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931.
Melamine salt of tripentaerythriol phosphate (MTP), as a new intumescent flame‐retardant, was prepared from tripentaerythritol (TPE), polyphosphoric acid, phosphoric pentoxide, and melamine, and then incorporated into polypropylene (PP) to obtain flame‐retarded PP‐MTP. FT‐IR analysis showed that MTP was in the form of cage structure. The flammability, combustion behavior, and thermal degradation and stability of flame‐retarded PP were characterized by using LOI, UL‐94 test, cone calorimetry, and TGA, respectively. By SEM, the char structure of PP‐MTP was analyzed. XRD diffraction tests showed that PP‐matrix of PP‐MTP presented better crystallized phases, when MTP was modified by methyl hydrogen siloxane. The relations of the dispersion of MTP in PP matrix to the compatibility between PP and MTP, and to the flame retardancy were discussed. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
932.
933.
《先进技术聚合物》2018,29(4):1294-1302
For the sake of improving the flame retardancy of epoxy resin (EP), a novel phosphorus‐containing phenolic resin (PPR) synthesized in our group instead of conventional phenolic resin (PR) was used to cure EP in the present research. The curing processes and the corresponding crosslinking structure and mechanical performance were investigated by differential scanning calorimeter and dynamic mechanical thermal analysis. Because of the introduction of flame‐retarding elements including P and Si, PPR exhibited higher charring capacity in the condensed phase, which is helpful to construct a char layer of higher quality. Correspondingly, PPR‐cured EP displayed remarkably improved flame retardance as compared to conventional PR‐cured EP through the related evaluations including limiting oxygen index, vertical burning test, and microscale combustion colorimeter. As a multifunction agent, it is believable that PPR possesses potential commercial value to prepare flame‐retardant EP with high performance. 相似文献
934.
《先进技术聚合物》2018,29(1):433-441
A method was elaborated to prepare flame retarded self‐reinforced polypropylene composites by injection moulding. The effect of intumescent flame retardant (FR) loading was comprehensively investigated on the morphology, flammability, and mechanical properties of the self‐reinforced polypropylene composites and compared with non‐reinforced counterparts of identical additive contents. Homogeneous distribution of both the reinforcing polypropylene fibres and the FR additive was achieved endowing significantly improved strength and stiffness accompanied with increased fire resistance. At 10% FR content, 37% reduction of peak of heat release rate, UL94 V‐2 rating, and LOI of 24.5 vol% were achieved without compromising the improved mechanical performance of the injection moulded self‐reinforced composites, ie, a 4‐fold increase of tensile strength and a 7‐fold increase of tensile modulus were reached compared with the non‐reinforced counterpart. At higher loading (15% FR), the FR properties improved further (LOI of 29.5 vol% was reached); however, due to the abrasive effect of the FR particles in the matrix, the structure of the reinforcing fibres tends to get damaged during the thermo‐mechanical processing, and thus their reinforcing efficacy deteriorated. It is demonstrated that the combination of polymer fibre reinforcement with other fillers (such as FRs) is advantageous and feasible even by injection moulding, but the balance between the individual attributed properties needs to be found. 相似文献
935.
《先进技术聚合物》2018,29(4):1194-1205
Epoxy resin (EP) is more and more important in many fields, but its application is limited due to the inflammability in air of EP. Therefore, reducing the fire hazard of EP is necessary. In this work, a kind of hybrid flame retardant (α‐ZrP‐RGO) consisting of a 2‐dimensional inorganic reduced graphene oxide (RGO) modified with a planar‐like α‐zirconium phosphate (α‐ZrP) particles was prepared successfully via 1‐step hydrothermal method. The effects of α‐ZrP‐RGO on the thermal performance, flame retardancy, and smoke suppression of EP were investigated by preparing EP composites containing both EP and α‐ZrP‐RGO. Thermogravimetric results revealed that α‐ZrP‐RGO could improve the char yield of EP at 700°C obviously. In addition, compared with pure EP, the peak heat release rate and the total heat release of EP composites were decreased significantly, while the limited oxygen index of EP composites was increased. Meanwhile, the smoke production rate of EP composites was reduced obviously with the addition of α‐ZrP‐RGO. The enhanced flame retardancy and smoke suppression of EP composites were mainly attributed to not only the physical barrier effect of both α‐ZrP and RGO but also the catalytic effect of α‐ZrP during the combustion process of EP composites. 相似文献
936.
《先进技术聚合物》2018,29(2):860-866
The exploration of green flame retardants is of great significance for fire safety, ecological environment protection, and resource saving. Herein, a novel phosphorus containing chitosan‐cobalt complex (CS‐P‐Co) was successfully synthesized for the first time and then introduced into polylactic acid matrix. Owning to the formation of cobalt salts, the CS‐P‐Co exhibits good thermal stability and catalytic char effect. The as‐fabricated biodegradable polylactic acid/CS‐P‐Co composites with small amounts of CS‐P‐Co (≤ 4.0 wt%) show remarkably improved flame retardancy, such as decreased peak heat release rate and total heat release by 23.0% and 20.0%, respectively. Scanning electron microscopy, Thermogravimetric analysis, and Raman results demonstrate that compact graphitized char layers are formed on the composite surface during combustion, attributed to the catalytic effect of CS‐P‐Co. The char inhibits diffusion of heat, mass, and oxygen, which plays a key role in the flame retardancy enhancement. 相似文献
937.
Molecular Firefighting—How Modern Phosphorus Chemistry Can Help Solve the Challenge of Flame Retardancy
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Dr. Maria M. Velencoso M. Sc. Alexander Battig M. Sc. Jens C. Markwart Priv.‐Doz. Dr. Bernhard Schartel Priv.‐Doz. Dr. Frederik R. Wurm 《Angewandte Chemie (International ed. in English)》2018,57(33):10450-10467
The ubiquity of polymeric materials in daily life comes with an increased fire risk, and sustained research into efficient flame retardants is key to ensuring the safety of the populace and material goods from accidental fires. Phosphorus, a versatile and effective element for use in flame retardants, has the potential to supersede the halogenated variants that are still widely used today: current formulations employ a variety of modes of action and methods of implementation, as additives or as reactants, to solve the task of developing flame‐retarding polymeric materials. Phosphorus‐based flame retardants can act in both the gas and condensed phase during a fire. This Review investigates how current phosphorus chemistry helps in reducing the flammability of polymers, and addresses the future of sustainable, efficient, and safe phosphorus‐based flame‐retardants from renewable sources. 相似文献
938.
研究了在空气-乙炔火焰中,阴离子型表面活性剂十二烷基磺酸钠(SDS)-正丁醇-正庚烷-水四组分构成的微乳液对镍钴的增敏作用。结果表明,在仪器最佳工作条件和合适酸度下,含水70%微乳液使火焰原子吸收法测镍钴的吸光度分别增敏61.1%、23.3%,使测定的灵敏度有较大的提高,用于饲料中镍钴的测定,回收率为96.4%~105.2%,相对标准偏差RSD为2.8%~5.6%,结果满意。 相似文献
939.
In this paper is proposed a simultaneous pre-concentration procedure using cloud point extraction for the determination of cadmium and lead in drinking water employing sequential multi-element flame atomic absorption spectrometry. The ligand used is 2-(2-thiazolylazo)-p-cresol (TAC) and the micellar phase is obtained using non-ionic surfactant octylphenoxypolyethoxyethanol (Triton X-114) and centrifugation.The optimization step was performed using two-level factorial design and Doehlert design. A multiple response function was established in order to get experimental conditions for simultaneous extraction of cadmium and lead.The method allows the determination of cadmium and lead with detection limits of 0.077 μg L− 1 and 1.05 μg L− 1 respectively, precision expressed as relative standard deviation (RSD) of 1.5 and 3.3% (n = 10) for cadmium concentrations of 30 μg L− 1 and 50 μg L− 1, respectively, and RSD of 1.8% and 2.7% for lead concentrations of 30 μg L− 1 and 50 μg L− 1, respectively. The accuracy was confirmed by analysis of a certified reference material of natural water.This method was applied for the determination of cadmium and lead in drinking water samples collected in Jaguaquara City, Brazil. Tests of addition/recovery were also performed for some samples and results varied from 95 to 104% for cadmium and 96 to 107% for lead. The cadmium and lead concentrations found in these samples were always lower than the permissible maximum levels stipulated by Brazilian Health Organization. 相似文献
940.