电子碰撞诱导原子从低激态向高激态弛豫

本文根据空心阴极放电中电子能量分布的物理图象,分析了原子从低激态向高激态弛豫的可能途径。建立高低激态集居数密度增量的关系。讨论高激态集居数密度增量获得可观量的条件。根据此条件分别选取钠原子的基态3s~2S_(1/2)和铜原子的亚稳态4s~2D_(3/2)为与激光共振的下能级,并激发具有较大自发发射几率的3s~2S_(1/2)→3p~2P°_(1/2)(和3p~2P°_(3/2))和4s~2D_(3/2)→4p~2P°_(1/2)跃迁,在远离上能级的高激态上观测到敏化荧光,并精确测得这些态的自发发射系数比值,而在更高激态上没有观测到敏化荧光,表明讨论中提出的条件是合理的。     

Degeneracy in NLP and the development of results motivated by its presence

We study notions of nondegeneracy and several levels of increasing degeneracy from the perspective of the local behavior of a local solution of a nonlinear program when problem parameters are slightly perturbed. Ideal nondegeneracy at a local minimizer is taken to mean satisfaction of second order sufficient conditions, linear independence and strict complimentary slackness. Following a brief exploration of the relationship of these conditions with the classical definition of nondegeneracy in linear programming, we recall a number of optimality and regularity conditions used to attempt to resolve degeneracy and survey results of Fiacco, McCormick, Robinson, Kojima, Gauvin and Janin, Shapiro, Kyparisis and Liu. This overview may be viewed as a structured survey of sensitivity and stability results: the focus is on progressive levels of degeneracy. We note connections of nondegeneracy with the convergence of algorithms and observe the striking parallel between the effects of nondegeneracy and degeneracy on optimality conditions, stability analysis and algorithmic convergence behavior. Although our orientation here is primarily interpretive and noncritical, we conclude that more effort is needed to unify optimality, stability and convergence theory and more results are needed in all three areas for radically degenerate problems.Research supported by National Science Foundation Grant ECS 90-00560 and Grant N00014-89-J-1537 Office of Naval Research     

神光装置放大自发辐射输出特性测量

讨论了大型激光装置放大自发辐射输出的一般特性，给出了神光装置放大自发辐射特性的测量结果。     

Sr1-xLaxTiO3的高温高压合成及XPS研究

 利用高温高压方法合成了有稀土元素La掺杂的钙钛矿氧化物Sr_1-xLa_xTiO₃。XRD测试表明，在x≤0.5时，样品基本为单相，呈立方相；晶胞体积随x的增加而增加，在x=0.4时开始减小。XPS测量发现，样品中存在Ti离子的变价。讨论了Ti离子价态的变化对晶格参数的影响。     

Some proximity and sensitivity results in quadratic integer programming

We show that for any optimal solution for a given separable quadratic integer programming problem there exist an optimal solution for its continuous relaxation such that wheren is the number of variables and(A) is the largest absolute subdeterminant of the integer constraint matrixA. Also for any feasible solutionz, which is not optimal for the separable quadratic integer programming problem, there exists a feasible solution having greater objective function value and with . We further prove, under some additional assumptions, that the distance between a pair of optimal solutions to an integer quadratic programming problem with right hand side vectorsb andb, respectively, depends linearly on b–b₁. Finally the validity of all the results for nonseparable mixed-integer quadratic programs is established. The proximity results obtained in this paper are extensions of some of the results described in Cook et al. (1986) for linear integer programming.This research was partially supported by Natural Sciences and Engineering Research Council of Canada Grant 5-83998.     

A fixed-point equation for the high-temperature phase of discrete lattice spin systems

A fixed-point equation on an infinite-dimensional space is proposed as an alternative to the usual definition of the infinite-volume limit in discrete lattice spin systems in the high-temperature phase. It is argued heuristically that the free energy and correlation functions one obtains by solving this equation agree with the usual definitions of these quantities. A theorem is then proved that says that if a certain finite-volume condition is satisfied, then this fixed-point equation has a solution and the resulting free energy is analytic in the parameters in the Hamiltonian. For particular values of the temperature this finite-volume condition may be checked with the help of a computer. The two-dimensional Ising model is considered as a test case, and it is shown that the finite-volume condition is satisfied for0.77 _critical.     

On the reliability of unsaturated hydraulic conductivity calculated from the moisture retention curve

In comparison with direct measurements of unsaturated hydraulic conductivity, the methods of calculations from the moisture retention curve are attractive for their fast and simple use and low cost. These are the main reasons for their increasing use, mainly in spatial variability studies. On the other hand, it is known that their applicability is limited. The possibility of the use of the retention curve to indirectly determine hydraulic conductivities is analyzed as follows. The theoretical derivation of the relationK(h) – (h) is briefly discussed with regards to potential sources of inaccuracy. The sensitivity of the algorithm forK(h) calculation is studied as a response to possible inaccuracies in the retention curve determination. Conclusions about the usability of calculated hydraulic conductivities are drawn.     

电位滴定法测定模拟高放废液中的游离酸

本文研究了用电位滴定法测定模拟高放废液中游离酸的方法。用草酸钾做络合剂以消除Ｆｅ＾３＋、Ａｌ＾３＋、Ｎｄ＾３＋等多种水解离子的影响，用标准碱直接进行电位滴定，即可快速准确地测定模拟高放废液中游离酸的含量。方法的相对标准偏差为１．８％，标准加入回收率为１００－１０１％，能为放射性废物固化试验提供可靠的分析数据。     

α—氨基酸的快原子轰击质谱

本文研究了１８种α－氨基酸的快原子轰击质谱，发现添加三氟乙酸溶液能显著提高灵敏度，改善谱图。特征碎片主要有中性丢失ＣＯ２Ｈ２，Ｈ２Ｏ，ＮＨ３的离子以及Ｒ＾＋离子。侧链的性质决定了碎片的产生和离子的强弱。     

兖州高硫煤的加氢热解脱硫及脱硫动力学

在加压热天平上，考察了氢气和氮扬气氛下高硫煤的热解脱硫。利用气相色谱在线分析研究了硫化氢氢气的逸出规律。结果表明，加氢热解比氮气下的热解有着更显著的脱友作用，脱硫率可达９０％以上。而且加氢热解下６５％的脱除硫转化为气相硫化氢，而氮气下热解是有８０％的硫转化为液相。