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81.
L. A. Bulygina V. I. Sokolov I. A. Utepova V. L. Rusinov O. N. Chupakhin 《Russian Chemical Bulletin》2007,56(5):1080-1082
Cyclopalladation of 6-ferrocenyl-2,2′-bipyridine and 2-ferrocenyl-1,10-phenanthroline in the presence of the N-acylamino acid salt as the asymmetric catalyst was performed. Some reactions of the resulting bicyclic palladium derivatives
with tridentate (N,N,C) ligands were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1039–1041, May, 2007. 相似文献
82.
Boshra R Sundararaman A Zakharov LN Incarvito CD Rheingold AL Jäkle F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(9):2810-2824
The binding properties of heteronuclear bidentate Lewis acids, in which an organoboron and an organotin moiety are attached adjacent to each other at one of the Cp rings of ferrocene, have been studied. Treatment of [1,2-fc(SnMe2Cl)(BClMe)] (1-Cl) (fc = ferrocenediyl) with one equivalent of pyridine or 4-dimethylaminopyridine (DMAP) resulted in diastereoselective complexation of boron. Adducts 2 and 3 have been studied by multinuclear NMR, and the stereoselectivity of complexation was further confirmed by single crystal X-ray diffraction of 2. The importance of cooperative effects that involve an intramolecular B-ClSn interaction on the diastereoselectivity is evident from comparison with binding studies on the phenyl-substituted analogue [1,2-fc(SnMe2Cl)(BPhMe)] (1-Ph). Complexation of 1-Ph led to diastereomeric mixtures of adducts 4 and 5, respectively, which were identified by multinuclear NMR including NOESY experiments. The solid-state structure of one of the diastereomers of 5 was confirmed by X-ray crystallography. Facile isomerization was found in solution and the barrier of activation was determined by VT NMR studies (4: Delta(#)(298) = 54.9+/-0.4 kJ mol(-1); 5: Delta(#)(298) = 70.3+/-0.1 kJ mol(-1)). Competitive binding of pyridine to 1-Cl and [FcB(Cl)Me] (Fc = ferrocenyl) showed that cooperative effects between tin and boron lead to significant Lewis acidity enhancement. Binding of a second nucleophile in the presence of excess of base occurred also at boron. The novel zwitterionic complexes [1,2-fc(BMe(py)2)(SnMe2Cl2)] (6) and [1,2-fc(BMe(dmap)(2))(SnMe(2)Cl2)] (7) formed, which consist of boronium cation and stannate anion moieties. The structure of 7 in the solid-state was confirmed by X-ray crystallography. Multinuclear NMR data and competition experiments indicate weak binding of chloride to tin in 7 and partial dissociation in solution. 相似文献
83.
A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclobutenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene. 相似文献
84.
Paul Krajnik Karl Schlögl Michael Widhalm 《Monatshefte für Chemie / Chemical Monthly》1990,121(5):413-419
Summary Mixtures of positional isomers of trisubstituted ferrocenes can conveniently be separated on a preparative scale by applying medium-pressure liquid chromatography to suitable intermediates. By this technique formyl, hydroxymethyl, and dimethylaminomethyl 1,2-dimethyl-and 1,2-tetramethylene ferrocene, resp., (2, 3, 4 and6, 7, 8, resp.) were prepared as pure isomers (on a gramscale) by appropriate interconversion and chromatographic separation steps.
Präparative Isomerentrennung von trisubstituierten Ferrocenen. 69. Mitt. über Ferrocenderivate
Zusammenfassung Mischungen von stellungsisomeren, trisubstituierten Ferrocenen können auch im präparativen Maßstab unter Anwendung der Mitteldruckchromatographie auf geeignete Zwischenprodukte glatt getrennt werden. Mit Hilfe dieser Technik wurden Formyl-, Hydroxymethyl- und Dimethylaminomethyl-1,2-dimethyl- bzw. 1,2-tetramethylen-ferrocen (2, 3, 4 bzw.6, 7, 8) durch Anwendung geeigneter Umwandlungs- und Chromatographie-Schritte im Grammaßstab isomerenrein erhalten.相似文献
85.
Tae-Jeong Kim Hee-Yeol LeeEun-Sook Ryu Dong-Kyu ParkChan Sik Cho Sang Chul ShimJong Hwa Jeong 《Journal of organometallic chemistry》2002,649(2):258-267
A series of chiral C1- and C2-symmetric ferrocenyl Schiff bases (1a-c), ferrocenyl aminoalcohols (2a), ferrocenylphosphinamides (2b-c), 1,1′-ferrocenyl-diol (3), and 1,1′-ferrocenyl-disulfonamide (4) were prepared and employed as base catalysts or as ligand for titanium(IV) complexes in the asymmetric addition of diethylzinc to aromatic aldehydes. High enantioselectivity up to almost 100% ee was achieved for the alkylation of benzaldehyde and p-methoxybenzaldehyde with 1 or 3. In contrast, however, the β-aminoalcohol (2a) and phosphinamides (2b and c) that are ubiquitous classes of base catalysts for this reaction proved inefficient in our hands, regardless of the types of substrates or reaction conditions. Comparative studies show that there exist various reaction parameters governing not only chemical yields but also optical yields. These include steric and electronic environment of the substrate, the solvent, the reaction temperature, and the nature of the ferrocene moieties. 相似文献
86.
Kumar R Misra R PrabhuRaja V Chandrashekar TK 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(19):5695-5707
Syntheses, characterization and properties of expanded corrole-ferrocene conjugates are reported. Ferrocenyl group are covalently linked to the corrole macrocycle through three different spacers groups. The synthetic strategy involved prior insertion of ferrocene with spacers to the dipyrromethane unit followed by a "3+2" acid-catalyzed oxidative coupling methodology. The optical and emission data of the expanded corrole-ferrocene conjugates depend on the nature and length of the spacer groups and the maximum effects are seen where ferrocene is directly linked to the meso carbon of macrocycle. The single crystal X-ray structure of two expanded corrole-ferrocene conjugates; [22]pentaphyrin (1.1.0.1.0) with different meso substituents, clearly reveal shortening of the C-C bond length linking the meso carbon and the aryl substituent containing the ferrocene moiety relative to meso aryl substituents without ferrocene. The results suggest that an electronic interaction between the two pi systems. Electrochemical data reveal harder oxidation for the ferrocene unit in the conjugates relative to free ferrocene; this suggests the electron donating nature of the ferrocene. The first corrole ring oxidation shows easier oxidation relative to 1 and the magnitude of shifts in potential is inversely proportional to the length of spacer. The molecular first hyperpolarizabilities (beta) measured at 1064 nm by HRS method vary in the range 20-32x10(-30) esu and imply that the beta values can be increased by enhancing the number of mobile electrons in the conjugation. The conjugates form 1:1 metal complex with the Rh(I) where rhodium is coordinated to one amino and one imino nitrogen of the dipyrromethane unit. 相似文献
87.
Hao Chen Yin‐Xia Wang Yu‐Xin Luan Mengchun Ye 《Angewandte Chemie (International ed. in English)》2020,59(24):9428-9432
Twofold C?H annulation of readily available formamides and alkynes without built‐in chelating groups was achieved. Ni?Al bimetallic catalysis enabled by a bulky BINOL‐derived chiral secondary phosphine oxide (SPO) ligand proved to be critical for high reactivity and high selectivity. This reaction uses readily available formamides as starting materials and provides a concise synthetic pathway to a broad range of chiral ferrocenes in 40–98 % yield and 93–99 % ee. 相似文献