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91.
The iodination of chlorinated aromatic compounds using Ag2SO4/I2, AgSbF6/I2, AgBF4/I2, and AgPF6/I2 offers access to iodoarenes that are valuable intermediates in organic synthesis. Specifically, iodination of phenols, anisoles, and anilines with a 3,5-dichloro substitution pattern preferentially yielded the ortho, para, and para iodinated product, respectively. In the case of chlorobenzene and 3-chlorotoluene, AgSbF6/I2, AgBF4/I2, and AgPF6/I2, but not Ag2SO4/I2, selectively introduced the iodine in para position to the chlorine substituent. 相似文献
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93.
The paper described a new ionic liquid, 1,3-dibutylimidazolium hexafluorophosphate, as extraction solvent for extraction and preconcentration of organophosphorus pesticides (fenitrothion, parathion, fenthion and phoxim) from water and fruit samples by dispersive liquid–liquid microextraction combined with high-performance liquid chromatography. The effects of experimental parameters, such as extraction solvent volume, disperser solvent and its volume, extraction and centrifugal time, sample pH, extraction temperature and salt addition, on the extraction efficiency were investigated. An extraction recovery of over 75% and enrichment factor of over 300-fold were obtained under the optimum conditions. The linearity relationship was also observed in the range of 5–1000 μg L−1 with the correlation coefficients (r2) ranging from 0.9988 to 0.9999. Limits of detection were 0.01–0.05 μg L−1 for four analytes. The relative standard deviations at spiking three different concentration levels of 20, 100 and 500 μg L−1 varied from 1.3–2.7, 1.4–1.9 and 1.1–1.7% (n = 7), respectively. Three real samples including tap water, Yellow River water and pear spiked at three concentration levels were analyzed and yielded recoveries ranging from 92.7–109.1, 95.0–108.2 and 91.2–108.1%, respectively. 相似文献
94.
以蒽醌(AQ)作为探针分子,利用激光光解技术研究了咪唑型离子液体1-丁基-3-甲基咪唑六氟化磷([bmim][PF6])与乙腈(MeCN)混合体系中的光化学反应行为.研究结果表明,离子液体[bmim][PF6]自身可与激发三线态的蒽醌分子(3AQ*)进行反应,且表观反应速率常数随着[bmim][PF6]/MeCN比例的不同呈现特殊规律性的变化.在离子液体的摩尔分数(xRTIL)为0.06处观察到一个明显的临界点.当xRTIL<0.06时,表观速率常数随xRTIL的增大而增大;而当xRTIL>0.06时,表观速率常数随xRTIL的增大而减小.文章给出了[bmim][PF6]/MeCN混合体系中激光诱导化学反应的动力学常数,并初步推测了其反应机理,进一步揭示了离子液体[bmim][PF6]的一些新的光化学特性. 相似文献
95.
基于与卡尔-菲休试剂的反应用库仑滴定法测定了六氟磷酸锂中的微量水分.对同一试样的不同进样量(0.5~5.0 mL 共 10 份)按所提出方法对其水分进行了测定,所得结果在26.3~27.9 μg·g-1 之间,平均值为 27.4μg·g-1,相对标准偏差为 0.72%. 相似文献
96.
Fenghui Liu 《应用有机金属化学》2003,17(9):737-738
Thallium(18‐crown‐6) hexafluorophosphate was prepared and its structure was determined by X‐ray diffraction analysis. The Tl+ ion is surrounded by six oxygen atoms of 18‐crown‐6 and three fluorine atoms of , forming a sandwiched structure. If the three Tl–F interactions were considered significant, the coordination number in the title compound would be nine. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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98.
Synthesis of bis-ornithine, a new Cα,α-disubstituted α-amino acid bearing orthogonally protected α and δ amine groups is reported. Bis-ornithine (bisOrn) and dipeptides containing bis-ornithine have been synthesized in solution up to multigram scale. As a first example, one of these compounds Boc-βAla-bisOrn(Alloc)2-OH has been attached to a solid support and used as template for the synthesis of a symmetrical assemblage of peptides. 相似文献
99.
Bilayer lipid membranes(BLM) formed from didodecyldimethylammonium bromide were made on the freshly exposed surface of a galssy carbon(GC) and were demonstrated by the acimpedance spectroscopy.The ion channels of membrane properties induced by PF6^- were studied by the cyclic voltammetric methods.Experimental results indicated that the ion channel of BLM was open in the presence of the PF6^- due to the interaction of PF6^- with the BLM,while it was switched off in the absence of PF6^-.Because the ion channel behavior was affected by the concentration of PF6^-,a sersor for PF6^- can be developed. 相似文献
100.
The effect of LiBF4 on the low-temperature performance of a Li-ion cell was studied by using a 1:1:1 (wt) EC/DMC/DEC mixed solvent. The results
show that the LiBF4-based electrolyte has a 2- to 3-fold lower ionic conductivity and shows rather higher freezing temperature compared with
a LiPF6-based electrolyte. Owing to electrolyte freezing, cycling performance of the Li-ion cell using LiBF4 was significantly decreased when the temperature fell below –20 °C. However, impedance data show that at –20 °C the LiBF4 cell has lower charge-transfer resistance than the LiPF6 cell. In spite of the relatively lower conductivity of the LiBF4-based electrolyte, the cell based on it shows slightly lower polarization and higher capacity in the liquid temperature range
(above –20 °C) of the electrolyte. This fact reveals that ionic conductivity of the electrolytes is not a limitation to the
low-temperature performance of the Li-ion cell. Therefore, LiBF4 may be a good salt for the low-temperature electrolyte of a Li-ion cell if a solvent system that is of low freezing temperature,
high solubility to LiBF4, and good compatibility with a graphite anode can be formulated.
Electronic Publication 相似文献