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Premixed counterflow flames with thermally sensitive intermediate kinetics and radiation heat loss are analysed within the framework of large activation energy. Unlike previous studies considering one-step global reaction, two-step chemistry consisting of a chain branching reaction and a recombination reaction is considered here. The correlation between the flame front location and stretch rate is derived. Based on this correlation, the extinction limit and bifurcation characteristics of the strained premixed flame are studied, and the effects of fuel and radical Lewis numbers as well as radiation heat loss are examined. Different flame regimes and their extinction characteristics can be predicted by the present theory. It is found that fuel Lewis number affects the flame bifurcation qualitatively and quantitatively, whereas radical Lewis number only has a quantitative influence. Stretch rates at the stretch and radiation extinction limits respectively decrease and increase with fuel Lewis number before the flammability limit is reached, while the radical Lewis number shows the opposite tendency. In addition, the relation between the standard flammability limit and the limit derived from the strained near stagnation flame is affected by the fuel Lewis number, but not by the radical Lewis number. Meanwhile, the flammability limit increases with decreased fuel Lewis number, but with increased radical Lewis number. Radical behaviours at flame front corresponding to flame bifurcation and extinction are also analysed in this work. It is shown that radical concentration at the flame front, under extinction stretch rate condition, increases with radical Lewis number but decreases with fuel Lewis number. It decreases with increased radiation loss. 相似文献
83.
Flame-retardant expandable graphite (EG)/silicone rubber (SR) composites were prepared using nano-CaCO3 particles as reinforcement filler. In addition to mechanical measurements, limited oxygen index (LOI), UL-94 and cone calorimeter tests (CCT), the thermal properties were tested by thermogravimetric analysis (TGA). The results showed that the content and particle size of the EG both had large effects on the flammability and mechanical properties of the EG/SR blends. The composites that contained 25 phr EG (50–80 mu) had excellent LOI values, 47–48, and achieved the UL-94 V-0 level while the pure SR sample had the LOI value of 25 and achieved the UL-94 V-2 level. The data obtained from the CCT indicated that the addition of EG decreased remarkably the heat release rate, smoke emission, and mass loss rate of the composites. SEM microphotographs of the EG/SR composites before and after combustion demonstrated that EG underwent a large volume expansion, and the multiporous char structure blocked heat transfer and protected the substrate from fire. 相似文献
84.
钝体后湍流预混燃烧的PDF模拟 总被引:3,自引:0,他引:3
本文采用PDF方法对矩形燃烧室内钝体后的湍流预混火焰进行了数值模拟。脉动速度-频率-标量联合的PDF输运方程用Monte Carlo方法求解,质量、动量和能量的平均值由基于无结构网格的有限体积法求解,压力通过状态方程获得。PDF方程中所需的平均密度、平均速度和压力由有限体积法提供,并将用Monte Carlo方法求出的雷诺应力、化学反应源项和比热比传递给有限体积法。本文对丙烷和空气燃烧的不同简化化学反应机理进行了研究,并与实验结果进行比较,获得满意的结果。 相似文献
85.
榕树型互连网络及光学实现 总被引:1,自引:0,他引:1
讨论了一种用扭曲向列相液晶器件和偏振分光棱镜实现光学榕树上互连网络的结构,这种结构具有直线式传输、无错位、无缩放,并能够实现模块化和集成化的优点。 相似文献
86.
Zhenyu Tian 《Proceedings of the Combustion Institute》2009,32(1):311-318
A premixed nitromethane/oxygen/argon flame at low pressure (4.67 kPa) has been investigated using tunable vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry. About 30 flame species including hydrocarbons, oxygenated and nitrogenous intermediates have been identified by measurements of photoionization efficiency spectra. Mole fraction profiles of the flame species have been determined by scanning burner position at some selected photon energies. The results indicate that N2 and NO are the major nitrogenous products in the nitromethane flame. Compared with previous studies on nitromethane combustion, a number of unreported intermediates, including C3H4, C4H6, C4H8, C2H2O, C2H4O, CH3CN, H2CNHO, C3H3N and C3H7N, are observed in this work. Based on our experimental results and previous modeling studies, a detailed oxidation mechanism including 69 species and 314 reactions has been developed to simulate the flame structure. Despite some small discrepancies, the predictions by the modeling study are in reasonable agreement with the experimental results. 相似文献
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基于带化学反应的二维轴对称Euler方程,利用带有Superbee限制函数的波传播算法,对共振腔中的氢气-空气预混气的聚心燃烧进行了数值模拟,讨论了共振腔不同抛物面对起爆的影响。数值结果表明,在开始阶段,燃烧诱导的激波在轴心、火焰和固壁的反射,使火焰失稳,随后共振腔中的抛物壁面上产生一定频率和强度的反射激波,不断穿越火焰,使火焰进一步失稳,加剧了燃烧速度,最终导致爆轰的形成。同时,火焰在与激波的作用过程中,形状扭曲变形,呈封闭端小敞口端大的扁平头部蘑菇云。共振腔抛物面的不同形状引起激波聚焦位置的变化,会影响激波和火焰的相互作用,使起爆提前或推迟,甚至不起爆。 相似文献
90.