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101.
J.M. Weber E. Leber M.-W. Ruf H. Hotop 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(4):587-594
Using a high resolution laser photoelectron attachment method, we have studied the formation of (H
2
O)
q
- (q = 2, 6, 7, 11, 15) cluster ions in collisions of slow free electrons (E = 1-80 meV) and Rydberg electrons (n = 12-300) with water clusters. Resonances at zero energy have been observed, the shapes of which are strongly dependent on
cluster size. The results are discussed in terms of the formation of metastable negative ions.
Received 8 March 1999 相似文献
102.
103.
本文报道了以620.6 ̄665.0nm范围内任意波长激光作用下产生的锂分子高位态紫外扩散带受激辐射的实验结果,在锂分子-原子系统中,由激光双光子激发、并通过碰撞能量转移过程以及多光子电离复合过程使锂分子高位态获得布居,从而得到紫外区扩散受激辐射,该辐射来自较高的某个三重态向低排斥态a^3Σu^+的跃迁的结果。文中对有关的辐射特性及激发机制进行了详细的分析和讨论。 相似文献
104.
Linda Didaoui A. Touabet A. Y. Badjah Hadj Ahmed B. Y. Meklati Werner Engewald 《Journal of separation science》1999,22(10):559-564
In reversed phase liquid chromatography (RP-HPLC), the validity of a multiparametric non-linear least-squares regression iterative method for the determination of the column dead time tM and the regression parameter (slope b), based on the use of alkan-2-ones, alkyl aryl ketones, and 1-nitroalkanes has been evaluated. The determination of tM and b has been extensively studied for two mobile phase systems acetonitrile-water and methanol-water on seven octadecyl-C18 and one octyl C8 analytical columns. The calculated tM and b values were compared with those obtained by Guardino's and Grobler's methods. The influence exerted thereon by the nature of the homologous series, the mobile phase composition, and the packing materials were investigated. 相似文献
105.
On textured n-type silicon substrates for solar cell manufacturing, the relation between light trapping behavior, structural
imperfections, energetic distribution of interface state densities and interface recombination losses were investigated by
applying surface sensitive techniques. The field-modulated surface photovoltage (SPV), in-situ photoluminescence (PL) measurements, total hemispherical UV-NIR-reflectance measurements and electron microscopy (SEM) were
employed to yield detailed information on the influence of wet-chemical treatments on preparation induced micro-roughness
and electronic properties of polished and textured silicon substrates. It was shown that isotropic as well as anisotropic
etching of light trapping structures result in high surface micro-roughness and density of interface states. Removing damaged
surface layers in the nm range by wet-chemical treatments, the density of these states and the related interface recombination
loss can be reduced. In-situ PL measurements were applied to optimise HF-treatment times aimed at undamaged, oxide-free and hydrogen-terminated substrate
surfaces as starting material for subsequent solar cell preparations.
相似文献
106.
基于多组态Dirac-Fock理论方法,利用GRASP92和RATIP以及在此基础上最新发展的RERR06程序,对类氢U91+(1s)离子的辐射复合截面以及辐射退激发过程进行了详细的理论研究.系统地计算了具有确定能量的连续电子被处于基态的类氢U91+(1s)离子俘获到nl (1≤n≤8, 0≤l≤6)轨道形成类氦U90+(1snl)离子的辐射复合截面,并研究了这辐射复合末态退激发谱的相对强度.研究发现,类氢U91+(1s)离子辐射复合到不同轨道的截面随其主量子数的增大而显著减小;同时,辐射复合末态的退激发对Kα谱线的相对强度有重要影响.
关键词:
辐射复合
多组态Dirac-Fock理论方法
辐射退激发 相似文献
107.
This paper presents a new numerical model to investigate the vibro-acoustic behaviour of two laminated glass plates enclosing a thin viscothermal fluid cavity. The aim of this work is to develop an original five layer (two skins plies, two adhesive films and a core ply) laminated plate finite element by mixing Kirchhoff and Mindlin plate’s theory. The formulation is based on the theory that accounts for the transverse shear in the adhesive films and in the core. The acousto-elastic model is established in dimensionless appropriate form including the effects of viscosity and thermal conductivity of fluid and by taking into account the fluid-structure interaction. The discretization of the energy functional by finite element method gives after minimisation a symmetrical coupled matrix system in which the acoustic matrices are frequency dependent. Therefore, an iterative procedure is derived to determine the eigenmodes of the coupled system. The modal approach is adopted to determine the vibro-acoustic system’s response. Then, the validation of the new laminate finite element model is achieved by comparing the sandwich plate results against data obtained from literature. Subsequently, predicted responses, such as the vibration transmissibility and the transmission loss of the coupled system, for a given laminated double glazing under an imposed homogeneous pressure are presented and discussed. Numerical results show the importance of both lamination and viscothermal fluid effects on double glazing vibro-acoustic behaviour. 相似文献
108.
有机场致发光中能带模型与分子理论的讨论 总被引:3,自引:3,他引:0
在有机场致发光中,能带模型及分子理论从20世纪就存在尖锐的矛盾。在分层优化方案中,经SiO2加速后的电子能量可以到达10eV,这足以激发发光材料发光,将分层优化方案应用到有机场致发光材料中。发现了固态阴极射线发光(SSCL),经过对它的交叉证明、普适性的验证,肯定了固态阴极射线的发光确实是在发光二极管,无机及有机场致发光之外的一种完全新型的电场诱导的发光。SSCL的特征是在它的光谱中出现短波发光峰,实验证明长波发光峰的减弱是由于电场离化效应。研究了这种效应出现的电压阈值并和SSCL的短波峰出现的电压相比,发现短波峰的出现是在激子的电场离化之后,从而找出了电子处于局域态与扩展态的分水岭,解释了在有机场致发光中能带模型和分子理论并不矛盾,只是适用的条件不同。激子的离化是随电场强度而渐进的变化,因此会有一个两种过程并存的范围。 相似文献
109.
光系统Ⅱ反应中心包含有2个去镁叶绿素分子(Pheo),2个β胡萝卜素分子(β-Car)和6个叶绿素a分子(Chla).对反应中心的时间分辨荧光光谱表明,两个β-Car具有不同的吸收光谱,吸收峰分别为489 nm(Car489)和507 nm(Car507),Car489靠近吸收峰为667 nm和675 nm的叶绿素a(Chl a),它的主要功能是保护反应中心免受单态氧的破坏,而不能将激发能传递给光化学反应活性的色素分子P680;Car507靠近吸收峰为669 nm的Chl a分子;能够将激发能传递给P680,进行电荷分离.采用全局优化拟合的方法对荧光光谱进行处理,Car489在61 ps时间内将能量传递给Chl a672, 随后传给Chl a677,处于激发态的Chl a677在3 ns衰减到基态;Car507在274 ps时间内将能量传递给P680,P680+Pheo-的电荷重组发生在3.8 ns和16 ns. 相似文献
110.
A simulation method is proposed to model electron–ion recombination in radiation tracks in liquid argon at 87 K. The method
is applied to calculate the electron escape probability in clusters of up to 20 pairs of electrons and cations that represent
a fragment of the track. The results reproduce the basic features of the track recombination in liquid argon observed in experiment. 相似文献