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61.
A new series of bisthiosemicarbazone derivative receptors(1,2 and 3)have been synthesized by simple steps ingood yields.Their anion recognition properties were studied by UV-Vis and ~1H NMR spectroscopy.The resultshowed that the receptors 1,2 and 3 all had a better selectivity to F~-,CH_3COO~- and H_2PO_4~-,but no evidentbinding with Cl~-,Br~-,I~-,NO_3~- and HSO_4~-.Upon addition of the three anions to the receptors in DMSO,thesolution acquired a color change from colorless to dark yellow that can be observed by the naked-eyes,thus the re-ceptors can act as fluoride ion sensors even in the presence of other halide ions.The data showed that it was regularthat the three receptors had different binding ability with the three anions.For the same anion,the association con-stants followed the trend:receptor 1>3>2.The UV-Vis data indicates that a 1:1 stoichiometry complex isformed through hydrogen bonding interactions between compound 1,2 or 3 and anions. 相似文献
62.
Chemical and physical analyses of malt, the main ingredient of beer, have been used to predict the concentration of certain volatile compounds in the finished beer.The prediction was done by means of the partial least squares regression (PLS2) in SIMCA. The total data set as well as individual malt clusters were submitted to PLS analysis. Best prediction was obtained by separating the total object matrix in classes according to similarity found by fuzzy pattern recognition (FCV). FCV was also used to separate the beer variables in classes and to select the subset of variables to be predicted.A joint approach of fuzzy pattern recognition to identify groups of samples and SIMCA-PLS2 to predict several dependent variables is suggested as a powerful tool in process-analytical chemistry. 相似文献
63.
Bile acid-based acyclic receptors bearing two imidazole and benzimidazole moieties have been synthesized. Anion binding studies using 1H NMR revealed that imidazolium receptor exhibits high selectivity for chloride ion while benzimidazolium receptor showed selectivity for Y-shaped acetate ion through hydrogen bond interactions involving imidazolium C-2 and acetyl methylene hydrogens. 相似文献
64.
65.
Lämmerhofer M 《Journal of chromatography. A》2005,1068(1):31-57
A review on the advantages, peculiarities, and the potential of enantioselective capillary electrochromatography (CEC) in nonaqueous media is presented. Some fundamentals on CEC with particular focus on enantioselective CEC are discussed. The strategies, concepts, preferentially utilized chiral selectors and column technologies that have been utilized to succeed in highly efficient enantiomer separations by nonaqueous CEC are described thoroughly. 相似文献
66.
67.
本文报道新的Tweezer(1)的合成,用^1HNMR研究了新的Tweezer分子和对硝基苯甲酸盐的配位效应,结果表明它兴通过氢键,静电引力和芳环夹心堆叠作用而自动缔合。 相似文献
68.
Direct CI mass spectrometry profiling of fatty acid methyl esters (FAMEs) from in situ thermal hydrolysis/methylation (THM) of whole bacterial cells with tetramethylammonium hydroxide (TMAH) has been demonstrated as a potential method for real time and fieldable detection/identification of microorganisms. Bacillus anthracis (Ames), Yersinia pestis (Nair. Kenya), Vibrio cholerae (E1 Tor), Brucella melitensis (Abortus wild) and Francisella tularensis (LVS vaccine) were profiled by this method during a 10-month period. Repeatability of the in situ FAME data was calculated using one-way analysis of variance (ANOVA) and a t-test. Artificial neural network (ANN) and multivariate statistics of the FAME profiles were also compared for bacterial identification/classification. Equivalent results were obtained with a multivariate rule building expert system (MuRES) and the ANN. However, the ANN analysis required much less computer time and was deemed the best choice for this application. In situ THM FAME profiles of the bacterial samples provided comparable results with those obtained from the Microbial Identification System (MIDI) (Newark, DE) wet chemistry-gas chromatographic based system. 相似文献
69.
Hiroyuki Asanuma Sumie Gotoh Takeshi Ban Makoto Komiyama 《Journal of inclusion phenomena and macrocyclic chemistry》1997,27(3):259-264
Poly(2-vinyl-4,6-diamino-1,3,5-triazine) efficiently binds nucleic acid bases and nucleosides in water by using complementary hydrogen bonding. The binding activity decreases in the order: U, T > A C, G. The corresponding monomer shows virtually no activity, indicating a predominant role of polymer effect for the molecular recognition in water. 相似文献
70.
Kubo T Hosoya K Nomachi M Tanaka N Kaya K 《Analytical and bioanalytical chemistry》2005,382(7):1698-1701
A molecularly imprinted polymer was prepared using a water-soluble crosslinking agent. An ionic complex was utilized as the assembly for the template molecule and the functional monomer, and water as porogenic solvent during preparation of the imprinted polymer. The results of chromatographic evaluations for the prepared polymer suggested that the polymer had much lower hydrophobicity compared with usual octadecyl group bonded silica or the usual molecular imprinted polymer prepared from ethyleneglycol dimethacrylate, and the selective recognition ability for template molecule in the completely aqueous condition. 相似文献