伴随有水蒸气凝结的烟气对流换热的实验研究

本文通过实验研究了冷凝式燃气热水器中烟气伴随有水蒸气凝结的受迫对流换热过程。着重介绍实验系统、测试方法和对塔板式换热器和肋片板式换热器的实验研究结果。实验表明,有水蒸气凝结时的烟气对流换热系数远大于无凝结时的换热系数,可提高数倍。在冷凝式换热器中,塔板式换热器的换热系数大于肋片板式换热器。     

高效传热管内凝结换热性能及阻力性能的实验研究

本文以ＨＦＣ１３４ａ和ＨＣＦＣ２２为工质对光管及两种不同槽型的强化传热管（ＤＡＥ－２管与ＤＡＥＣ管）的水平管内凝结换热进行了对比实验研究、研究发现,ＤＡＥ－２管平均换热系数比光管提高了１４０％～１７０％,而单位长度阻力损失增加了５０％～１００％,ＤＡＥＣ管平均换热系数比光管提高了１６０％～２００％,同时单位长度阻力损失增加了７０％～１３０％。此外,本文给出了ＤＡＥ－２管和ＤＡＥＣ管平均换热系数及阻力损失的计算关联式,可用于冷凝器设计。     

多孔涂层横向抽吸效应强化膜状凝结换热的研究

研究多孔涂层界面抽吸效应对强化膜状凝结换热的影响。考察了多孔涂层的特性参数对凝液膜厚度和换热系数的影响。与Nusselt理论预示值对照表明,多孔涂层界面抽吸效应是强化膜状凝结换热的重要因素。     

压水堆冷凝回流特性的研究

利用高压汽水两相流试验系统模拟压水堆小破口失水事故中冷凝回流传热模式,进行了传热、流动及不凝结气影响的试验。实验表明：冷凝回流传热是一种十分有效的传热模式,它在很小的一、二次侧温差时就能排放大量堆芯余热。冷凝回流系统在正常情况下流动阻力很小且稳定,但在达到回流流动极限后出现不稳定。不凝结气的存在将大大降低蒸汽发生器的传热能力,但一般情况下,系统能自动增加一次侧压力而达到排除余热的目的。     

On Condensations in the Bogoliubov Weakly Imperfect Bose Gas

We show that condensation in the Bogoliubov weakly imperfect Bose gas (WIBG) may appear in two stages. If interaction is such that the pressure of the WIBG does not coincide with the pressure of the perfect Bose gas (PBG), then the WIBG may manifest two kinds of condensations: nonconventional Bose condensation in zero mode, due to the interaction (the first stage), and conventional (generalized) Bose–Einstein condensation in modes next to the zero mode due to the particle density saturation (the second stage). Otherwise the WIBG manifests only the latter kind of condensation.     

Generalized Two-State Theory for an Atom Laser and Its Interference

We present a generalized two-state theory to study the output coupler for Bose-Einstein condensate atoms and its interference. The results show that the fraction of outcoupled atoms can be adjusted between 0% and 100% by mrying the amplitude of the rf. radiation, and the interference patterns of the two coherent outputs that are coupled out of a double-well trapped potential vary with time. Moreover, we study the influence of atom-atom interactions on the output. In contrast with the case without atom-atom interactions, collapses and revivals appear in the number of the output atoms.     

Bose–Einstein condensation in dilute atomic gases: atomic physics meets condensed matter physics

Bose–Einstein condensed atomic gases are a new class of quantum fluids. They are produced by cooling a dilute atomic gas to nanokelvin temperatures using laser and evaporative cooling techniques. The study of these quantum gases has become an interdisciplinary field of atomic and condensed matter physics. Topics of many-body physics can now be studied with the methods of atomic physics. Many long-standing predictions of the theory of the weakly interacting Bose gas have been verified, including thermodynamic properties of the phase transition and dynamic properties such as shape oscillations and sound propagation. Stimulated light scattering was used to determine the dynamic structure factor both in the phonon and free-particle regime. Atomic Bose condensates show a variety of novel phenomena which include multi-component spinor condensates, magnetic domain formation, miscibility and immiscibility of quantum fluids, and finite-size effects.     

Heterogeneous Catalysis to Drive the Waste-to-Pharma Concept: From Furanics to Active Pharmaceutical Ingredients

A perspective on the use of heterogeneous catalysis to drive the waste-to-pharma concept is provided in this contribution based on the conversion of furanics to active pharmaceutical ingredients (APIs). The provided overview of the concept in this perspective article has been exemplified for two key molecule examples: Ancarolol and Furosemide.     

Brownmillerites CaFeO2.5 and SrFeO2.5 as Catalyst Support for CO Oxidation

The support material can play an important role in oxidation catalysis, notably for CO oxidation. Here, we study two materials of the Brownmillerite family, CaFeO_2.5 and SrFeO_2.5, as one example of a stoichiometric phase (CaFeO_2.5, CFO) and one existing in different modifications (SrFeO_2.75, SrFeO_2.875 and SrFeO₃, SFO). The two materials are synthesized using two synthesis methods, one bottom-up approach via a complexation route and one top-down method (electric arc fusion), allowing to study the impact of the specific surface area on the oxygen mobility and catalytic performance. CO oxidation on ¹⁸O-exchanged materials shows that oxygen from SFO participates in the reaction as soon as the reaction starts, while for CFO, this onset takes place 185 °C after reaction onset. This indicates that the structure of the support material has an impact on the catalytic performance. We report here on significant differences in the catalytic activity linked to long-term stability of CFO and SFO, which is an important parameter not only for possible applications, but equally to better understand the mechanism of the catalytic activity itself.     

聚氨酯软质塑料的合成工艺

聚氨酯(polyurethane)是主链上含有重复氨基甲酸酯基团聚合物的总称,由聚二异氰酸酯或多异氰酸酯与多羟基化合物加聚而得。其合成工艺投资大,耗电多,浪费大。本文的合成路线则较合理地解决这些问题。