全文获取类型
收费全文 | 38891篇 |
免费 | 5331篇 |
国内免费 | 7698篇 |
专业分类
化学 | 37757篇 |
晶体学 | 606篇 |
力学 | 2582篇 |
综合类 | 338篇 |
数学 | 741篇 |
物理学 | 9896篇 |
出版年
2024年 | 80篇 |
2023年 | 350篇 |
2022年 | 981篇 |
2021年 | 1081篇 |
2020年 | 1416篇 |
2019年 | 1282篇 |
2018年 | 1287篇 |
2017年 | 1443篇 |
2016年 | 1883篇 |
2015年 | 1829篇 |
2014年 | 2266篇 |
2013年 | 3958篇 |
2012年 | 2626篇 |
2011年 | 2752篇 |
2010年 | 2243篇 |
2009年 | 2447篇 |
2008年 | 2415篇 |
2007年 | 2594篇 |
2006年 | 2542篇 |
2005年 | 2404篇 |
2004年 | 2274篇 |
2003年 | 1919篇 |
2002年 | 1449篇 |
2001年 | 1106篇 |
2000年 | 962篇 |
1999年 | 902篇 |
1998年 | 841篇 |
1997年 | 761篇 |
1996年 | 625篇 |
1995年 | 586篇 |
1994年 | 515篇 |
1993年 | 453篇 |
1992年 | 417篇 |
1991年 | 242篇 |
1990年 | 173篇 |
1989年 | 173篇 |
1988年 | 152篇 |
1987年 | 89篇 |
1986年 | 80篇 |
1985年 | 70篇 |
1984年 | 66篇 |
1983年 | 17篇 |
1982年 | 37篇 |
1981年 | 38篇 |
1980年 | 15篇 |
1979年 | 22篇 |
1978年 | 9篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1975年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Qing An WU Zhen Yuan XU Mei ZHENG Dan Qian XU Jun XU Yin Chu SHENCollege of Chemical Engineering Materials Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(7)
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae. 相似文献
52.
53.
54.
以金刚石压腔高压装置为工具,用Ⅱ型金刚石作压砧兼红外窗口,对本征态聚苯胺进行了高压(0~8.4 GPa)就位红外光谱测试。结果表明:在4.8~5.2 GPa压力区间,代表醌环振动的吸收峰相对代表苯环振动的吸收峰变小,表明聚苯胺在此压力区间结构上发生了显著变化,且这种变化是不可逆的。聚苯胺的高压(0~14.5 GPa)电阻测量结果表明:当压力小于7.5 GPa时,电阻随压力升高而显著降低,据此认为聚苯胺为电子性导电物质;在7.5 GPa处电阻出现极小值,然后又缓慢升高,至10 GPa后基本不变。推测聚苯胺电阻极小值是由结构变化引起的。至于红外光谱与电阻测量结果反映聚苯胺结构变化的压力值不一致,可能是由于测试条件不同所致。 相似文献
55.
许多乙酰芳胺类化合物具有优异的生物活性,例如除草剂苯噻草胺,可抑制细胞生长和分裂,防除稻田中禾本科杂草[1];杀菌剂甲霜灵可防治作物霜霉病[2]。本文将具有多种生物活性的嘧啶基团引入到乙酰芳胺结构中[3],合成下列10个未见文献报道的标题化合物Ⅰ,通... 相似文献
56.
Y. Yavin 《Journal of Optimization Theory and Applications》1993,78(1):77-91
Stochastic optimal control techniques are applied to compare the performance of identical medium-range air-to-air missiles which have different thrust-mass profiles. The measure of the performance is the probability of reaching a lock-on-point with a favorable range of guidance and flight parameters, during a fixed time interval [0,t
f
], given that, during the flight, the trajectories of the missile are subjected to a variety of constraints including dynamic pressure constraints. 相似文献
57.
在水热晶化合成一系列NASICON型化合物的基础上,应用固体高分辨31P和29Si MAS NMR,研究了几种NASICON化合物的结构,观察其骨架原子P和Si在结构中的状态及分布,并解释了由于在结构中发生取代作用而引起,Si或P的化学位移的变化. 相似文献
58.
Maria Marques Zhengtian Yu Marvin D. Rausch James C. W. Chien 《Journal of polymer science. Part A, Polymer chemistry》1995,33(16):2787-2793
4-Vinylcyclohexene (VCH) and cyclooctadiene (COD) were investigated as termonomers in EPDM (ethylene/propylene/diene) synthesis by using rac-ethylenebis (1-η5-indenyl) zir-conium dichloride ( 1 ) as a catalyst precursor. Homopolymerizations of VCH, vinylcycloh-exane and cyclohexene were compared. The parameter Kπκp, which is the apparent rate constant for Ziegler-Natta polymerization, is about the same for VCH and vinylcyclohexanebut is 10 times smaller for cyclohexene. Therefore, the linear olefinic double bond is more active than the cyclic internal double bond. VCH reduces ethylene polymerization rate but not propylene polymerization rate in copolymerizations. In terpolymerizations, VCH tends to suppress ethylene incorporation especially at elevated polymerization temperature and Lowers the polymer MW by about two-fold. COD has very low activity as a termonomer. © 1995 John Wiley & Sons, Inc. 相似文献
59.
A. L. Ivanovskii 《Theoretical and Experimental Chemistry》2007,43(1):1-27
The present state of research on the production and modeling of nanostructures based on titanium carbide-a typical representative
of an extensive class of carbides of d-and f-metals-is reviewed. Methods for the synthesis of various Ti-C nanostructures
(molecular clusters, nanocrystallites, nanospheres, nanofibers, nanowires) are examined, and their morphology, atomic structure,
and known physicochemical characteristics are described. Theoretical models of the atomic structure and properties of new
types of nanostructures in the titanium-carbon system (endo-and exohedral titanofullerenes, “hybrid” structures based on carbon
nanotubes, the so-called peapods, nanocables, and a number of others) and the prospects for their application as components
of nanoceramics, hydrogen accumulators, materials for spintronics, etc. are discussed.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 1, pp. 1–23, January–February, 2007. 相似文献
60.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献