裂解色谱法研究PMR型聚酰亚胺前体的反应过程

用裂解气相色谱法研究ＰＭＲ型聚酰亚胺前体在反应中的化学变化过程，以裂解产物醇和环戊二烯的生成率表示酰胺化或酰亚胺化及交联的程度，结果表明，酰胺化或酰亚胺化在５０℃以下不发生，在１８０～２２０℃完成，降冰片烯端基在１５０℃以下不发生交联反应，在２８０℃，１０～１８小时可完成交联反应。     

毛细管气相色谱法测定5种中草药中有机氯农药的残留量

建立了怀牛夕等 5种中草药中六六六及滴滴涕异构体含量的气相色谱分析方法。样品以石油醚 +丙酮在索氏提取器中提取 ,提取液以浓硫酸净化。采用SE 30弹性石英毛细管柱分离样品 ,GC ECD检测六六六、滴滴涕农药的残留量。方法的线性范围为 5 .7× 10 - 7～ 2 .8× 10 - 4μg ;最小检测量为 1.3× 10 - 1 4～ 2 .5×10 - 1 2 g ;加样平均回收率为 88.8%～ 99.1% ;RSD为 0 .9%～ 5 .3%。     

白酒中C_9－C_（18）脂肪酸的气相色谱分析

白酒中Ｃ＿９－Ｃ＿（１８）脂肪酸的气相色谱分析周在德，曾永昌（四川大学化学系成都６１００６４）关键词气相色谱法，白酒，Ｃ＿９－Ｃ＿（１８）脂肪酸。白酒中脂肪酸的含量及相互比例关系，极大地影响着白酒的色，香，味，风格￣（［１］［２］）。一般采用的化学分...     

A supported gold catalyst for the elimination of hydrogen from CO2 feed gas in the production of urea

Supported gold catalyst for eliminating hydrogen from CO₂ feed gas in the production of urea is found to be superior to other industrial catalysts (e.g. Pt/Al₂O₃ and PdPt/Al₂O₃) in catalytic activity and resistance to sulfur poisoning.     

Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: implications for hydrogen storage in porous materials

A systematic modulation of organic ligands connecting dinuclear paddle-wheel motifs leads to a series of isomorphous metal-organic porous materials that have a three-dimensional connectivity and interconnected pores. Aromatic dicarboxylates such as 1,4-benzenedicarboxylate (1,4-bdc), tetramethylterephthalate (tmbdc), 1,4-naphthalenedicarboxylate (1,4-ndc), tetrafluoroterephthalate (tfbdc), or 2,6-naphthalenedicarboxylate (2,6-ndc) are linear linkers that form two-dimensional layers, and diamine ligands, 4-diazabicyclo[2.2.2]octane (dabco) or 4,4'-dipyridyl (bpy), coordinate at both sides of Zn(2) paddle-wheel units to bridge the layers vertically. The resulting open frameworks [Zn(2)(1,4-bdc)(2)(dabco)] (1), [Zn(2)(1,4-bdc)(tmbdc)(dabco)] (2), [Zn(2)(tmbdc)(2)(dabco)] (3), [Zn(2)(1,4-ndc)(2)(dabco)] (4), [Zn(2)(tfbdc)(2)(dabco)] (5), and [Zn(2)(tmbdc)(2)(bpy)] (8) possess varying size of pores and free apertures originating from the side groups of the 1,4-bdc derivatives. [Zn(2)(1,4-bdc)(2)(bpy)] (6) and [Zn(2)(2,6-ndc)(2)(bpy)] (7) have two- and threefold interpenetrating structures, respectively. The non-interpenetrating frameworks (1-5 and 8) possess surface areas in the range of 1450-2090 m(2)g(-1) and hydrogen sorption capacities of 1.7-2.1 wt % at 78 K and 1 atm. A detailed analysis of the sorption data in conjunction with structural similarities and differences concludes that porous materials with straight channels and large openings do not perform better than those with wavy channels and small openings in terms of hydrogen storage through physisorption.     

天花粉蛋白的化学——Ⅴ.粉末状结晶天花粉蛋白的拉曼光谱

本文报道粉末状结晶天花粉蛋白的拉曼光谱。酰胺Ⅰ和酰胺Ⅲ的振动谱带在1680和1250 cm~(-1)。骨架C_α—C—N的振动谱带在965 cm~(-1)。苯丙氨酸残基的特征谱带在1010和1620 cm~(-1)。酪氨酸残基的特征谱带在845和862 cm~(-1)。色氨酸残基的特征谱带在765 cm~(-1)。酰胺Ⅰ和Ⅲ的谱带中,B折叠和无序结构的特征较为明显。表征无序结构的965 cm~(-1)谱带很弱。     

毛细管气相色谱法测定染发剂中七种染料组份

采用毛细管气相色谱法对染发剂中苯酚、邻苯二酚、对苯二酚、间苯二酚、邻苯二胺、对苯二胺和间苯二胺七种染料进行了分析。结果表明，该方法能有效地分离这七种染料，其检出限为苯酚50ng、邻苯二胺160ng、对苯二胺240ng、邻苯二酚280ng、间苯二胺180ng、对苯二酚190ng、间苯二酚180ng。方法测定精密度为2.07-4.33％，回收率为96.1％-103.3％。方法具有操作准确、简单、快速、实用等特点。     

General application of jäntti's method for the fast calculation of sorption equilibrium

On the basis of a molecular model for adsorption kinetics Jäntti introduced a method to calculate equilibriums shortly after a change of the pressure of the sorptive gas. In the present paper we show that this method is useful in many more situations than those intended originally.     

固相微萃取/二氧化锡气体传感器联用技术对果蔬中有机磷农药残留的快速检测

研究了固相微萃取(SPME)和二氧化锡气体传感器的联用技术对果蔬中有机磷农药残留乐果、氧乐果、甲胺磷、乙酰甲胺磷、马拉硫磷、敌百虫等的快速检测。结果表明，在85℃下，解吸8min，二氧化锡气体传感器在2min内完成对有机磷农药残留的快速检测。零解吸时间测量的甲胺磷的动态响应曲线表明。SPME／二氧化锡气体传感器联用技术对分析SPME的解吸平衡非常有利。     

Development of a new analytical method for the evaluation of hazards from slow decomposition of waste streams and process solutions

A wide variety of liquid streams are generated as part of the process research and development effort. Frequently these streams are drummed off, either as intermediates that must be held for processing or as wastes that must be sent off-site for disposal. Because of the long times and low concentrations often involved, current thermoanalytical techniques were inadequate to detect the potential of streams to generate gas. A custom-made apparatus, the gas evolution test cell (GETC), was developed in the Merck Research Laboratories to measure the gas generation potential of various streams under precisely defined conditions, is the key innovation for the development of a quantitative gas-generation test method.