全文获取类型
收费全文 | 4544篇 |
免费 | 765篇 |
国内免费 | 558篇 |
专业分类
化学 | 4736篇 |
晶体学 | 10篇 |
力学 | 215篇 |
综合类 | 32篇 |
数学 | 151篇 |
物理学 | 723篇 |
出版年
2024年 | 5篇 |
2023年 | 44篇 |
2022年 | 101篇 |
2021年 | 121篇 |
2020年 | 253篇 |
2019年 | 205篇 |
2018年 | 218篇 |
2017年 | 168篇 |
2016年 | 250篇 |
2015年 | 268篇 |
2014年 | 313篇 |
2013年 | 557篇 |
2012年 | 259篇 |
2011年 | 314篇 |
2010年 | 246篇 |
2009年 | 234篇 |
2008年 | 267篇 |
2007年 | 275篇 |
2006年 | 256篇 |
2005年 | 198篇 |
2004年 | 201篇 |
2003年 | 208篇 |
2002年 | 153篇 |
2001年 | 129篇 |
2000年 | 95篇 |
1999年 | 72篇 |
1998年 | 74篇 |
1997年 | 73篇 |
1996年 | 45篇 |
1995年 | 34篇 |
1994年 | 45篇 |
1993年 | 46篇 |
1992年 | 31篇 |
1991年 | 14篇 |
1990年 | 16篇 |
1989年 | 12篇 |
1988年 | 12篇 |
1987年 | 6篇 |
1986年 | 13篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1970年 | 4篇 |
排序方式: 共有5867条查询结果,搜索用时 15 毫秒
81.
Varughese M. Alexander 《Tetrahedron letters》2005,46(40):6957-6959
Bismuth(III) nitrate pentahydrate is found to be an efficient catalyst for the Pechmann condensation reaction of phenols and β-ketoesters under solvent-free conditions. The reaction protocol is simple and is followed by aqueous work-up leading to the formation of the corresponding coumarin derivatives in good yield and high purity. 相似文献
82.
L. Leite D. Jansone M. Fleisher H. Kazhoka J. Popelis N. Veretennikova I. Shestakova I. Domracheva E. Lukevics 《Chemistry of Heterocyclic Compounds》2004,40(6):715-724
The respective 4-(arylvinyl)lactones and compounds of the Michael adduct type were synthesized by the condensation of substituted benzaldehydes with 3-cyano-4,6,6-trimethyl-5,6-dihydro-2-pyranone in the presence of catalytic amounts of sodium hydroxide. It was shown by the semiempirical AM1 method that the indicated products can be formed through one and the same intermediate compound. Some of the synthesized phenylvinyl-5,6-dihydro-2-pyranones have a cytotoxic effect, and this corresponds to the prognosis of the OREX expert system. 相似文献
83.
Condensation of propanal with cyanothioacetamide and morpholine gave 3-cyano-4-ethyl-5-methyl-6-morpholino-2-piperidone, the
structure of which was studied by X-ray analysis. Reaction of propanal with cyanothioacetamides and cycloalkanone enamines
gave 3-cyano-4-ethyl-2,5,6,7-tetrahydropyrindin-2(1H)-one and 3-cyano-4-ethyl-5,6-hexamethylenepyridine-2(1H)-thione. The
latter was used for the preparation of substituted 2-benzyloxycarbonylmethylthiopyridine and 3-amino-2-benzyloxycarbonylthieno[2,3-b]pyridine.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1053–1059, July, 2005. 相似文献
84.
85.
A model is presented that describes quantitatively the condensation of analytes in pico- and nanogram masses sampled with electrothermal vaporization (ETV). It presumes that the analyte vapor condensation of such low amounts occurs mainly heterogeneously, predominantly on growing carbon particulates originating from the graphite furnace before the analyte vapor achieves saturation via cooling. The model regards the coagulation of carbon particles and the diffusion of analyte atoms. The criterion whether or not an analyte atom sticks to a colliding particle is chosen as a function depending on its temperature and on the common GFAAS pretreatment temperatures. Heterogeneous condensation of six analytes with different volatilities, Ag, Cu, Fe, Ni, Mn, and Pb, is calculated for the ETV unit with an axially focusing convection upstream described in Part I. Modifier effects are taken into account. The results are compared to measured data. 相似文献
86.
STUDY ON 1-HEXENE POLYMERIZATION BASED ON ZIEGLER-NATTA CATALYSTS WITH DOPED SUPPORT 总被引:1,自引:0,他引:1
XueJiang Zhi-qiangFan 《高分子科学》2004,(4):305-308
A series of Ti/Mg supported catalysts are prepared by using ball-milled mixtures of MgCl2-ethanol adducts and NaCl as supports, and 1-hexene polymerizations catalyzed by the novel catalysts are studied. It is found that the molecular weight distribution of poly(1-hexene) becomes apparently narrower when catalysts with doped supports are used, indicating that changing the structure of the support is an effective way to regulate the active center distribution of heterogeneous Ziegler-Natta catalyst. 相似文献
87.
Submicron-size monodisperse polystyrene/polyglutaraldehyde (PS/PGLA) composite particles having aldehyde groups at the surfaces were produced by the seeded aldol condensation polymerization of glutaraldehyde at various temperatures of 040°C. Since a part of aldehyde groups was consumed by the Cannizzaro reaction (hemiacetal formation) as a intermolecular reaction of PGLA, the amount of aldehyde groups on PS/PGLA composite particles was varied by the competition between the aldol condensation reaction and the Cannizzaro reaction at the various temperatures.Part CXXXIX of the series Studies on Suspension and Emulsion 相似文献
88.
Cimpeanu V Parvulescu VI Amorós P Beltrán D Thompson JM Hardacre C 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(18):4640-4646
Heterogeneous catalytic oxidation of a series of thioethers (2-thiomethylpyrimidine, 2-thiomethyl-4,6-dimethyl-pyrimidine, 2-thiobenzylpyrimidine, 2-thiobenzyl-4,6-dimethylpyrimidine, thioanisole, and n-heptyl methyl sulfide) was performed in ionic liquids by using MCM-41 and UVM-type mesoporous catalysts containing Ti, or Ti and Ge. A range of triflate, tetrafluoroborate, trifluoroacetate, lactate and bis(trifluoromethanesulfonyl)imide-based ionic liquids were used. The oxidations were carried out by using anhydrous hydrogen peroxide or the urea-hydrogen peroxide adduct and showed that ionic liquids are very effective solvents, achieving greater reactivity and selectivity than reactions performed in dioxane. The effects of halide and acid impurities on the reactions were also investigated. Recycling experiments on catalysts were carried out in order to evaluate Ti leaching and its effect on activity and selectivity. 相似文献
89.
多相催化反应原位红外系统及其应用 总被引:1,自引:0,他引:1
设计和建立了一套能耐高温的用于多相催化反应研究的原位红外系统,反应温度从室温到1150K,系统真空为1.0*10^5-1.0-10^-4Pa,红外光谱检测范围为4800-200cm^-1。此系统扩展了原仪器的功能,提高了仪器利用率和效率。 相似文献
90.