), which was responsible for the synthesis of Linagliptin (LNG) with 2,3-Dichloro-5,6-Dicyano-1,4-benzoquinone (DDQ), or with Chloranilic acid (CHA) complexes in acetonitrile (MeCN) at temperatures of (25 ± 2 °C). Then, a UV–Vis spectrophotometer was utilized to identify Linagliptin (LNG) from these complexes. For the quantitative measurement of Linagliptin in bulk form, UV–Vis techniques have been developed and validated in accordance with ICH criteria for several aspects, including selectivity, linearity, accuracy, precision, LOD, LOQ, and robustness. The optimization of the complex synthesis was based on solvent polarization; the ratio of molecules in complexes; the association constant; and Gibbs energy (ΔG°). The experimental work is supported by the computational investigation of the complexes utilizing density functional theory as well as (QTAIM); (NCI) index; and (RDG). According to the optimized conditions, Beer’s law was observed between 2.5–100 and 5–100 µM with correlation coefficients of 1.9997 and 1.9998 for LGN-DDQ and LGN-CHA complexes, respectively. For LGN-DDQ and LGN-CHA complexes, the LOD and LOQ were (1.0844 and 1.4406 μM) and (3.2861 and 4.3655 μM), respectively. The approach was successfully used to measure LGN in its bulk form with high precision and accuracy. 相似文献