全文获取类型
收费全文 | 7424篇 |
免费 | 1151篇 |
国内免费 | 3194篇 |
专业分类
化学 | 6158篇 |
晶体学 | 389篇 |
力学 | 436篇 |
综合类 | 106篇 |
数学 | 2378篇 |
物理学 | 2302篇 |
出版年
2024年 | 30篇 |
2023年 | 78篇 |
2022年 | 210篇 |
2021年 | 238篇 |
2020年 | 274篇 |
2019年 | 260篇 |
2018年 | 253篇 |
2017年 | 401篇 |
2016年 | 532篇 |
2015年 | 355篇 |
2014年 | 514篇 |
2013年 | 907篇 |
2012年 | 806篇 |
2011年 | 765篇 |
2010年 | 641篇 |
2009年 | 630篇 |
2008年 | 626篇 |
2007年 | 609篇 |
2006年 | 503篇 |
2005年 | 439篇 |
2004年 | 365篇 |
2003年 | 304篇 |
2002年 | 304篇 |
2001年 | 266篇 |
2000年 | 214篇 |
1999年 | 207篇 |
1998年 | 170篇 |
1997年 | 142篇 |
1996年 | 134篇 |
1995年 | 121篇 |
1994年 | 107篇 |
1993年 | 74篇 |
1992年 | 60篇 |
1991年 | 39篇 |
1990年 | 44篇 |
1989年 | 24篇 |
1988年 | 26篇 |
1987年 | 14篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 11篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Tanmoy Dutta Yong Li Aaron L. Thornton Da‐Ming Zhu Zhonghua Peng 《Journal of polymer science. Part A, Polymer chemistry》2013,51(18):3818-3828
Donor‐acceptor conjugated polymers containing a new imide‐functionalized naphthodithiophene (INDT) as the acceptor unit and a 2,2'‐bithiophene with varied substituents as the donor unit have been synthesized. The bandgaps of these polymers depend strongly on the dihedral angle of the 2,2'‐bithiophene unit. The 3,3'‐dialkoxy substitution (polymers PDOR / PBOR ) leads to near planar bithiophene conformation due to the well‐known S–O short contact, while the 3,3'‐dialkyl substitution (polymer PDR ) results in significant twisting due to the steric effect. Consequently PDOR / PBOR shows the lowest bandgap of 1.82/1.85 eV while PDR has a bandgap of 2.38 eV. Bulk‐heterojunction solar cells of the polymer/fullerene blends have been fabricated. Preliminary results show that PBOR gives the best device performance with power conversion efficiencies as high as 2.45% in air without any thermal annealing treatment, indicating the promising potential of INDT‐containing conjugated polymers for efficient solar cells. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 3818–3828 相似文献
22.
《Journal of Coordination Chemistry》2012,65(21):3473-3483
Two Co(II) coordination polymers, [CoL(npa)]·2H2O (1) and [CoL(Hnpa)2] (2) (L = 1,4-bis(5,6-dimethylbenzimidazole-1-yl)benzene, H2npa = 5-nitroisophthalic acid), have been synthesized in different solvent systems and characterized by Infrared (IR) spectroscopy, elemental analysis, and powder and single crystal X-ray diffraction. Compound 1 was synthesized under solvothermal conditions with DMF as solvent and had a pair of L ligands adopting a μ2-bridging mode and connecting two Co2+ cations to generate a 26-membered Co2L2 loop. The npa2? link adjacent Co2L2 loops via a bis(monodentate) bridging mode to create a 1-D channel-like chain structure. Compound 2 was obtained under hydrothermal conditions, and the carboxylate of the monodeprotonated Hnpa? adopt a μ1-η0?:?η1 coordination to connect adjacent Co2+ cations into a 2-D polymeric layer. The μ2-bridging L ligands connect adjacent 2-D [Co(Hnpa)]n polymeric layers into a 3-D NaCl-like framework. The Co2+ cations and the L ligands in compounds 1 and 2 exhibit different coordination geometries and conformations. Effects of solvents on the construction of Co(II) coordination polymers were investigated. In addition, the electrochemical behavior of carbon paste electrodes containing 1 and 2 and the thermal stabilities of 1 and 2 were investigated. 相似文献
23.
《Journal of Coordination Chemistry》2012,65(7):1212-1220
A tetranuclear Zn(ΙΙ) complex, [Zn4L2(OAc)2(CH3OH)2] with an unsymmetric Salen-type bisoxime (H3L?=?6-hydroxy-4′,6′-dibromo-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol), has been synthesized and structurally characterized. There are two kinds of coordination geometry (trigonal bipyramidal and square pyramidal) in the Zn(ΙΙ) complex. The molecule has serious distortion probably from the asymmetry. The complex exhibits blue emission with the maximum emission wavelength λ max?=?423?nm when excited with 340?nm. 相似文献
24.
Aishakhanam H. Pathan Ganesh N. Naik Raghavendra P. Bakale Shrinath S. Machakanur Kalagouda B. Gudasi 《应用有机金属化学》2012,26(3):148-155
A series of Co(II), Ni(II), Cu(II), and Zn(II) complexes of a tridentate hydrazone were prepared and characterized by various spectro‐analytical techniques and magnetic moment studies. The complexes were found to be monomeric and non‐electrolytes. The copper complex is electrochemically active in the applied potential range. The compounds synthesized in the present study have shown promising antiproliferative activity when screened using the in vitro method against two human cancer cell lines: HeLa and HepG2. The Escherichia coli DNA‐binding properties of all the compounds were investigated with UV–visible absorption spectrophotometric titrations, viscosity measurements, DNA melting experiments and gel electrophoreses measurements. The compounds were demonstrated to act as DNA intercalators with appreciable DNA‐binding constant values. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
25.
Boguslaw Zegarliński 《Journal of statistical physics》1986,43(3-4):687-705
We give a condition on a Gibbs measure for an attractive Markov specification, which assures extremality and the global Markov property. As an example of application we consider the class of attractive Markov specifications defined on a compact configuration space over a two-dimensional lattice by the interaction Hamiltonians (assumed to have a finite set of periodic ground configurations) satisfying Peierl's condition. We prove that each extremal Gibbs measure for such a specification, at sufficiently low temperature, has the global Markov property.On leave of absence from the Institute of Theoretical Physics, University of Wrocaw, Poland. 相似文献
26.
纳米六方相氮化铝的合成和光学性能研究 总被引:1,自引:0,他引:1
报道了以AlCl3和Mg3N2为反应物, 在500 ℃条件下, 用简易的设备, 合成六方相AlN纳米材料. 样品的XRD和XPS图谱表明, 实验得到的AlN样品是纯的六方相AlN, 其中的杂质相含量均小于仪器的探测灵敏度. TEM图表明, AlN样品呈多孔网络状结构, 网络的骨架大小在10~20 nm之间. 对AlN样品的光学性能的研究表明, AlN样品的禁带宽度值约为6.12 eV; 红外吸收谱以680 cm-1为中心形成一个很宽的红外吸收带; 其拉曼散射峰较AlN薄膜和AlN单晶向低波数方向移动. 相似文献
27.
本文报道了锌、镉、汞、铅硫化物半导体极超微粒子的制备以及它们的光谱性质,比较了它们的粗、细粒子的吸收光谱和荧光光谱的差异,用量子化粒径效应解释了当超微粒子的粒径减小时出现的能级分裂.同时讨论了上述物质的极超微粒子在老化过程中的行为及其原因. 相似文献
28.
归纳了应用于过程模拟的重要热力学模型,对选择力学模型的决策树、热力学性质数据的收集与检验、热力学模型的使用和检验等问题进行了讨论。 相似文献
29.
根据自治动力系统中周期跟踪性和极限跟踪性的定义,将其引入到非自治动力系统。研究了非自治动力系统中周期跟踪性和极限跟踪性的动力学性质,得到:(1)若F = { f i } i = 0 ∞ 拓扑共轭于G = { g i } i = 0 ∞ ,则F 具有周期跟踪性当且仅当G 具有周期跟踪性;(2)若F = { f i } i = 0 ∞ 拓扑共轭于G = { g i } i = 0 ∞ ,则F 具有极限跟踪性当且仅当G 具有极限跟踪性;(3)若乘积系统( X × Y , F × G ) 具有周期跟踪性,则( X , F ) 和( Y , G ) 具有周期跟踪性。 以上结论对非自治动力系统中跟踪性的发展有一定的促进作用。 相似文献
30.
利用算子的一致可逆性质,定义了一个新的谱集,分别给出了有界线性算子满足(ω)性质的充分条件和必要条件,并在此基础上得到算子与其算子演算满足(ω)性质的判定条件。 相似文献