移动火焰锋面(MFF)模型火焰锋面确定条件的进一步改进

考虑碳粒表面还原反应的移动火焰锋面模型(MFF-Ⅰ)在推导火焰锋面位置时,仅考虑了碳粒表面氧化反应的影响.本文综合考虑碳粒表面的氧化反应、还原反应对火焰锋面位置的影响,给出更严格的推导,即MFF-Ⅱ模型.在通常的燃烧工况下,改进模型MFF-Ⅱ与原始模型MFF-Ⅰ相比,预报结论基本一致.但对于较低氧浓度的工况,比如再燃、气化问题,改进模型MFF-Ⅱ同样可以给出可信的预报结果,而这是MFF-Ⅰ模型所不及的.     

氢气流量对混合物理化学气相沉积法制备MgB_2超薄膜的影响

用混合物理化学气相沉积法(Hybrid physical-chemical vapor deposition简称为HPCVD)制备了MgB2超薄膜.在背景气体压强、B2H6的流量和成膜时间等条件一定的情况下,当氢气的流量从200到400sccm范围内变化时,观察了其对成膜的影响.结果显示,随氢气流量增大,膜表面粗糙度增大,同时膜面的连接性变好,伴随着样品的超导转变温度得到提高.对于平均厚度是10nm和15nm的样品,氢气流量分别是200sccm和300sccm时,Tc分别是26K和33K与28K和37K.     

Near-surface turbulence in the atmospheric boundary layer

Measurements of the near-surface turbulence in the atmospheric boundary layer have been made using hot-wire probes above the salt flats of northwestern Utah, where the momentum thickness Reynolds number, R_θ, is O(10⁶), and the surface is smooth and nearly devoid of flow obstructions. The measurements were made with arrays of up to 24 parallel straight sensors and with a modular 12-sensor probe capable of measuring all of the components of the instantaneous velocity vector and velocity gradient tensor. Measurements were also made in a laboratory wind tunnel at R_θ=1730 using 22 straight sensors. The data analysis focuses on the effects of the Reynolds number on turbulence properties and on the physics of the dissipation rate of turbulent kinetic energy.Some properties are found to be dependent on the Reynolds number when normalized with inner variables, while others are not. Among those that show the significant Reynolds number dependence are the rms and the skewness factor of the streamwise velocity fluctuations.Significant differences in flow structure, particularly those related to high rates of dissipation, are implied by the data. The joint PDF and covariance integrand of streamwise and wall normal vorticity fluctuations show less preferred orientation of the vorticity vector in the buffer layer at R_θ of O(10⁶) than at R_θ=1070. The largest contribution to the dissipation rate, at O(10⁶) is by the ∂w/∂z velocity gradient, while this term makes a quite small contribution to the dissipation rate at low R_θ. Here w and z are the spanwise velocity fluctuations and direction, respectively. Conditional analysis in the streamwise-wall normal (x−y) plane based on high instantaneous dissipation rate shows that the typical high dissipation rate events are generally similar at high and low Reynolds numbers, but display some significant differences.     

高阶PMD统计特性研究

讨论了三阶偏振模色散(PMD)的统计特性及其对于高阶PMD补偿系统的影响.数值模拟结果表明,随着即时差分群时延(DGD)的增加,二阶PMD单位矢量旋转速率的统计覆盖范围的变化趋势与主偏振态(PSP)旋转斜率的相应变化正好相反.此外,随着即时DGD的增加,二阶PMD模值的统计覆盖范围不断增加,使得高速光通信系统中高阶PMD补偿的实现将更加困难.     

Kinetic study of electrochemically induced Michael reactions of o‐benzoquinones with 2‐acetylcyclohexanone and 2‐acetylcyclopentanone

The reaction of electrochemically generated o‐benzoquinones ( 2a‐f ) as Michael acceptors with 2‐acetylcyclohexanone (ACH) and 2‐acetylcyclopentanone (ACP), as nucleophiles has been studied in various pHs using cyclic voltammetry. The results indicate that the participation of o‐benzoquinones ( 2a‐f ) in the Michael reaction with acetylcyclohexanone (ACH) to form the corresponding catechol derivatives ( 4a‐f ). Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. Copyright © 2007 John Wiley & Sons, Ltd.     

二次风率对分级进风燃烧室内湍流燃烧与NOx生成的影响

本文在分级进风燃烧室的热态实验装置上,测量了燃烧室内湍流燃烧的温度场和组分浓度场,研究了分级进风的流量比率即二次风率对燃烧及NOx生成的影响.得到了四组不同二次风率下燃烧室内气体温度和O2、CO2、CO与NO浓度的分布.     

The Tunneling Radiation Characteristics of Kerr-Newman de Sitter Black Hole

The strictly thermal spectrum in dragging coordinate system and the tunneling radiation characteristics of stationary axisymmetry Kerr-Newman de Sitter black hole is studied. The result shows that the tunneling rates at the event and cosmological horizon are related to the change of Bekenstein-Hawking entropy and that the factual radiation spectrum is not strictly pure thermal. Thus an exact correction to the Hawking thermal spectrum is present.     

Measurement and analysis of fission rates in a spherical mockup of uranium and polyethylene

Measurements of the reaction rate distribution were carried out using two kinds of Plate Micro Fission Chamber （PMFC）. The first is a depleted uranium chamber and the second an enriched uranium chamber. The material in the depleted uranium chamber is strictly the same as the material in the uranium assembly. With the equation solution to conduct the isotope contribution correction, the fission rate of 238U and 235U were obtained from the fission rate of depleted uranium and enriched uranium. Then, the fission count of 238U and 235U in an individual uranium shell was obtained. In this work, MCNP5 and continuous energy cross sections ENDF/BV.0 were used for the analysis of fission rate distribution and fission count. The calculated results were compared with the experimental ones. The calculation of fission rate of DU and EU were found to agree with the measured ones within 10% except at the positions in polyethylene region and the two positions near the outer surface. Because the fission chamber was not considered in the calculation of the fission counts of 238U and 235U, the calculated results did not agree well with the experimental ones.     

Mechanistic study of the reaction of methyl peroxy radical (CH3O2) with formaldehyde (CH2O)

ABSTRACT

A direct dynamic study on the reactions of CH₃O₂?+?CH₂O was carried out over the temperature range of 300–1500?K. All stationary points were calculated with the M06-2X/6-311++G(d,p) level of theory and identified for local minimum. The energetic parameters were refined at QCISD (T)/cc-pVTZ and CCSD (T)/cc-pVTZ levels of theory. Three channels were explored and a reaction of hydrogen abstraction from CH₂O by CH₃O₂ was identified as dominant channel which involves the formation of a prereactive complex in the entrance channel. The rate coefficient of the dominant channel was calculated with TST and TST/Eck and the Eckart tunnelling effect is only important over the lower temperature region. The calculated rate coefficient of the dominant channel has positive temperature dependence and agrees reasonably with the available literature data.