The general approach for the synthesis of substituted cyclobutenyl- and norbornadienyllithiums containing masked trifluoromethyl group

α,β-Unsaturated trifluoromethylketones of cyclobutene number containing trimethylstannyl substituent in β-position were firstly prepared by the addition of trimethylstannyllithium to the corresponding trifluoromethylenaminoketones. The protection of carbonyl function under basic conditions conserving the organometallic substituent was elaborated. The generation of corresponding organolithiums by Sn-Li exchange and their reactivity was studied.     

DNA‐backbone radio resistivity induced by spin blockade effect

Coherent control of OH‐free radicals interacting with the spin‐triplet state of a DNA molecule is investigated. A model Hamiltonian for molecular spin singlet‐triplet resonance is developed. We illustrate that the spin‐triplet state in DNA molecules can be efficiently populated, as the spin‐injection rate can be tuned to be orders of magnitudes greater than the decay rate due to small spin‐orbit coupling in organic molecules. Owing to the nano‐second life‐time of OH free radicals, a non‐equilibrium free energy barrier induced by the injected spin triplet state that lasts approximately longer than one‐micro second in room temperature can efficiently block the initial Hydrogen abstraction and DNA damage. For a direct demonstration of the spin‐blockade effect, a molecular simulation based on an ab‐initio Car‐Parrinello molecular dynamics is deployed. © 2010 Wiley Periodicals, Inc. J Comput Chem 2010     

Stability of new electrostatic discharge protection and electromagnetic wave shielding effectiveness from poly(vinyl chloride)/graphite/nickel nanoconducting composites

Poly(vinyl Chloride)/graphite nanosheet/nickel (PVC/GN) nancomposites are new alternative candidates for electrostatic charge dissipation and electromagnetic interference shielding applications due to their lightweight, ease processing and tunable conductivities. The structures of the nanocomposites were examined by means of scanning electron microscopy (SEM) and X-ray analysis. The mechanical properties such as hardness, modulus of elasticity and elongation at break as a function of GN content were examined. The applicability of the nanocomposites as electrostatic charge dissipation was tested in terms of displaying the variation of decay voltage with time. In addition, the dielectric properties such as real and imaginary permittivity of composites as functions of frequency were investigated. Finally, the electromagnetic properties were measured in the frequency range from 1 to 12 GHz and compared with theoretical modeling. The highest shielding effectiveness at microwave frequency of these nanocomposites was 47 dB which is realistic for defense applications like radar evasion.     

5-溴-2-羟基苯甲醇的不对称羟基保护

采用分步法对5-溴-2-羟基苯甲醇中的不对称羟基进行了选择性保护.以2,3-二氢吡喃和氯甲醚为保护基,经两步反应得5-溴-2-甲醚氧基苯甲-2-(四氢吡喃)醚,其结构经1H NMR, IR和MS表征.     

Attenuated total reflectance spectroscopy of simultaneous processes: Corrosion inhibition of cuprous oxide by benzotriazole

Attenuated total reflectance (ATR) spectroscopy was used to perform in situ studies of the corrosion inhibition of cuprous oxide (Cu₂O) by benzotriazole (BTA) in aqueous solution at concentrations from 1 to 20 μM. Because two separate processes occur simultaneously, that of Cu₂O corrosion and corrosion inhibition by BTA adsorption, the spectral information was subjected to deconvolution by a conjugate gradient minimization algorithm. Under these conditions, a solution phase concentration of 7-10 μM BTA nearly completely inhibited the corrosion of Cu₂O in deionized water. Using a Langmuir adsorption model, this represented only 25% of the maximally covered surface area.     

导体板上单极天线对电磁脉冲响应特性的矩量法分析

 针对应用广泛的单极天线,基于矩量法分析了天线对高空电磁脉冲和高功率微波、超宽带非核电磁脉冲的响应,计算了三类电磁脉冲通过天线耦合产生感应电流频谱响应和时域瞬态响应,窄带脉冲的响应曲线与入射脉冲有较大相似性,电流响应峰值依次为100,60和10.3 A,对现有大功率限幅器的功率容限提出了更高的要求。     

短期趋势判断与投资组合优选

针对股市非常有限的可预测性和投资组合优化时间窗口的选择问题,本文从股指趋势和个股收益率趋势类别两个层次上进行前瞻分析,并依据股指趋势判断和不同时间窗口对应的边际风险收益,提出投资组合优化计算的时间窗口选择规则,动态地进行资产组合优化。通过沪深A股及沪深300成份股两个样本集合的应用研究表明,考虑多层次短期趋势预测的动态投资组合选择方法能有效地改善资产组合绩效,是股市资产风险管理的有效方法之一。     

化学战剂的分析测试进展

综述了气相色谱、液相色谱、红外光谱、色质联用、生化传感器、核磁共振、军用侦毒设备、分光光度计、毛细管电泳等仪器对化学战剂分析测试的应用进展情况．     

Interaction of fast electrons and gamma-quanta with radiation protection ferric oxide composites

Physical processes of fast electron and gamma-radiation beam interaction with radiation protection ferric oxide composite materials are investigated together with dependences of energy (flux) accumulation and transmission coefficients on the gamma-radiation energy and thickness of a protective screen. Integral characteristics of radiation protection materials are calculated. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 66–71, November, 2008.