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141.
142.
A series of transition metal (Ni, Cu, Pd) complexes derived from macrocyclic tetrabenzo[b,f,j,n] [1,5,9,13]tetraazacyclohexadecine (TAAB) was synthesized and their mesomorphic properties studied by differential scanning calorimetry, polarized optical microscopy and X-ray powder diffraction (XRD). These compounds have eight alkoxy side chains attached around the central molecular core and form disc-like molecules. All the derivatives exhibited columnar mesophases over a wide range of temperature. The mesomorphic behaviour was found to be dependent on the incorporated metal and the carbon length of the alkoxy side chains. The clearing temperatures decreased in the order M = Ni > Pd > Cu; this decrease was probably due to the size of the metal ions. Some derivatives with shorter side chains (n = 10, 12) were room temperature liquid crystals. All compounds were found to exhibit hexagonal columnar (Colh) phases which were confirmed by powder XRD. 相似文献
143.
We report time-resolved transient spectral hole burning of Verneuil-grown 20 ppm and ca. 0.6 ppm ruby (Al2O3:Cr3+) in zero field and low magnetic fields B∥c at 4 K. The hole-burning spectroscopy of the 20 ppm sample implies relatively rapid cross relaxation in the 4A2 ground state on the ∼1 ms timescale both in zero field and in low magnetic fields, B∥c, up to 0.2 T. In the 0.6 ppm sample, side-hole to anti-hole conversion is observed both in zero field and in low magnetic fields. This conversion is caused by population storage in 4A2 ground state levels. Spin-lattice relaxation, on the 200 ms timescale, is directly observed from the time dependence of the resonant hole and anti holes in B∥c, consistent with a very low cross-relaxation rate. However, in zero field cross relaxation in the 4A2 ground state is still a significant relaxation mechanism for the 0.6 ppm sample resulting in hole decay in ∼50 ms. 相似文献
144.
Ruppeiner geometry has been successfully applied in the study of the black hole microstructure by combining with the small–large black hole phase transition, and the potential interactions among the molecular-like constituent degrees of freedom are uncovered. In this paper, we will extend the study to the triple point, where three black hole phases coexist acting as a typical feature of black hole systems quite different from the small–large black hole phase transition. For the six-dimensional charged Gauss–Bonnet anti-de Sitter black hole, we thoroughly investigate the swallow tail behaviors of the Gibbs free energy and the equal area laws. After obtaining the black hole triple point in a complete parameter space, we exhibit its phase structures both in the pressure–temperature and temperature–horizon radius diagrams. Quite different from the liquid–vapor phase transition, a double peak behavior is present in the temperature–horizon radius phase diagram. Then we construct the Ruppeiner geometry and calculate the corresponding normalized curvature scalar. Near the triple point, we observe multiple negatively divergent behaviors. Positive curvature scalar is observed for the small black hole with high temperature, which indicates that the repulsive interaction dominates among the microstructure. Furthermore, we consider the variation of the curvature scalar along the coexisting intermediate and large black hole curves. Combining with the observation for different fluids, the result suggests that this black hole system behaves more like the argon or methane. Our study provides a first and preliminary step towards understanding black hole microstructure near the triple point, as well as uncovering the particular properties of the Gauss–Bonnet gravity. 相似文献
145.
146.
In this study, the optical conductivity of substitutionary doped graphene is investigated in the presence of the Rashba spin orbit coupling (RSOC). Calculations have been performed within the coherent potential approximation (CPA) beyond the Dirac cone approximation. Results of the current study demonstrate that the optical conductivity is increased by increasing the RSOC strength. Meanwhile it was observed that the anisotropy of the band energy results in a considerable anisotropic optical conductivity (AOC) in monolayer graphene. The sign and magnitude of this anisotropic conductivity was shown to be controlled by the external field frequency. It was also shown that the Rashba interaction results in electron–hole asymmetry in monolayer graphene. 相似文献
147.
Shuzheng Yang Qingquan Jiang Huiling Li 《International Journal of Theoretical Physics》2007,46(3):625-636
The strictly thermal spectrum in dragging coordinate system and the tunneling radiation characteristics of stationary axisymmetry
Kerr-Newman de Sitter black hole is studied. The result shows that the tunneling rates at the event and cosmological horizon
are related to the change of Bekenstein-Hawking entropy and that the factual radiation spectrum is not strictly pure thermal.
Thus an exact correction to the Hawking thermal spectrum is present. 相似文献
148.
After taking into account energy conservation and the particle’s self-gravitation interaction, Hawking radiation of the massive
particle as tunneling from Schwarzshild-anti-de Sitter black hole is studied by using Parikh-Wilczek’s semi-classical quantum
tunneling approach. Meanwhile, Hawking radiation as tunneling from the black hole is reexamined by developing Angheben–Nadalini–Vanzo–Zerbini
(ANVZ) covariant method to cover energy conservation and the particle’s self-gravitation interaction. Both the results perfectly
generalize those obtained by Parikh and Wilczek, and show that the tunneling rate is related to the change of Bekenstein-Hawking
entropy, and the factual emission spectrum is not exactly thermal, but satisfies the underlying unitary theory.
PACS: 04.70-s, 9760. Lf. 相似文献
149.
Homonuclear chalcogen–chalcogen bond interactions in complexes pairing YO3 and YHX molecules (Y = S,Se; X = H,Cl, Br,CCH, NC,OH, OCH3): Influence of substitution and cooperativity 下载免费PDF全文
Mehdi D. Esrafili Fariba Mohammadian‐Sabet 《International journal of quantum chemistry》2016,116(7):529-536
MP2/aug‐cc‐pVTZ calculations are performed on complexes of YO3 (Y = S, Se) with a series of electron‐donating chalcogen bases YHX (X = H, Cl, Br, CCH, NC, OH, OCH3). These complexes are formed through the interaction of a positive electrostatic potential region (π‐hole) on the YO3 molecule with the negative region in YHX. Interaction energies of the binary O3Y???YHX complexes are in the range of ?4.37 to ?12.09 kcal/mol. The quantum theory of atoms in molecules and the natural bond orbital analysis were applied to characterize the nature of interactions. It was found that the formation and stability of these binary complexes are ruled mainly by electrostatic effects, although the electron charge transfer from YHX to YO3 unit also seems to play an important role. In addition, mutual influence between the Y???N and Y???Y interactions is studied in the ternary HCN???O3Y???YHX complexes. The results indicate that the formation of a Y???N interaction tends to weaken Y???Y bond in the ternary systems. Although the Y???Y interaction is weaker than the Y???N one, however, both types of interactions seem to compete with each other in the HCN???O3Y???YHX complexes. © 2016 Wiley Periodicals, Inc. 相似文献
150.
采用硅的局部氧化技术以及湿法刻蚀技术,利用2.6 μm的光刻掩模板在n型硅片上形成了栅极孔径为1 μm的场发射阴极的栅极空腔阵列,实现了用大阵点尺寸的栅极掩模板制备较小尺寸栅孔阵列。硅的湿法刻蚀溶液采用各向同性的硝酸和氢氟酸混合溶液,刻蚀后空腔的深度和宽度均随刻蚀时间线性增加。同时,由于刻蚀溶液具有较高的Si/SiO2 刻蚀选择比,栅极孔径随刻蚀时间增大的速度远低于深度和宽度增大的速度,栅极孔径主要取决于掩模的尺寸和氧化层的厚度。通过选择掩模板的尺寸以及氧化层的厚度,采用局部氧化技术和湿法刻蚀技术能够制备出微米或亚微米的场发射阴极的栅极空腔阵列。 相似文献