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81.
82.
四氢呋喃(THF)-Na2O-SiO2-Al2O3-H2O体系水热合成的THF-FER沸石,经酸交 换-焙烧脱THF(Ⅰ)或焙烧脱THF-酸交换(Ⅱ)的不同方式处理,均可制得低钠H- FER沸石。经XRD,^27Al与^29Si MAS NMR,低温氮吸附等表征证明,通过1273K高温 的热处理和1073K饱和水蒸气下的水热处理,H-FER沸石骨架保持高度稳定。在高温 水蒸气作用下,Si(2Al)容易从骨架上脱离,而Si(1Al)则保持相对稳定,以(Ⅱ )方法处理,制备的H-FER沸石在水热条件下易产生较多的硅差劲基缺陷。经高温 热和水热处理后,H-FER沸石孔道结构基本保持完美、开放。 相似文献
83.
E. R. Hensema M. E. R. Sena M. H. V. Mulder C. A. Smolders 《Journal of polymer science. Part A, Polymer chemistry》1994,32(3):527-537
New aromatic poly-1,2,4-triazoles and poly-1,3,4-oxadiazoles are studied as thermally stable membrane materials. Various groups were introduced onto the pendant phenyl groups of poly-1,2,4-triazoles. Glass transition temperature, degradation temperature, and cold crystallization behavior were studied as a function of these groups. Cold crystallization appeared to be highly sensitive to macromolecular regularity. The solubility of poly-1,3,4-oxadiazoles was highly improved upon incorporation of 5-t-butylisophthalic, 1,1,3-trimethyl-3-phenylindane, 4,4′-(2,2′-diphenyl) hexafluoro propane, and diphenyl ether groups into the polymeric main chain, whereas the high glass transition temperatures and degradation temperatures typical for aromatic poly-1,3,4-oxadiazoles were maintained. © 1994 John Wiley & Sons, Inc. 相似文献
84.
Poly(3,3-dimethyl oxetane) fractions ranging in number average molecular weights from 18500 to 130000 have been isothermally crystallized from the relaxed melt state in the temperature range from 12 to 44 °C, where only the monoclinic modification is formed. The influence of molecular weight and undercooling in crystallization kinetics has been analyzed. The level of crystallinity is very slightly dependent on molecular weight but the influence of this parameter on the time scale of the crystallization is relatively pronounced. The crystallization temperature coefficient was determined and it was found a constant value of the product of the interfacial energies in the range of molecular weights which has been analyzed. Growth rate measurements were carried out for fraction ¯M
n=130000 and it was found that the temperature coefficients for overall and growth rates are equal. Finally, the comparison of the experimental results for this polymer with those reported for poly(oxetane) shows two main differences: first, the crystallization rate is slower for poly(3,3-dimethyl oxetane) and second, the temperature coefficient is smaller for this polymer. 相似文献
85.
K. Rossmanith 《Monatshefte für Chemie / Chemical Monthly》1995,126(5):543-547
Summary The Separation Factors for Pr/La, Nd/Pr, and Sm/Nd, characterizing the crystallization of ammonium and magnesium double nitrates under practical conditions, were determined analytically and are discussed. They confirm that La and Pr can be separated better by fractional crystallization of ammonium double nitrates, whereas in the presence of Sm the magnesium double nitrates are preferable. 相似文献
86.
《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(1):160-163
This paper describes the preparation of uniform silver nanowires by reducing freshly prepared silver chloride with glucose at 180 °C for 18 hours in the absence of any surfactants or polymers. Scanning electron microscopy studies indicated that the silver nanowires are about 100 nm in diameter and up to 500 μm in length. High‐resolution transmission electron microscopy analyses showed that the silver nanowires grow perpendicularly to the Ag(200) plane. The silver nanowires are believed to grow through a solid–solution–solid process. Some influential factors on the growth of silver nanowires are also discussed. 相似文献
87.
Effect of multi-walled carbon nanotubes on non-isothermal crystallization kinetics of polyamide 6 总被引:2,自引:0,他引:2
The non-isothermal crystallization behaviors of multi-walled carbon nanotubes (MWNTs)/polyamide 6 (PA6) composites were investigated by differential scanning calorimetry (DSC). Three methods, namely, Avrami, Ozawa and Mo, were carried out to analyze the non-isothermal crystallization data. The results showed that the MWNTs in PA6 acted as effective nucleation agents. However the crystallization rate of composites obtained was lower than that of the neat PA6. It is indicated that the presence of MWNTs influenced the mechanism of nucleation and the growth of PA6 crystallites. 相似文献
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