制冷空调系统替代工质的发展现状及方向

本文主要针对CFC11、CFC12以及HCFC22介绍了目前替代工质的发展现状,阐述了混合工质以及氨、二氧化碳、碳氢化合物等自然工质作为替代工质的特点以及其发展现状,总结了制冷空调系统替代工质的发展方向。     

基于Unity 3D的船舶压缩空气系统的虚拟设计

针对目前船舶空气压缩仿真训练系统大多采用半物理仿真与二维软件界面仿真相结合方式训练效果不佳的问题,将虚拟现实技术引入到船舶压缩空气系统的仿真设计;设计一套基于Unity 3D的船舶压缩空气系统,实现虚拟仿真程序和三维虚拟场景的实时交互,生成一个逼真的三维视觉、听觉、触觉的感官世界,加强培训人员的沉浸感,从而获得一种置身于真实环境中的感受;系统可供学员无限制反复训练,节省系统的维护费用,规避实物操作设备中可能出现的各种风险,提高训练效果。     

快递企业航空货运网络的构建

快递业竞争激烈,构建高效合理的航空货运网络是快递企业提高竞争力的重要手段。“枢纽—辐射”式航空货运网络是整合航空快递资源、提高航空快递资源利用效率、提高快递企业竞争力的有效模式。本文以降低航空快递网络成本、加快航空快递处理时间为目标,从航空快递网络枢纽的选取、指派关系的确定、枢纽个数的选择三个方面研究了航空快递网络模型建立问题,选用遗传算法求解不同枢纽个数下航空快递网络的运输成本,并据此进行枢纽的选取,运用重力模型法进行指派关系的确定,在此基础上运用超效率DEA模型确定枢纽个数。接着,以包含17个节点的顺丰航空快递网络的规划为例,对本文所提出的模型和算法进行了验证,验证结果证实了模型的合理性。本文的研究为快递企业构建航空货运网络提供了科学实用的方法,该方法的使用可以降低航空货运成本,提高效率,从而提高快递企业的竞争力。     

光学玻璃折射率精密测量中环境条件修正公式的研究

该文指出了在光学玻璃折射率测量中目前使用的气压修正公式在折射率精密测量中的不适应与缺陷。并从空气折射率的最新计算公式入手,着重研究和提出了新的环境条件修正公式。指出在不同测试精度和不同测试条件下应采用不同的修正公式。     

高效液相色谱三元梯度分离法测定大气中11种醛酮类化合物的研究

研究选择了以２,４－二硝基苯肼衍生化三元梯度洗脱的高效液相色谱测定大气中１１种醛酮类化合物的最佳色谱分离条件,醛酮类化合物的检出限０．４５到２．０４ｎｇ,各化合物保留时间和相对标准偏差ｓ,≤０．３８％在所测定的含量范围内具有很好的线性关系,每种化合物的相关系数均大于０．９９９;研究了涂敷２,４－二硝基苯肼硅胶吸附采样夹的制作方法,并应用于大气环境中醛酮类化合物的分析。方法简单、快速,１１种醛酮类化     

Investigations of the catalytic properties of manganese oxides for the oxygen reduction reaction in alkaline media

The oxygen reduction reaction (ORR) was studied in KOH electrolyte on different manganese oxides, dispersed on a carbon powder (MnO_x/C). The oxides were prepared by different methods, for producing MnO, Mn₃O₄ and MnO₂ as major phases dispersed on the Vulcan XC-72 carbon. The oxides were characterized by XRD (X-ray diffraction) and in situ XANES (X-ray absorption near edge structure). The electrochemical measurements were made using cyclic voltammetry and steady state polarization curves carried out in an ultra-thin layer rotating ring/disk electrode. The results have shown lower activity for the ORR on the MnO_x/C species compared to that on Pt/C, but higher activity compared to that of pure Vulcan carbon. Formation of involving 2e⁻ per O₂ molecule is the main path of the ORR in the studied MnO_x/C catalysts but, at low overpotentials and rotation rates the number of electrons is raised to 4 due to the occurrence of a disproportionation reaction. Large differences of electrocatalytic activity were seen for the different oxide species, and these were related to the presence of a Mn(IV) phase and the occurrence of a mediation processes involving the reduction of Mn(IV) to Mn(III), followed by the electron transfer of Mn(III) to oxygen.     

质子交换膜燃料电池MnO2-Pt/C复合催化剂阴极的富氧作用

质子交换膜燃料电池空气电极阴极催化剂的富氧作用是提高其性能的关键.应用化学氧化法制备MnO2-Pt/C复合催化剂,研究MnO2的富氧作用,应用CV、CP、TEM等方法表征该催化剂,并组装成单电池测试其性能.     

湿式氧化用于染料废水脱色:过去20年回顾（英文）

Wet air oxidation(WAO), a liquid phase reaction between organic materials in water and oxygen, is one of the most economical and technologically viable advanced oxidation processes for wastewater treatment, particularly toxic and high organic content wastewater. WAO is the liquid phase oxidation of organics or oxidizable inorganic components at elevated temperatures(125–320 °C) and pressures(0.5–20 MPa) using gaseous oxygen(or air) as oxidant. In the past two decades, the WAO process was widely studied and applied in the treatment of dye wastewater. Compared to conventional WAO, catalytic WAO processes have higher efficiency and use moderate reaction conditions. The catalysts included homogenous and heterogeneous types. The key points that need to be solved are recycling of homogenous catalysts and better stability of heterogeneous catalysts. In the present review, the technological processes are first introduced, then some research history and hotspots of WAO research are presented, and finally, its application in the treatment of dye wastewater in the past two decades is summarized to reveal the impressive changes in modes, trends, and conditions used. The application includes model pollutant studies and wastewater tests.     

一种高稳定性光纤F-P标准具的设计

法布里-珀罗(F-P)标准具广泛应用于光纤通信与光纤传感领域。实心标准具受自身材料的限制,无法满足高稳定性的要求。空气隙标准具采用热膨胀系数极低的垫片,提高了器件的温度稳定性能。介绍了低温漂光纤F-P标准具的设计和制作,出射光自由光谱范围为100GHz,损耗为3dB,0~70℃温度漂移小于3GHz。相比于采用传统方法制作的标准具,该光纤F-P标准具稳定性更高,解决了实心标准具折射率和热膨胀变化大的问题。     

甲烷和空气部分氧化制合成气

使用空气做氧化剂,可减轻甲烷部分氧化制合成气反应中催化剂床层的“热点”问题,而且可大大降低加压反应条件下反应爆炸的危险性,因此易于工业化,对国内外在这一领域的研究总结表明,以空气与甲烷部分氧化制合成气在理论和反应条件上都是可行的,但忖用于空气来转化CH4的抗高温烧结和抗结炭性能好的催化剂有待进一步研究和开发,参考文献10篇。