全文获取类型
收费全文 | 17113篇 |
免费 | 2942篇 |
国内免费 | 2193篇 |
专业分类
化学 | 20650篇 |
晶体学 | 50篇 |
力学 | 106篇 |
综合类 | 77篇 |
数学 | 776篇 |
物理学 | 589篇 |
出版年
2024年 | 32篇 |
2023年 | 290篇 |
2022年 | 413篇 |
2021年 | 591篇 |
2020年 | 1167篇 |
2019年 | 819篇 |
2018年 | 793篇 |
2017年 | 585篇 |
2016年 | 1030篇 |
2015年 | 1139篇 |
2014年 | 1274篇 |
2013年 | 1547篇 |
2012年 | 1177篇 |
2011年 | 1210篇 |
2010年 | 981篇 |
2009年 | 1006篇 |
2008年 | 1070篇 |
2007年 | 903篇 |
2006年 | 885篇 |
2005年 | 837篇 |
2004年 | 810篇 |
2003年 | 775篇 |
2002年 | 543篇 |
2001年 | 306篇 |
2000年 | 266篇 |
1999年 | 288篇 |
1998年 | 246篇 |
1997年 | 257篇 |
1996年 | 200篇 |
1995年 | 189篇 |
1994年 | 126篇 |
1993年 | 87篇 |
1992年 | 99篇 |
1991年 | 40篇 |
1990年 | 43篇 |
1989年 | 46篇 |
1988年 | 36篇 |
1987年 | 23篇 |
1986年 | 21篇 |
1985年 | 25篇 |
1984年 | 14篇 |
1983年 | 16篇 |
1982年 | 10篇 |
1981年 | 2篇 |
1980年 | 9篇 |
1979年 | 3篇 |
1977年 | 7篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1969年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
《Magnetic resonance in chemistry : MRC》2003,41(1):61-64
Palladium(II) dichloride reacts with 1,10‐bis(2‐pyrrolyl)‐2,5,9‐triaza‐1,9‐decadiene to give a [Pd(C15H20N5)]Cl complex in which the ligand is four‐coordinated, leaving one pyrrole group dangling. By using COSY, gHSQC, gHMBC connectivities and NOE experiments it has been concluded that one linkage isomer exists in DMSO solution, in spite of the fact that different sets of N atoms of potentially pentadentate ligand might be involved in coordination, and that the three chelate rings in the complex cation are arranged in a sequence: five‐membered, six‐membered, five‐membered which is different from that (5–5–6) found by x‐ray studies on the related [Ni(C15H20N5)]Cl compound. NMR studies allowed an unambiguous assignment of all 1H and 13C NMR resonances for the complex. Results of x‐ray structural analysis of [Pd(C15H20N5)](CH3COO)H2O supported the five‐membered, six‐membered, five‐membered ring sequence in the [Pd(C15H20N5)]+ complex cation and show an E (trans) orientation of the dangling pyrrole group with respect to the metal center. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
33.
34.
在齐次Morrey-Herz空间上建立了高阶交换子~$T^{m}_{b,l}$ 和 ~$M^{m}_{b,l}$的有界性,其中~$T^{m}_{b,l}$ 和 ~$M^{m}_{b,l}$ 是由分数次积分算子和分数次极大算子分别与~BMO($R^{n}$)函数生成的高阶交换子. 相似文献
35.
Michael C. W. Chan Dr. 《化学:亚洲杂志》2008,3(1):18-27
The notion of weak attractive ligand–polymer interactions is introduced, and its potential application, importance, and conceptual links with “cooperative” ligand–substrate interactions are discussed. Synthetic models of weak attractive ligand–polymer interactions are described, in which intramolecular weak C? H???F? C interactions (the existence of which remains contentious) have been detected by NMR spectroscopy and neutron and X‐ray diffraction experiments. These C? H???F? C interactions carry important implications for the design of catalysts for olefin polymerization, because they provide support for the practical feasibility of ortho‐F???Hβ ligand–polymer contacts proposed for living Group 4 fluorinated phenoxyimine catalysts. The notion of weak attractive noncovalent interactions between an “active” ligand and the growing polymer chain is a novel concept in polyolefin catalysis. 相似文献
36.
Mohamed Haouas Amine Harrane Mohamed Belbachir Francis Taulelle 《Journal of Polymer Science.Polymer Physics》2007,45(22):3060-3068
Results of multinuclear MAS NMR spectroscopy are reported for poly (ε‐caprolactone)/maghnite nanocomposite formation, with ε‐caprolactone in situ polymerized in the presence of maghnite, a proton exchanged montmorillonite clay. Exfoliated and intercalated materials with different maghnite loading in the range 3–15 wt % were investigated. 1H NMR evidences Brønsted acid hydroxyl groups in the silicate layers and shows that their broad signal at 7.6 ppm present in the parent clay disappears in the nanocomposite material. 27Al MAS NMR results show that beside the hexacoordinated aluminum signal, two additional peaks corresponding to two different tetrahedral Al sites are present in the clay framework. The NMR signal intensity of only one of them was found to be affected in the nanocomposites compared with the parent maghnite, suggesting that these specific aluminum sites are the reactive ones at the initial stages of the polymerization. However almost no changes occurred in the 29Si NMR spectra, confirming that the polymer grafting, as indicated earlier by atomic force microscopy, took place on the aluminum tetracoordinated sites rather than on the silicon sites. A mechanism of maghnite surface catalyzed polymerization of ε‐caprolactone was proposed, involving Brønsted and Lewis acid sites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3060–3068, 2007 相似文献
37.
Abhimanyu O. Patil Stephen Zushma Robert T. Stibrany Steven P. Rucker Louise M. Wheeler 《Journal of polymer science. Part A, Polymer chemistry》2003,41(13):2095-2106
Novel nickel(II) bisbenzimidazole complexes were prepared via a three‐step synthetic procedure consisting of aniline/diacid condensation, ligand N‐alkylation, and metal complexation. The complexes were characterized by X‐ray crystallography and found to possess a pseudotetrahedral geometry. Upon activation with methylaluminoxane, these nickel bisbenzimidazoles did not polymerize simple olefins (e.g., ethylene, propylene, and 1‐butene) but were found to carry out the rapid and efficient polymerization of norbornene. The polynorbornene products were characterized by gel permeation chromatography/light scattering, 13C NMR, and IR, and their Mark–Houwink and dn/dc parameters were determined. The molecular weights of the polynorbornenes were very high (weight‐average molecular weight = 587,000–797,000 g/mol). 13C NMR suggested that the polymerization occurred via vinyl addition (i.e., a 2,3‐linked polymer); no ring‐opened product was observed. Thermogravimetric analysis indicated that the polynorbornenes were stable up to 400 °C under nitrogen. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2095–2106, 2003 相似文献
38.
SocaltheBerlinskitheoremforplanarquadraticSystem(QS)is:TheoremA[1]SupposethataQShas4finitecriticalpoints(CPs),Ifthequadrila... 相似文献
39.
关于多项式系数微分方程复振荡理论的两个结果 总被引:2,自引:0,他引:2
本文证明了:如果ak-j(j=1,…,k)为多项式,degak-j=nk-j,存在某个ak-s(1≤s≤k)满足:当1≤j<s时,nk-j/j≤nk-s/s;当s<j≤k时,nk-j<nk-s-(j-s).如果F≠0是整函数且满足σ(F)=β<(nk-s+s)/s,那么微分方程f(k)+a 相似文献
40.