全文获取类型
收费全文 | 2769篇 |
免费 | 564篇 |
国内免费 | 257篇 |
专业分类
化学 | 3123篇 |
晶体学 | 8篇 |
力学 | 130篇 |
综合类 | 19篇 |
数学 | 109篇 |
物理学 | 201篇 |
出版年
2024年 | 6篇 |
2023年 | 42篇 |
2022年 | 103篇 |
2021年 | 100篇 |
2020年 | 218篇 |
2019年 | 168篇 |
2018年 | 180篇 |
2017年 | 117篇 |
2016年 | 202篇 |
2015年 | 202篇 |
2014年 | 216篇 |
2013年 | 299篇 |
2012年 | 190篇 |
2011年 | 185篇 |
2010年 | 165篇 |
2009年 | 155篇 |
2008年 | 157篇 |
2007年 | 134篇 |
2006年 | 149篇 |
2005年 | 98篇 |
2004年 | 101篇 |
2003年 | 98篇 |
2002年 | 61篇 |
2001年 | 52篇 |
2000年 | 25篇 |
1999年 | 16篇 |
1998年 | 17篇 |
1997年 | 33篇 |
1996年 | 13篇 |
1995年 | 10篇 |
1994年 | 14篇 |
1993年 | 14篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 3篇 |
排序方式: 共有3590条查询结果,搜索用时 15 毫秒
61.
The discharge of diverse pollutants has led to a complex water environment and posed a huge health threat to humans and animals. Self-propelled micromotors have recently attracted considerable attention for efficient water remediation due to their strong localized mass transfer effect. However, a single functionalized component is difficult to tackle with multiple contaminants and requires to combine different decontamination effects together. Here, we introduced a multifunctional micromotor to implement the adsorption and degradation roles simultaneously by integrating the poly(aspartic acid) (PASP) adsorbent with a MnO2-based catalyst. The as-prepared micromotors are well propelled in contaminated waters by MnO2 catalyzing hydrogen peroxide. In addition, the catalytic ramsdellite MnO2(R-MnO2) inner layer is decorated with Fe2O3 nanoparticles to improve their catalytic performance, contributing to an excellent degradation ability with 90% tetracycline (TC) removal in 50 minutes by enhanced Fenton-like reactions. Combining the attractive adsorption capability of poly (aspartic acid) (PASP), the composite micromotors offer an efficient removal of heavy metal ions in short time. Moreover, the designed micromotors are able to simultaneously remove antibiotic and heavy metals in mixed contaminants circumstance just in single treatment. This multifunctional micromotor with distinctive decontamination ability exhibits a promising prospective in treating multiple pollutants in the future. 相似文献
62.
In this paper, a novel improvement in the catalytic Fenton reaction system named MHACF-NH2-MIL-101(Cr) was constructed based on H2 and Pd/NH2-MIL-101(Cr). The improved system would result in an accelerated reduction in FeIII, and provide a continuous and fast degradation efficiency of the 10 mg L-1 4-chlorophenol which was the model contaminant by using only trace level FeII. The activity of Pd/NH2-MIL-101(Cr) decreased from 100% to about 35% gradually during the six consecutive reaction cycles of 18 h. That could be attributed to the irreversible structural damage of NH2-MIL-101(Cr). 相似文献
63.
多相催化反应原位红外系统及其应用 总被引:1,自引:0,他引:1
设计和建立了一套能耐高温的用于多相催化反应研究的原位红外系统,反应温度从室温到1150K,系统真空为1.0*10^5-1.0-10^-4Pa,红外光谱检测范围为4800-200cm^-1。此系统扩展了原仪器的功能,提高了仪器利用率和效率。 相似文献
64.
65.
Isabel W. C. E. Arends Roger A. Sheldon Martin Wallau Ulf Schuchardt 《Angewandte Chemie (International ed. in English)》1997,36(11):1144-1163
Zeolites are viewed by some as the “philosopher's stone” of modern chemistry.[1] They are more or less indispensable in oil refining and petrochemicals manufacture where they are widely applied as solid acid catalysts. More recently attention has been focused on their use in the manufacture of fine chemicals. The synthetic utility of zeolites and related molecular sieves (zeotypes) has been considerably extended by the incorporation of redox metals into their frameworks. The resulting redox molecular sieves catalyze a variety of selective oxidations under mild conditions in the liquid phase. Their structural diversity–including variation of the redox metal, incorporation of metal complexes, and the size and polarity of the micropores–provides the possibility of designing tailor-made solid catalysts (“mineral enzymes”) for liquid-phase oxidations with clean oxidants such as O2, H2O2, and RO2H. Hence, they have enormous potential in industrial organic synthesis as environmentally friendly alternatives to traditional oxidations employing inorganic oxidants in stoichiometric amounts. A primary aim of this review is to familiarize organic chemists with the synthetic potential of redox molecular sieves. An outline of their synthesis, structures, and chemical properties, highlighting their unique advantages, is followed by a discussion of general (mechanistic) features that influence the choice of a suitable catalyst for a particular type of oxidation. The main part of the review deals with the oxidation of various substrates of synthetic interest–such as alkanes, alkenes, (alkyl)arenes, alcohols, and amines–and emphasizes the advantages of redox molecular sieves (including selectivity and stability) over their homogeneous counterparts. New directions towards truly biomimetic solid catalysts, for example zeolite-encapsulated chiral metal complexes as heterogeneous catalysts for asymmetric oxidations, are high-lighted. 相似文献
66.
67.
68.
Rafael Luque Zeid A. ALOthman Alina M. Balu Leonid Voskressensky 《Molecules (Basel, Switzerland)》2021,26(21)
A perspective on the use of heterogeneous catalysis to drive the waste-to-pharma concept is provided in this contribution based on the conversion of furanics to active pharmaceutical ingredients (APIs). The provided overview of the concept in this perspective article has been exemplified for two key molecule examples: Ancarolol and Furosemide. 相似文献
69.
Conventional methods generally used to synthesize heterogeneous photocatalysts have some drawbacks, mainly the difficult control/preservation of catalysts’ morphology, size or structure, which strongly affect the photocatalytic activity. Supercritical carbon dioxide (scCO2)-assisted techniques have recently been shown to be a promising approach to overcome these limitations, which are still a challenge. In addition, compared to traditional methods, these innovative techniques permit the synthesis of high-performance photocatalysts by reducing the use of toxic and polluting solvents and, consequently, the environmental impact of long-term catalyst preparation. Specifically, the versatility of scCO2 allows to prepare catalysts with different structures (e.g., nanoparticles or metal-loaded supports) by several supercritical processes for the photocatalytic degradation of various compounds. This is the first updated review on the use of scCO2-assisted techniques for photocatalytic applications. We hope this review provides useful information on different approaches and future perspectives. 相似文献
70.