全文获取类型
收费全文 | 616篇 |
免费 | 2篇 |
国内免费 | 4篇 |
专业分类
化学 | 412篇 |
综合类 | 5篇 |
物理学 | 205篇 |
出版年
2021年 | 2篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 7篇 |
2015年 | 8篇 |
2014年 | 3篇 |
2013年 | 22篇 |
2012年 | 49篇 |
2011年 | 30篇 |
2010年 | 24篇 |
2009年 | 22篇 |
2008年 | 21篇 |
2007年 | 41篇 |
2006年 | 36篇 |
2005年 | 28篇 |
2004年 | 31篇 |
2003年 | 32篇 |
2002年 | 28篇 |
2001年 | 25篇 |
2000年 | 18篇 |
1999年 | 28篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 24篇 |
1995年 | 28篇 |
1994年 | 18篇 |
1993年 | 9篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 1篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有622条查询结果,搜索用时 15 毫秒
81.
水样中铜,铅,镉的巯基棉富集火焰原子吸收测定 总被引:4,自引:0,他引:4
翟贵仙 《光谱学与光谱分析》1992,12(1):119-122
在测定水样中铜、铅及镉的时候用巯基棉在采样现场富集简便快速,且灵敏准确,避免了样品运送的不便和萃取富集的繁琐。 相似文献
82.
本实验对含13味中药的治肺癌复方原药,头煎及二煎残渣和浸汁,经0.45μ膜分离的颗粒物,可溶态,以及可溶态分别通过阳离子交换树脂,用三氯甲烷萃取后所得各自柱截留物,穿过物,有机相,水相等共15个样品中铬,镍,按照中药微量元素初级和次形态分析的要求,进行分析测定,以此计算出一套形态分析参数和相关数据,为探讨中草约中微量元素的化学形态提供了新的信息。 相似文献
83.
84.
S. L. C. Ferreira H. S. Ferreira G. D. Matos D. S. Anunciação W. N. L. dos Santos V. P. Campos 《应用光谱学评论》2013,48(8):633-653
Abstract: This article presents a critical evaluation of the analytical procedures used for the determination of lead in seawater, which is important because lead is a good indicator of marine pollution caused by human activities. Sampling, storage, and pretreatment techniques are briefly overviewed, including the significance of systematic errors that cannot be corrected later on. The main techniques in this article are electrothermal–atomic absorption spectrometry (ET-AAS), inductively coupled plasma–mass spectrometry (ICP-MS), and voltammetry. Flame atomic absorption spectrometry (FAAS) and inductively coupled plasma–optical emission spectrometry (ICP-OES) are treated as well, although their limits of quantification are not sufficient for a determination of lead in unpolluted seawater. Even when separation and preconcentration techniques are applied, these techniques are only capable of detecting lead in polluted coastal seawater. Separation and preconcentration are actually also required for ET-AAS and ICP-MS in order to determine the lowest concentrations of lead found in unpolluted open-ocean seawater, which is still a challenge for the analytical chemist. 相似文献
85.
Dimiter L. Tsalev E. I. Tserovski A. G. Raitcheva A. I. Barzev R. G. Georgieva Z. K. Zaprianov 《光谱学快报》2013,46(2):331-346
An analytical scheme for the determination of up to fifteen trace elements in nails and hair has been proposed. Samples were solubilized by means of aqueous tetraalkylammonium hydroxide (alkyl = methyl or ethyl). Cadmium, Cr, Cu, Fe, Mn, Pb and Zn were determined by pulse-nebulization flame AAS, employing the Slotted Tube Atom Trap (STAT) for Cd and Pb. Suitable chemical modifiers have been applied in electrothermal AAS (ETAAS) determinations of Cd and Pb (ammonium hydrogen phosphate), As, Sb, Se and Sn (palladium), while no modifier was needed in determinations of Al, Co, Cr, Mn, Mo and Ni. Calibration was performed by means of matrix-matched standards and the technique was verified by standard additions, comparison with neutron activation and analysis of hair reference material. The usefulness of this technique for occupational exposure monitoring is briefly discussed. 相似文献
86.
Araujo RG Oleszczuk N Rampazzo RT Costa PA Silva MM Vale MG Welz B Ferreira SL 《Talanta》2008,77(1):400-406
Two analytical methods for the determination of cadmium in wheat flour by electrothermal atomic absorption spectrometry without prior sample digestion have been compared: direct solid sampling analysis (SS) and slurry sampling (SlS). Besides the conventional modifier mixture of palladium and magnesium nitrates (10 μg Pd + 3 μg Mg), 0.05% (v/v) Triton X-100 has been added to improve the penetration of the modifier solution into the solid sample, and 0.1% H2O2 in order to promote an in situ digestion for SS. For SlS, 30 μg Pd, 12 μg Mg and 0.05% (v/v) Triton X-100 have been used as the modifier mixture. Under these conditions, and using a pyrolysis temperature of 800 °C, essentially no background absorption was observed with an atomization temperature of 1600 °C. About 2 mg of sample have been typically used for SS, although as much as 3-5 mg could have been introduced. In the case of SlS multiple injections had to be used to achieve the sensitivity required for this determination. Calibration against aqueous standards was feasible for both methods. The characteristic mass obtained with SS was 0.6 pg, and that with SlS was 1.0 pg. The limits of detection were 0.4 and 0.7 ng g−1, the limits of quantification were 1.3 and 2.3 ng g−1 and the relative standard deviation (n = 5) was 6-16% and 9-23% for SS and SlS, respectively. The accuracy was confirmed by the analysis of certified reference materials. The two methods were applied for the determination of cadmium in six wheat flour samples acquired in supermarkets of different Brazilian cities. The cadmium content varied between 8.9 ± 0.5 and 13 ± 2 ng g−1 (n = 5). Direct SS gave results similar to those obtained with SlS using multi-injections; the values of both techniques showed no statistically significant difference at the 95% confidence level. Direct SS was finally adopted as the method of choice, due to its greater simplicity, the faster speed of analysis and the better figures of merit. 相似文献
87.
88.
采用原子吸收分光光度法测定了11种治疗冠心病中成药物中镁含量。结果表明,药物中含有较丰富的镁元素,它为临床上探讨镁元素与冠心病关系提供了有用的数据。 相似文献
89.
应用原子吸收光谱法检测了老年高血压、冠心病患者血清铁、红细胞内铁及血清铁蛋白、MCH、MCHC。发现老年冠心病患者血清铁、红细胞内铁、血清铁蛋白含量明显高于对照组(P<0.01)。老年高血压患者血清铁蛋白、红细胞内铁、MCH、MCHC也明显高于对照组(P<0.01),血清铁与对照组比较有显著性差异(P<0.05)。结果表明:老年高血压,冠心病患者存在铁代谢异常,其游离铁与储存铁的增加可能是其发病的危险因素之一。 相似文献
90.
流动注射蒸气发生原子吸收光谱测定痕量铜 总被引:11,自引:1,他引:10
建立了流动注射蒸气发生原子吸收光谱测定铜的新方法。使含有微量邻菲咯啉的样品溶液与硼氢化钠溶液汇合并反应生成蒸气态物质。在Ar载气下随反应液进入气液分离器分离 ,并进入石英管原子化器在 1 0 0 0℃下检测。在 5 0 0 μL进样体积下 ,铜的检出限为 1 8μg·L- 1 ,相对标准偏差为 2 6%(n =1 1 ,c=1 0 0 μg·L- 1 )。采样频率为 1 4 4样·h- 1 。分析标准参考物质大米粉和头发样品中的铜 ,结果与标准值一致 相似文献