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951.
Blends of poly(ε‐caprolactone) (PCL) with zein (PCL/zein) in different proportions (100/0, 75/25, 50/50, 25/75 and 0/100 wt% containing 5 wt% glycerol) were compared based on their mechanical properties (tensile strength, elongation at break, and Young's modulus), and on their thermal properties, the latter determined by thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMTA). The morphology of the materials was studied by scanning electron microscopy (SEM). Blends of PCL/zein showed reduced tensile strength and elongation at break, but increased Young's modulus compared to the pure polymers, in agreement with the DMTA and SEM results. These findings indicated that PCL and zein were incompatible. TGA showed that the thermal stability was enhanced by the addition of zein to PCL, whereas SEM showed a poor interfacial interaction between the polymers. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
952.
An end-channel amperometric detector with a guide tube for working electrode was designed and integrated on a home-made glass microchip. The guide tube was directly patterned and fabricated at the end of the detection reservoir, which made the fixation and alignment of working electrode relatively easy. The fabrication was carried out in a two-step etching process. A 30 μm carbon fiber microdisk electrode and Pt cathode were also integrated onto the amperometric detector. The baseline separation of dopamine (DA), catechol (CA) and epinephrine (EP) was achieved within 80 s. Relative standard deviations of not more than 5.2% were obtained for both peak currents and migration times of DA and CA (n=5). Using standard adding method, DA in tLrine and plasma samples was detected. The recoveries were in the range of 83%—103%. 相似文献
953.
Recycling Chiral Organocatalyst (4S)-Phenoxy-(S)-proline for Direct Asymmetric Aldol Reaction in Ionic Liquid (bmim)PF6 总被引:1,自引:0,他引:1
Room temperature ionic liquid (bmim)PF6 was evaluated for recycling an organocatalyst (4S)-phenoxy-(S)-proline for direct asymmetric aldol reactions. The desired aldol products were obtained with good yields up to 93.2% and enantioselectivities up to 88.5%, and isolation of the products by simple extraction allowed recycling the ionic liquid containing the immobilized catalyst in subsequent reactions without significant decrease of yields and enantioselectivities. 相似文献
954.
K. Masenelli‐Varlot E. Reynaud G. Vigier J. Varlet 《Journal of Polymer Science.Polymer Physics》2002,40(3):272-283
Intercalated and exfoliated nanocomposites were prepared by extrusion and injection of polyamide‐6 and highly swollen or slightly swollen montmorillonite, respectively. The microstructure of the nanocomposites has been studied previously. In this article, we investigated the influence of the preferential orientation of the montmorillonite sheets on the mechanical properties of the nanocomposites. Dynamic mechanical analysis and tensile tests showed that the elastic modulus depends mainly on the filler loading. A parallel coupling could well account for the behavior of the nanocomposites. The calculated elastic and storage moduli of montmorillonite were set to 140 and 40 GPa, respectively. Compression tests were performed to study the anisotropy of the mechanical properties. The elastic modulus and flow strain were sensitive to the filler orientation. A Tandon–Weng approach was applied to consider the geometry of the filler. In all low‐deformation tests, no significant difference between intercalated and exfoliated systems was observed. Finally, the influence of the dispersion and exfoliation state of the filler on the ultimate properties of the nanocomposites (tensile tests) is discussed. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 272–283, 2002 相似文献
955.
V. P. Korolev 《Journal of Structural Chemistry》2006,47(6):1084-1090
A new equation is suggested to define the temperature dependence of the Gibbs energy of hydration of hydrophobic substances: ΔG 0 = b 0 + b 1 T + b 2lnT. According to this equation, the hydration heat capacity is in inverse proportion to temperature. Consistent values of hydration heat capacity of nonpolar solutes have been obtained for different temperatures using data on solubility and dissolution enthalpy. The contributions of the hydrocarbon radicals and OH group to the heat capacity of hydration of the compounds were found for the temperature range 248–373 K. The hydration heat capacity of the hydroxyl group has a weak dependence on temperature and increases by only 12 J/(mol·K) in the specified temperature interval. Changes in the hydration entropy of hydrophobic and OH groups are calculated for the temperature increasing from 248 K to 373 K. 相似文献
956.
Benedetti M Tamasi G Cini R Natile G 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(24):6122-6132
The use of a sterically hindered diamine ligand (Me(4)DACH) has allowed for the first time, the isolation and characterization, both in the solid state (X-ray crystallography) and in solution (circular dichroism), of pure DeltaHT rotamers of [Pt(Me(4)dach)(5'-GMP)(2)] (compounds 1 and 2 for R,R and S,S configurations of the Me(4)DACH ligand, respectively). Comparison of the CD spectra obtained for each rotamer, which differ only in the chirality of the Me(4)DACH ligand (R,R or S,S) or in the chirality of the HT conformation (Delta or Lambda), allowed us to conclude that, in the 200-350 nm range, the contributions to the overall CD spectrum that stem from diamine chirality and diamine-induced chirality of platinum d--d transitions or from sugar chirality are negligible relative to the exciton chiral coupling that occurs for pi-pi* transitions of the cis guanines. Accurate molecular structures of 1.10 D(2)O and 2.14 D(2)O (conventional crystallographic agreement indexes R(1) convergent to 2.07 % and 2.18 %, respectively) revealed that the crystallized rotamers have a DeltaHT conformation that is in agreement with all previously reported X-ray structures of [Pt(diamine)(nucleos(t)ide)(2)] complexes. This conformation allows the 5'-phosphate to be located in proximity to the Me(4)DACH ligand so that (P)O...HC(N) hydrogen-bond interactions exists in both complexes. For both structures, the canting of the guanine planes on the coordination plane is right-handed (R; canting angle (Phi) of 80.9 degrees and 73.2 degrees, respectively); this indicates that the canting direction is driven by the HT conformation chirality (Delta for both compounds) and not by the chirality of the carrier ligand (different for the two compounds). Density functional theory analysis of the conformational space as a function of Phi indicated a good agreement between the computed and experimental structures. The increase in energy for Phi values below 65 degrees and 55 degrees (for 1 and 2, respectively) is mainly due to the short intramolecular contacts between C(8)H and the cis N-Me groups on the same side of the platinum coordination plane. 相似文献
957.
Krishna Gopal Dongol M. Cristina Melo e Silva Kouki Matsubara Taisuke Matsumoto Shuntaro Mataka Thies Thiemann 《无机化学与普通化学杂志》2003,629(6):945-947
The preparation of two η6‐estra‐1, 3, 5(10), 6‐tetraene tricarbonylchromium complexes 4 and 6 are described. In both cases only one stereoisomer can be isolated, in contrast to other estrane‐tricarbonylchromium complexes, where complexations are non‐stereoselective. X‐ray crystal structural analysis of 4 discloses that only the more sterically hindered β‐facial isomer is formed. It is assumed that the 6, 7‐olefinic moiety exerts a directive influence on the complexation. 相似文献
958.
ValeryN. Kalinin IgorV. Shishkov SergeyK. Moiseev ElviraE. Shults GenrikhA. Tolstikov NataliaI. Sosnina PavelV. Petrovskii KonstantinA. Lyssenko Helmut Schmidhammer 《Helvetica chimica acta》2006,89(5):861-869
In a search for starting materials for the preparation of 7,8‐fused morphine alkaloid derivatives, 8‐[(1E‐2‐phenylethenyl]codeinone dimethyl ketal ( 4 ) and 8‐[(1E‐2‐phenylethenyl]codeine ( 5 ) were prepared. These dienes were used as substrates in the Diels–Alder reactions. Compound 5 formed the ‘normal’ adduct 12 with N‐phenylmaleimide, while compound 4 behaved in reactions with dienophiles as the ‘masked’ diene 11 , a 8‐[(1E)‐2‐phenylethenyl]‐substituted thebaine, yielding the corresponding 19‐substituted 6,14‐endo‐etheno‐6,7,8,14‐tetrahydrothebaines. Specifically, reaction of 4 with methyl vinyl ketone gave rise to 19‐[(1E)‐phenylethenyl]thevinone ( 14 ) whose structure was elucidated by an X‐ray diffraction analysis. The thebaine derivative 11 was also prepared from 4 . 相似文献
959.
《Electroanalysis》2006,18(23):2361-2368
The oxidation of benzophenone‐4 (2‐hydroxy‐4‐methoxybenzophenone‐5‐sulfonic acid) at glassy carbon electrode gives rise to stable redox active electropolymerized film during repetitive potential cycling between 0 to 1.3 V (Ag/AgCl). Cyclic voltammogram of poly(benzophenone‐4) film shows a redox couple with well‐defined peaks. The redox response of the modified electrode was found to be depending on the pH of the contacting solution. The peak potentials were shifted to a less positive region with increasing pH and the dependence of the peak potential was found to be 51 mV/pH. The electrocatalytic behavior of poly(benzophenone‐4) film modified electrode towards oxidation of dopamine, ascorbic acid and reduction of nitrite was investigated. The oxidation of dopamine and ascorbic acid occurred at less positive potential on poly(benzophenone‐4) film compared to bare glassy carbon electrode. For dopamine, the overpotential was reduced about 180 mV. Feasibility of utilizing poly(benzophenone‐4) film coated electrode in analytical estimation of dopamine, ascorbic acid and nitrite was also demonstrated. 相似文献
960.
《Electroanalysis》2005,17(20):1861-1864
Electrochemical study of barley grain lipid‐transfer protein (LTP) revealed that it may belong to the metal‐binding protein class. Using differential pulse polarography the presence of Cu(II) and Zn(II) ions in the native LTP structure was proved, as well as its affinity for binding Ni(II) ion. Application of a more sensitive electroanalytical technique, such as anodic stripping voltammetry with analyte preconcentration, revealed the presence of Pb(II) and Cd(II) ions and also enabled the following Hg(II) ion binding. Possible biological role of LTP in plant stress response and its contribution to barley phytoextraction potential are discussed. 相似文献