全文获取类型
收费全文 | 1485篇 |
免费 | 191篇 |
国内免费 | 115篇 |
专业分类
化学 | 745篇 |
晶体学 | 4篇 |
力学 | 258篇 |
综合类 | 46篇 |
数学 | 69篇 |
物理学 | 669篇 |
出版年
2024年 | 6篇 |
2023年 | 15篇 |
2022年 | 52篇 |
2021年 | 60篇 |
2020年 | 63篇 |
2019年 | 48篇 |
2018年 | 30篇 |
2017年 | 60篇 |
2016年 | 65篇 |
2015年 | 68篇 |
2014年 | 60篇 |
2013年 | 157篇 |
2012年 | 99篇 |
2011年 | 84篇 |
2010年 | 69篇 |
2009年 | 75篇 |
2008年 | 55篇 |
2007年 | 86篇 |
2006年 | 87篇 |
2005年 | 54篇 |
2004年 | 51篇 |
2003年 | 56篇 |
2002年 | 43篇 |
2001年 | 47篇 |
2000年 | 45篇 |
1999年 | 37篇 |
1998年 | 36篇 |
1997年 | 27篇 |
1996年 | 20篇 |
1995年 | 28篇 |
1994年 | 24篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 11篇 |
1990年 | 16篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 3篇 |
1959年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有1791条查询结果,搜索用时 15 毫秒
51.
Modeling Studies of the Formation and Destruction of NO in Pulsed Barrier Discharges in Nitrogen and Air 总被引:1,自引:0,他引:1
This paper presents the results of modeling studies on the formation and destruction of NO in pulsed barrier discharges in nitrogen and air. The goals of this work are to identify the major processes involved in the formation and destruction of NO in air discharges, to distinguish between oxidative and reductive paths for NO destruction, to explore the potential importance of excited state reactions, to evaluate the role of water in such systems, and to identify the final products in the absence of heterogeneous processes. In all cases, the systems were modeled with 100×10–4% (100 ppm) of added NO, with and without 3% added water. The focus in all of this work is chemistry in the post-pulse regime. 相似文献
52.
《先进技术聚合物》2018,29(4):1255-1260
Acoustic felts are commonly used in white goods. Bearing that into mind, this paper aims to enhance sound absorption behavior of such felts, in particular, within the low and medium frequency ranges. In doing so, wool and jute felt samples were coated with electrospun polyacrylonitrile nanofibrous membrane. These nanocoated felts were studied in terms of their sound absorption performance, air permeability, and surface morphology. The results indicated that the air permeability of the felts could be drastically decreased by coating with nanofibers, which was required for better acoustic performance of felt‐like structures. Moreover, the samples having higher amount polyacrylonitrile nanofibers tended to demonstrate better sound absorbency. 相似文献
53.
《Journal of Polymer Science.Polymer Physics》2018,56(4):319-329
In the electrospinning process, the measurement of extension rate of the straight jet is not an easy task. In this study, the diameter profile of the tapering straight jet is determined with a laser light‐scattering technique. Afterwards, the jet extension rate () is derived and used to compare with the solution‐intrinsic rates, for example, the terminal relaxation rate and the Rouse relaxation rate. The extension rate of the straight jet depends on position: it is highest near the cone apex (region I) and decays to a constant value in the major jet (region II) until approaching the jet end (region III), at which the extension rate abruptly drops to nearly zero, that is, I >II ≫III ∼ 0. The jet diameter in region III is independent of solution concentration and applied voltage, but is scaled to the flow rate with an exponent of ∼0.37. The derived exponent is consistent with a simple prediction based on the counterbalance between the stretching electric force and the compressive force induced by the air drag force. Provided that air friction becomes overwhelming at the straight jet end, the long electrified jet is likely to buckle, thereby triggering the instability of jet whipping. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018 , 56, 319–329 相似文献
54.
《Journal of separation science》2018,41(15):3105-3112
Simultaneous derivatization and air‐assisted liquid–liquid microextraction using an organic that is solvent lighter than water has been developed for the extraction of some parabens in different samples with the aid of a newly designed device for collecting the extractant. For this purpose, the sample solution is transferred into a glass test tube and a few microliters of acetic anhydride (as a derivatization agent) and p‐xylene (as an extraction solvent) are added to the solution. After performing the procedure, the homemade device consists of an inverse funnel with a capillary tube placed into the tube. In this step, the collected extraction solvent and a part of the aqueous solution are transferred into the device and the organic phase indwells in the capillary tube of the device. Under the optimal conditions, limits of detection and quantification for the analytes were obtained in the ranges of 0.90–2.7 and 3.0–6.1 ng/mL, respectively. The enrichment and enhancement factors were in the ranges of 370–430 and 489–660, respectively. The method precision, expressed as the relative standard deviation, was within the range of 4–6% (n = 6) and 4–9% (n = 4) for intra‐ and interday precisions, respectively. The proposed method was successfully used for the determination of methyl‐, ethyl‐, and propyl parabens in cosmetic, hygiene and food samples, and personal care products. 相似文献
55.
为了解大同市居民对室内空气质量的认知情况,并分析认知程度与教育的关系,于2016年3月至5月,在大同市城区的9个社区随机对居民进行问卷调查。问卷内容包括居民对室内空气质量安全知识的了解,检测室内空气质量的意愿和治理意愿3个方面。将居民所处地域、居民的年龄与学历对室内空气质量安全认知程度的影响分别进行统计学分析。结果表明,大同市居民室内空气质量安全认知程度总体得分15.8,得分率为52.7%;新城区的居民对室内空气质量安全认知水平高于老城区居民(p<0.05);学历越高且越年轻的居民对室内空气质量安全的认知水平越高,寻求有关机构进行室内空气检测和治理的意愿更强烈,且对检测和治理的费用承受度较高。大同市居民对室内空气质量安全认知程度总体不高,还应加强对市民的室内空气质量安全方面的教育。 相似文献
56.
Lithium‐Ion Endohedral Fullerene (Li+@C60) Dopants in Stable Perovskite Solar Cells Induce Instant Doping and Anti‐Oxidation 下载免费PDF全文
Dr. Il Jeon Dr. Hiroshi Ueno Seungju Seo Dr. Kerttu Aitola Ryosuke Nishikubo Prof. Akinori Saeki Dr. Hiroshi Okada Prof. Gerrit Boschloo Prof. Shigeo Maruyama Prof. Yutaka Matsuo 《Angewandte Chemie (International ed. in English)》2018,57(17):4607-4611
Herein, we report use of [Li+@C60]TFSI? as a dopant for spiro‐MeOTAD in lead halide perovskite solar cells. This approach gave an air stability nearly 10‐fold that of conventional devices using Li+TFSI?. Such high stability is attributed to the hydrophobic nature of [Li+@C60]TFSI? repelling moisture and absorbing intruding oxygen, thereby protecting the perovskite device from degradation. Furthermore, [Li+@C60]TFSI? could oxidize spiro‐MeOTAD without the need for oxygen. The encapsulated devices exhibited outstanding air stability for more than 1000 h while illuminated under ambient conditions. 相似文献
57.
Qing L? Ming Hua LIU* Laboratory of Colloid Interface Science Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences 《中国化学快报》2001,(12)
Langmuir monolayer at the air/water interface is the basis to understand the molecular arrangement and to fabricate the organized molecular films1. Bolaamphiphiles describes the molecules in which two head functional groups are linked by one or two hydrophobic chains2,3. In comparison with the one-headed amphiphile, abundant configurations of Langmuir monolayer are expected in bolaamphiphiles. Generally, three kinds of configurations of the Langmuir monolayers of bolaamphiphile at the air/w… 相似文献
58.
Modified High‐Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium‐Ion Batteries 下载免费PDF全文
Dr. Ya You Dr. Hugo Celio Jianyu Li Dr. Andrei Dolocan Prof. Dr. Arumugam Manthiram 《Angewandte Chemie (International ed. in English)》2018,57(22):6480-6485
High‐Ni layered oxides are promising next‐generation cathodes for lithium‐ion batteries owing to their high capacity and lower cost. However, as the Ni content increases over 70 %, they have a high dynamic affinity towards moisture and CO2 in ambient air, primarily reacting to form LiOH, Li2CO3, and LiHCO3 on the surface, which is commonly termed “residual lithium”. Air exposure occurs after synthesis as it is common practice to handle and store them under ambient conditions. The air exposure leads to significant performance losses, and hampers the electrode fabrication, impeding their practical viability. Herein, we show that substituting a small amount of Al for Ni in the crystal lattice notably improves the chemical stability against air by limiting the formation of LiOH, Li2CO3, LiHCO3, and NiO in the near‐surface region. The Al‐doped high‐Ni oxides display a high capacity retention with excellent rate capability and cycling stability after being exposed to air for 30 days. 相似文献
59.
Věra JandováZdeněk Bastl Jan ŠubrtJosef Pola 《Journal of Analytical and Applied Pyrolysis》2011,92(2):287-291
Pulsed infrared laser-irradiation of titanium monoxide leads to ablation and when carried out in gaseous benzene (1-5 Torr) to simultaneous dielectric breakdown of benzene into low molecular carbonaceous species which allow carbothermal reduction of ablated TiOx particles and their protection by carbonaceous shell. The deposited particles are characterized by Fourier transform infrared Raman and X-ray photoelectron spectroscopy and by electron microscopy and shown to be stable towards oxidation in air. The reported process can find use in protection of gas-phase produced reactive nanoparticles by carbon phase. 相似文献
60.
Adsorption at the air-water interface and emulsification properties of grain legume protein derivatives from pea and broad bean 总被引:2,自引:0,他引:2
Tsoukala A Papalamprou E Makri E Doxastakis G Braudo EE 《Colloids and surfaces. B, Biointerfaces》2006,53(2):203-208
Functional properties of native and modified (through induced autolysis) pea (Pisum sativum L.) and broad bean (Vicia faba L.) protein derivatives are studied. In specific, protein solubility and behavior at the air–water interface through surface pressure measurements are investigated. Furthermore the ability of the protein products to act as emulsifying agents and to stabilize emulsions is studied through oil droplet size distribution measurements and by the protein adsorbed at the oil–water interface. The data reveal that the ability of the proteins to act as surfactants and build up a rigid film around the oil droplets, mainly depends on their suitable molecular configuration and structure. Hydrolysis did not promote the functionality of the legume proteins. Broad bean exhibited better functionality than pea, before and after hydrolysis. Some comparisons were also made with lupin (Lupinus albus L.) protein isolate. 相似文献