全文获取类型
收费全文 | 23249篇 |
免费 | 3137篇 |
国内免费 | 2847篇 |
专业分类
化学 | 19759篇 |
晶体学 | 657篇 |
力学 | 1468篇 |
综合类 | 267篇 |
数学 | 2180篇 |
物理学 | 4902篇 |
出版年
2024年 | 68篇 |
2023年 | 330篇 |
2022年 | 707篇 |
2021年 | 897篇 |
2020年 | 1188篇 |
2019年 | 942篇 |
2018年 | 876篇 |
2017年 | 852篇 |
2016年 | 1202篇 |
2015年 | 1132篇 |
2014年 | 1233篇 |
2013年 | 2333篇 |
2012年 | 1362篇 |
2011年 | 1299篇 |
2010年 | 1137篇 |
2009年 | 1254篇 |
2008年 | 1256篇 |
2007年 | 1421篇 |
2006年 | 1289篇 |
2005年 | 1148篇 |
2004年 | 1090篇 |
2003年 | 873篇 |
2002年 | 746篇 |
2001年 | 564篇 |
2000年 | 527篇 |
1999年 | 468篇 |
1998年 | 437篇 |
1997年 | 383篇 |
1996年 | 352篇 |
1995年 | 312篇 |
1994年 | 198篇 |
1993年 | 202篇 |
1992年 | 196篇 |
1991年 | 114篇 |
1990年 | 102篇 |
1989年 | 83篇 |
1988年 | 66篇 |
1987年 | 69篇 |
1986年 | 60篇 |
1985年 | 78篇 |
1984年 | 64篇 |
1983年 | 32篇 |
1982年 | 52篇 |
1981年 | 46篇 |
1980年 | 36篇 |
1979年 | 34篇 |
1978年 | 23篇 |
1977年 | 24篇 |
1976年 | 18篇 |
1973年 | 23篇 |
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
91.
Yong LU Hong WANG Ye LIU Ming Yuan HE 《中国化学快报》2006,17(10):1397-1400
Recently, miniature H2 generator to power fuel cells for portable/micro electronic devices and passenger propulsion has been the focus of intense research activities1-3. One of the strategies is to find simple CO-free H2 production with novel microreactor… 相似文献
92.
Yu. D. Perfiliev V. S. Rusakov L. A. Kulikov A. A. Kamnev K. Alkhatib 《Hyperfine Interactions》2006,167(1-3):881-885
To explain line broadening in emission Mössbauer spectra as compared to the corresponding absorber measurements, the model of trapped electrons has been proposed. Auger electrons (emitted, e.g. after electron capture by 57Co or after the converted isomeric transition of 119mSn), as well as secondary electrons, may be trapped in the proximity to the nucleogenic ion. Electrons captured by lattice traps at different distances from the daughter ion induce an asymmetric distribution of quadrupole splitting in the resulting emission spectra, as shown in a few examples. This model is supported by estimates of quadrupole splitting values which may be caused by such trapped electrons located at specified distances from the nucleogenic atom. 相似文献
93.
功能性丙烯酸/MBAM体系共聚产物的研制 总被引:2,自引:0,他引:2
以丙烯酸和MBAM为主要原料,经聚合,合成了一种高性能的具有良好保水性能的聚合产物,其保水量达到750~1000倍.50℃以下有良好的保水性能,28℃以下有极好的保水性能,并研究了工艺条件对该产品性能的影响因素. 相似文献
94.
Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献
95.
A simple method of determining ultra-trace Au in natural water was presented by using graphite furnace atomic absorption spectrophotometry (GFAAS) after in situ enrichment with thiol cotton fiber (TCF). The sample solution was adjusted to pH 1.5-2.0 with HCl, then the water sample was passed through a column packed with 0.10-0.20 g TCF and the flow rate was controlled at 20-40 ml min−1. The effects of interferences, such as complexing and oxidizing agents and other elements adsorbed on TCF were overcome by chemical treatments prior to the desorption of Au. The adsorbed Au was adsorbed with 2.0 ml hot acid, then it was extracted with 1.00 ml methyl isobutylketone (MIBK). For a 5 l water sample, the detection limit of Au is 0.02 ng l−1. The relative standard deviation (R.S.D.) for the determination of 1.44 ng l−1 Au was 9.4%.The method was applied to determine ultra-trace Au both in suspended phase and soluble phase in natural water, the concentrations of total Au in natural water samples range from 0.51 to 67.82 ng l−1. The recovery of added 0.50-6.00 ng l−1 Au was 80-95%. The method is useful in prospecting for Au deposits by means of hydrogeochemical methods. The enrichment is carried out in the field, and then the determination of Au is completed later in the laboratory. 相似文献
96.
S. S. Andreev A. D. Akhsakhalyan M. A. Bibishkin N. I. Chkhalo S. V. Gaponov S. A. Gusev E. B. Kluenkov K. A. Prokhorov N. N. Salashchenko F. Schafers S. Yu. Zuev 《Central European Journal of Physics》2003,1(1):191-209
We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed
at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss
normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing
of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements
for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography
(ψ-13nm) and short period multilayer optics. 相似文献
97.
混凝土动态劈裂拉伸试验的数值模拟 总被引:4,自引:0,他引:4
采用LS-DYNA有限元编码程序,对混凝土的动态劈裂拉伸试验进行了数值模拟,给出了混凝土试样在不同类型加载情况下应力分布之间的差异,证实了动态劈裂拉伸试验的有效性,提出了改进试验方法的若干结论. 相似文献
98.
What features characterize complex system dynamics? Power laws and scale invariance of fluctuations are often taken as the hallmarks of complexity, drawing on analogies with equilibrium critical phenomena. Here we argue that slow, directed dynamics, during which the system's properties change significantly, is fundamental. The underlying dynamics is related to a slow, decelerating but spasmodic release of an intrinsic strain or tension. Time series of a number of appropriate observables can be analyzed to confirm this effect. The strain arises from local frustration. As the strain is released through “quakes,” some system variable undergoes record statistics with accompanying log‐Poisson statistics for the quake event times. We demonstrate these phenomena via two very different systems: a model of magnetic relaxation in type II superconductors and the Tangled Nature model of evolutionary ecology and show how quantitative indications of aging can be found. © 2004 Wiley Periodicals, Inc. Complexity 10: 49–56, 2004 相似文献
99.
A plasma reactor that has a transient traveling arc has been used to study hydrogen in relation to in-flight reduction of metal oxide particles. Experiments were done to determine the nature of the arc and its interaction with the reactor gas. The lifetime of the excited atomic hydrogen was measured and it was found to be more than 4 ms after the arc had ceased. Powders and tablets of oxides were exposed to the pulsed-arc treated hydrogen and found to react much more rapidly and intensely than when exposed to hot molecular hydrogen. The results suggest that atomic hydrogen will exist throughout the volume of such a reactor for a period that is sufficient to reduce particles of FeO, Cr2O3, and TiO2. 相似文献
100.
In this paper, based on the Lame function and Jacobi elliptic function, the perturbation method is appliedto some nonlinear evolution equations to derive their multi-order solutions. 相似文献