Rotational spectrum of the Ar–dimethyl sulfide complex

The rotational spectra of three isotopomers of the Ar–dimethyl sulfide (DMS) complex – normal, ³⁴S, and ¹³C species – were measured in the frequency region from 3.7 up to 24.1 GHz by Fourier transform microwave spectroscopy. The normal species yielded 43 a-type and 79 c-type transitions. No Ar tunneling splitting was observed, while many transitions were split by the internal rotation of the two methyl tops of the DMS unit. In cases where the K-type splitting was close to that due to methyl internal-rotation, several forbidden transitions were observed that followed b-type selection rules. All of the observed transition frequencies were analyzed simultaneously using a phenomenological Hamiltonian also used in previously published work describing the Ar–dimethyl ether (DME) and Ne–DME complexes. The rotational and centrifugal distortion constants and the potential barrier height to methyl-top internal rotation, V₃, were determined. The rotational constants were consistent with an Ar–DMS center of mass (cm) distance of 3.796 (3) Å and a S–cm–Ar angle of 104.8 (2)°. The V₃ potential barrier obtained, 736.17 (32) cm⁻¹, was 97.8% of the DMS monomer barrier. By assuming a Lennard–Jones-type potential, the dissociation energy was estimated to be 2.4 kJ mol⁻¹, which was close to the value for Ar–DME, 2.5 kJ mol⁻¹.     

野生植物菊状千里光营养成分的测定

对野生植物菊状千里光的营养成分进行测定 ,结果表明 ,菊状千里光中至少含有 17种氨基酸、多种营养成分、丰富的矿物元素、维生素及 β-胡萝卜素。为开发利用植物资源提供了科学依据。     

Super S_(25)与New S_(25)光电阴极的光谱响应特性的数值模拟

根据多碱光电阴极的光谱响应理论表达式 ,对荷兰DEP公司和日本Hamamatsu公司美国分公司开发的两种SuperS2 5阴极的光谱响应曲线进行了理论模拟 ,得到了这些阴极的有关特性参量 ,并通过对模拟结果的分析以及与美国夜视实验室研制的NewS2 5光电阴极特性的比较 ,揭示了两种SuperS2 5光电阴极内在机理和可能采用的工艺处理方法 ,对多碱光电阴极的理论研究和实际操作具有指导意义     

光谱探针猩红S与牛血清白蛋白结合的发光光谱

利用荧光光谱和紫外吸收光谱,详细研究了不同温度下猩红S(PS)与牛血清白蛋白(BSA)的结合反应,发现PS对BSA的内源性荧光具有较强的猝灭作用,其猝灭机理属于静态猝灭,由此求得PS与BSA间的结合常数、结合位点数及热力学参数等.结果表明:PS与BSA之间形成了1:1稳定复合物,它们之间的作用力主要是静电引力.根据Fo...     

Site-specific ϕ- and ψ-torsion angle determination in a uniformly/extensively 13C- and 15N-labeled peptide

A solid-state rotational-echo double resonance (REDOR) NMR method was introduced to identify the ?- and ψ-torsion angle from a ¹H–¹⁵N or ¹H–¹³C′ spin system of alanine-like residues in a selectively, uniformly, or extensively ¹⁵N-/¹³C-labeled peptide. When a C_α(i) or a ¹⁵N peak is site-specifically obtainable in the NMR spectrum of a uniformly ¹⁵N/¹³C-labeled sample system, the ψ- or ?-torsion angle specified by the conformational structure of peptide geometry involving ¹⁵N(i)–¹H_αi–¹⁵N(i + 1) or ¹³C′(i − 1)–¹H^Ni–¹³C′(i) spin system can be identified based on ¹³C_α- or ¹⁵N-detected ¹H_α–¹⁵N or ¹H_N–¹³C REDOR experiment. This method will conveniently be utilized to identify major secondary motifs, such as α-helix, β-sheet, and β-turn, from a uniformly ¹⁵N-/¹³C-labled peptide sample system. When tested on a ¹³C-/¹⁵N-labeled model system of a three amino acid peptide Gly–[U–¹³C, ¹⁵N]Ala–[U–¹³C, ¹⁵N]Leu, the ψ-angle of alanine obtained experimentally, ψ = −40 ± 30°, agreed reasonably well with the X-ray determined angle, ψ = −39°.     

基于GaSe和GaSe0.7S0.3单晶的单脉冲CO2激光倍频器

描述了使用电感储能发生器和半导体转换开关泵浦的工作波长为10.6μm的高效CO2激光器。给出了激光泵浦的非线性晶体GaSe和GaSe0.7S0.3的二次谐波振荡的实验数据和理论估算结果。结果显示,GaSe晶体在输入能量为180mJ时,最大能量转换效率为0.38%,倍频激光的峰值功率为8 kW。     

Yb:FAP和Yb:C_3S_2-FAP晶体光谱的温度特性和选择激发

报导了Yb :FAP和Yb :C3S2 _FAP晶体在不同温度下的吸收光谱和荧光光谱实验结果 ,研究发现由于电子_声子近共振耦合作用 ,Yb :FAP和Yb :C3S2 _FAP晶体均存在有明显的振动谱 ,Yb :FAP晶体的零声子线在低温下还劈裂为相差 10cm- 1 的两条线 .采用激光选择激发技术研究了Yb3 离子在FAP和C3S2 _FAP晶体中的格位特征 ,结果表明Yb3 离子在这两种基质中都只占据Ca(Ⅱ )格位 ,但由于CaF2 的挥发 ,导致了Ca(Ⅱ )格位的局部畸变 .     

相对论性无自旋氢原子的散射态

研究获得了相对论性无自旋氢原子散射态的精确解,给出了精确的相移表达式和按"k/2π标度"归一化的散射态的径向波函数,讨论了散射振幅的解析性质 .     

Experimental and theoretical analyses on the microwave backscattering ability and differential radar reflectivity of non-spherical hydrometeors

This paper experimentally and theoretically examines the scattering properties of simulated non-spherical hydrometeors including water oblates, ice oblates and ice sphere-cone-oblates, in terms of the backscattering cross-section and the differential reflectivity. The experimental measurements of the backscattering cross-sections of non-spherical hydrometeor samples were performed in the Electromagnetic Scattering Laboratory of China National Space Industrial Corporation. Meanwhile, the backscattering cross-sections have been computed with the transition (T) matrix method. The theoretical results are compared with the experimental data, showing that the calculations are consistent with the observations in general. Experimental and theoretical analyses indicate that the backscattering cross-section of non-spherical particles increases as the particle size parameter increases, and fluctuates when the sizes are larger under the effect of resonance scattering. Differential reflectivity Z_DR of water oblates in natural rainfall is always greater than 0 dB whereas Z_DR of hailstones may be negative. There is a good linear relationship between differential reflectivity and aspect ratio of a particle. These derivations agree with the literature and can be used to identify the presence of hail particles and distinguish between plate-type and columnar-type hydrometeors. In this study, the measuring experiment and the T-matrix method calculations for the scattering of simulated raindrop and ice particles are also briefly described.     

Synthesis, morphology and random laser action of ZnO nanostructures

Three-dimensional (3-D) ZnO random-wall nanostructures and one-dimensional (1-D) ZnO nanorods were prepared on silicon substrates by a simple solid-vapour phase thermal sublimation technique. Optical pumped random lasing has been observed in the ZnO random-wall arrays with a threshold intensity of 0.38 MW/cm² in the emission wavelength from 380 to 395 nm. The optical gain was attributed to the closed-loop scattering and light amplification of the ZnO random-wall. The experimental result suggests that the morphology of nanostructure is the key factor to effect random lasing.