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61.
Examples of exact expressions for the moments (mainly of the mean) of functions of sample moments are given. These provide checks on alternative developments such as asymptotic series for n, and simulation processes. Exact expressions are given for the mean of the square of the sample coefficient of variation, particularly in uniform sampling; Frullani integrals studied by G. H. Hardy arise. It should be kept in mind that exact results for (joint) moment generating functions (mgfs) are of interest as they produce a means of obtaining exact results for (cross) moments—including moments with negative indices. Thus an exact expression for the joint mgf of the 1st two noncentral moments can be used to obtain the mean of the (c.v.)2 (but not for the mean of the c..). A general expression is given for the moment generating function of the sample variance. The limitations of Fisher's symbolic formula for the characteristic function of sample moments (or more general statistics) are noted.This research was sponsored by the Applied Mathematical Sciences Research program, Office of Energy Research, U. S. Department of Energy under contract DE-AC0584OR21400 with the Martin Marietta Energy Systems. Inc. 相似文献
62.
The molecular intrinsic characteristic contour (MICC) is defined as the set of all the classical turning points of electron movement in a molecule. Studies on the MICCs of some medium organic molecules, such as dimethylether, acetone, and some homologues of alkanes, alkenes, and alkynes, as well as the electron density distributions on the MICCs, are shown for the first time. Results show that the MICC is an intrinsic approach to shape and size of a molecule. Unlike the van der Waals hard-sphere model, the MICC is a smooth contour, and it has a clear physical meaning. Detailed investigations on the cross-sections of MICCs have provided a kind of important information about atomic size changing in the process of forming molecules. Studies on electron density distribution on the MICC not only provide a new insight into molecular shape, but also show that the electron density distribution on the boundary surface relates closely with molecular properties and reactivities. For the homologues of alkanes, Rout(H), Dmin, and Dmax (the minimum and maximum of electron density on the MICC), all have very good linear relationships with minus of the molecular ionization potential. This work may serve as a basis for exploring a new reactivity indicator of chemical reactions and for studying molecular shape properties of large organic and biological molecules. 相似文献
63.
The molecular intrinsic characteristic contour (MICC) is defined based on the classical turning point of electron movement in a molecule. Three typical organic molecules, I.e. Methane, methanol and formic acid, were employed as examples for detailed introduction of our method. Investigations on the cross-sections of MICC provide important information about atomic size changing in the process of forming molecules. The electron density distributions on the MICCs of these molecules were calculated and shown for the first time. Results showed that the electron density distribution on the MICC correlates closely with molecular chemical properties, and it provides a new insight into molecular boundary. 相似文献
64.
以去离子水与乙二醇的混合液(体积分数分别为36.5%,48.7%,59.0%及71.2%,以下简称混合液)作为同轴传输线的绝缘介质,进行了μs级高电压负充电条件下的正电极击穿实验,研究了混合液的击穿电压、击穿时间、相对介电常数及电阻率与体积分数的关系。实验结果表明:在充电电压为20kV时,71.2%的混合液比36.5%的混合液的平均击穿电压提高25.1%,平均击穿时间延长10.49%,而相对介电常数减小868%。同时,随着充电时间的缩短,混合液的击穿电压提高。 相似文献
65.
《高分子化学》课程是大部分工科化工、材料类专业的必修课程,如何在工科专业高分子化学课程教学中体现工科特色,成为大家关注的热点.针对什么是工科特色,提出了本人的见解.并就如何在教学过程中体现工科特色介绍了本人的探索与尝试. 相似文献
66.
In the dynamics analysis and synthesis of a con-trolled system, it is important to know for what feedback gains can the controlled system decay to the demanded steady state as fast as possible. This article presents a sys-tematic method for finding the optimal feedback gains by taking the stability of an inverted pendulum system with a delayed proportional-derivative controller as an example. First, the condition for the existence and uniqueness of the stable region in the gain plane is obtained by using the D-subdivision method and the method of stability switch. Then the same procedure is used repeatedly to shrink the stable region by decreasing the real part of the rightmost charac-teristic root. Finally, the optimal feedback gains within the stable region that minimizes the real part of the rightmost root are expressed by an explicit formula. With the optimal feedback gains, the controlled inverted pendulum decays to its trivial equilibrium at the fastest speed when the initial val-ues around the origin are fixed. The main results are checked by numerical simulation. 相似文献
67.
For a spatial characteristic, there exist commonly fat-tail frequency distributions of fragment-size and -mass of glass, areas enclosed by city roads, and pore size/volume in random packings. In order to give a new analytical approach for the distributions, we consider a simple model which constructs a fractal-like hierarchical network based on random divisions of rectangles. The stochastic process makes a Markov chain and corresponds to directional random walks with splitting into four particles. We derive a combinatorial analytical form and its continuous approximation for the distribution of rectangle areas, and numerically show a good fitting with the actual distribution in the averaging behavior of the divisions. 相似文献
68.
《Physics letters. A》2019,383(19):2272-2276
Magnetic field design is important in cylindrical Hall thrusters and using permanent magnets to generate magnetic field is very promising in the future. In two typical permanent magnet configurations (i.e., ring and cylindrical configurations) of cylindrical Hall thrusters, discharge characteristics are compared in this paper through the experiments and simulations. The study shows that the cylindrical configuration can bring about higher thruster performance in the same working condition. The reason is that the potential drop of the cylindrical configuration is mainly concentrated in the channel, which is beneficial for the electrons to obtain energy to promote the ionization of the propellant. However, the voltage regulation range of the cylindrical configuration is lower because the anode is more easily overheated. 相似文献
69.
70.
Bilender P. Allahverdiev 《Mathematical Methods in the Applied Sciences》2019,42(1):229-236
In this study, maximal dissipative second‐order dynamic operators on semi‐infinite time scale are studied in the Hilbert space , that the extensions of a minimal symmetric operator in limit‐point case. We construct a self‐adjoint dilation of the dissipative operator together with its incoming and outgoing spectral representations so that we can determine the scattering function of the dilation as stated in the scheme of Lax‐Phillips. Moreover, we construct a functional model of the dissipative operator and identify its characteristic function in terms of the Weyl‐Titchmarsh function of a self‐adjoint second‐order dynamic operator. Finally, we prove the theorems on completeness of the system of root functions of the dissipative and accumulative dynamic operators. 相似文献