Preparation of hole transporting polymers by condensation polymerization of triphenylamine derivatives

Hole transporting polymers were prepared by condensation polymerization of triphenylamine and N,N,N',N'‐tetraphenylbenzidine (TPD) having alkyl group with aldehydes in the presence of p‐toluenesulfonic acid. The obtained polymers had molecular weight higher than 10,000 and good film formation ability. It was found that the aromatic amine monomers were connected with aldehyde monomer at the p‐position of the phenyl group. TPD‐aldehyde polymers had almost the same UV absorption and redox potentials as those of TPD monomer indicating that the electronic structure of amine unit did not change by the polymerization. The hole transporting mobility was in the range of 10⁻³‐10⁻⁶cm²/Vs. The electroluminescent device consisting of ITO/TPD polymer/Alq/Mg‐Ag had a maximum luminance of 9000 cd/m².     

三维非谐势阱中玻色－爱因斯坦凝聚的数值计算

本文从G－P平均势场理论出发,探讨了三维球对称非谐势阱中玻色－爱因斯坦凝聚(BEC)的G－P方程;用数值计算方法研究了三维球对称非谐势阱中原子间有相互作用的玻色－爱因斯坦凝聚气体的基态解;分析了非谐振势能项对玻色－爱因斯坦凝聚体的分布、能量和化学势的影响。     

Heterogeneous Photocatalysis of Metronidazole in Aquatic Samples

Metronidazole (MET) is a commonly detected contaminant in the environment. The compound is classified as poorly biodegradable and highly soluble in water. Heterogeneous photocatalysis is the most promoted water purification method due to the possibility of using sunlight and small amounts of a catalyst needed for the process. The aim of this study was to select conditions for photocatalytic removal of metronidazole from aquatic samples. The effect of catalyst type, mass, and irradiance intensity on the efficiency of metronidazole removal was determined. For this purpose, TiO₂, ZnO, ZrO₂, WO₃, PbS, and their mixtures in a mass ratio of 1:1 were used. In this study, the transformation products formed were identified, and the mineralization degree of compound was determined. The efficiency of metronidazole removal depending on the type of catalyst was in the range of 50–95%. The highest MET conversion (95%) combined with a high degree of mineralization (70.3%) was obtained by using a mixture of 12.5 g TiO₂–P25 + PbS (1:1; v/v) and running the process for 60 min at an irradiance of 1000 W m⁻². Four MET degradation products were identified by untargeted analysis, formed by the rearrangement of the metronidazole and the C-C bond breaking.     

COUPLING BETWEEN LAMINAR FILM CONDENSATION AND NATURAL CONVECTION ON OPPOSITE SIDES OF A VERTICAL PLATE

Theoretical analyses which incorporate one-dimensional heat conduction along a plate and transverse heat conduction approximations are presented to predict the net heat transfer between laminar film condensation of a saturated vapour on one side of a vertical plate and boundary layer natural convection on the other side. It is assumed that countercurrent boundary layer flows are formed on the two sides. The governing boundary layer equations of this problem and their corresponding boundary conditions are all cast into dimensionless forms by using a non-similarity transformation. Thus the resulting system of equations can be solved by using the local non-similarity method for the boundary layer equations and a finite difference method for the heat conduction equation of the plate. The plate temperature and the heat flux through the plate are repetitively determined until the solutions for each side of the plate match. The predicted results show that the effect of Pr_c is not negligible for larger values of A* (thermal resistance ratio between natural convecti on side and condensing film side) and the approximation of transverse heat conduction overpredicts the plate temperature for lower values of R_t (thermal resistance ratio between plate and condensing film). However, no significant differences are observed between the two different approximations for higher values of R_t. © by 1997 John Wiley & Sons, Ltd.     

PROGRESSIVE FRAGMENT MODELING OF FAILURE WAVE IN CERAMICS UNDER PLANAR IMPACT LOADING

Polycrystalline ceramics have heterogeneous meso-structures which result in high singularity in stress distribution. Based on this, a progressive fragment model was proposed which describes the failure wave formation and propagation in shocked ceramics. The governing equation of the failure wave was characterized by inelastic bulk strain with material damage and fracture. And the inelastic bulk strain consists of dilatant strain from nucleation and expansion of microcracks and condensed strain from collapse of original pores. Numerical simulation of the free surface velocity was performed in good agreement with planar impact experiments on 92.93％ aluminas at China Academy of Engineering Physics. And the longitudinal, lateral and shear stress histories upon the arrival of the failure wave were predicted, which present the diminished shear strength and lost spall strength in the failed layer.