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81.
Ying Lv Bofeng Zhang Guobing Zou Xiaodong Yue Zhikang Xu Haiyan Li 《Entropy (Basel, Switzerland)》2022,24(7)
Domain adaptation aims to learn a classifier for a target domain task by using related labeled data from the source domain. Because source domain data and target domain task may be mismatched, there is an uncertainty of source domain data with respect to the target domain task. Ignoring the uncertainty may lead to models with unreliable and suboptimal classification results for the target domain task. However, most previous works focus on reducing the gap in data distribution between the source and target domains. They do not consider the uncertainty of source domain data about the target domain task and cannot apply the uncertainty to learn an adaptive classifier. Aimed at this problem, we revisit the domain adaptation from source domain data uncertainty based on evidence theory and thereby devise an adaptive classifier with the uncertainty measure. Based on evidence theory, we first design an evidence net to estimate the uncertainty of source domain data about the target domain task. Second, we design a general loss function with the uncertainty measure for the adaptive classifier and extend the loss function to support vector machine. Finally, numerical experiments on simulation datasets and real-world applications are given to comprehensively demonstrate the effectiveness of the adaptive classifier with the uncertainty measure. 相似文献
82.
Sarvesh Kumar Jos Romero Michael Probst Thana Maihom Gustavo García Paulo Limo-Vieira 《Molecules (Basel, Switzerland)》2022,27(15)
The geometrical effect of chlorine atom positions in polyatomic molecules after capturing a low-energy electron is shown to be a prevalent mechanism yielding Cl2−. In this work, we investigated hexachlorobenzene reduction in electron transfer experiments to determine the role of chlorine atom positions around the aromatic ring, and compared our results with those using ortho-, meta- and para-dichlorobenzene molecules. This was achieved by combining gas-phase experiments to determine the reaction threshold by means of mass spectrometry together with quantum chemical calculations. We also observed that Cl2− formation can only occur in 1,2-C6H4Cl2, where the two closest C–Cl bonds are cleaved while the chlorine atoms are brought together within the ring framework due to excess energy dissipation. These results show that a strong coupling between electronic and C–Cl bending motion is responsible for a positional isomeric effect, where molecular recognition is a determining factor in chlorine anion formation. 相似文献
83.
Kevin D. Oliphant Marius Karger Yoichi Nakanishi Ralf R. Mendel 《Molecules (Basel, Switzerland)》2022,27(12)
Molybdenum (Mo) is an essential trace element in all kingdoms of life. Mo is bioavailable as the oxyanion molybdate and gains biological activity in eukaryotes when bound to molybdopterin, forming the molybdenum cofactor. The imbalance of molybdate homeostasis results in growth deficiencies or toxic symptoms within plants, fungi and animals. Recently, fluorescence resonance energy transfer (FRET) methods have emerged, monitoring cellular and subcellular molybdate distribution dynamics using a genetically encoded molybdate-specific FRET nanosensor, named MolyProbe. Here, we show that the MolyProbe system is a fast and reliable in vitro assay for quantitative molybdate determination. We added a Strep-TagII affinity tag to the MolyProbe protein for quick and easy purification. This MolyProbe is highly stable, resistant to freezing and can be stored for several weeks at 4 °C. Furthermore, the molybdate sensitivity of the assay peaked at low nM levels. Additionally, The MolyProbe was applied in vitro for quantitative molybdate determination in cell extracts of the plant Arabidopsis thaliana, the fungus Neurospora crassa and the yeast Saccharomyces cerevisiae. Our results show the functionality of the Arabidopsis thaliana molybdate transporter MOT1.1 and indicate that FRET-based molybdate detection is an excellent tool for measuring bioavailable Mo. 相似文献
84.
Recent results by the authors on proton diffractive dissociation (single, double and central) in the low-mass resonance region with emphasis on the LHC kinematics are reviewed and updated. Based on the previous ideas that the contribution of the inelastic proton–Pomeron vertex can be described by the proton structure function, the contribution of the inelastic Pomeron–Pomeron vertex appearing in central diffraction is now described by a Pomeron structure function. 相似文献
85.
以基于准位相匹配和频与差频级联二阶非线性[X^(2):X^(2)]基础上的全光开关的理论分析作指导,进行了周期极化铌酸锂晶体(PPLN)和退火质子交换光波导(APE)的实验制备,利用所研制的PPLN-APE器件,以自行研制的工作波长为1.54μm的被动调Q掺钴铝酸镁激光器作为控制光源,以工作波长为1.5μm的连续二极管激光器为信号光源进行了级联二阶非线性全光开关实验。当控制光峰值功率为3kw,信号光功率为1mW时,实现13%的开关效率,分析了进一步提高全光开关性能的途径。 相似文献
86.
A modified form of the steady state treatment for the determination of excited state proton transfer rate constants was successfully applied to a variety of oxygen and nitrogen center aromatic excited acids. These compounds shared the characteristic of being more acidic in the lowest excited singlet state (S1) than in the ground electronic state (S0) and of requiring a concentrated mineral acid medium for protonation. This treatment was extended to phenanthridone, the lactam of 6-hydroxyphenanthridine, which is a weak enough base in the ground and the excited states to require moderately concentrated mineral acids for protonation, and becomes a stronger base in the excited state than it is in the ground state. Phenanthridone exists as an -lactam and is a weaker base in the ground and excited states than the -lactams derived from 2-hydroxypyridine, 2-hydroxyquinoline, and 1-hydroxyisoquinoline. It is also a much weaker base than the vinylogous -lactams. The reasons for this are discussed here. 相似文献
87.
H. A. Das 《Isotopes in environmental and health studies》2013,49(5):241-244
The leaching of microconstituents from granular solid wastes is often studied by column experiments. The underlying assumption is that the flow is of the one-compartment or “backmix” type. The influence of small deviations from this ideal situation on the outcome of the leaching experiment depends slightly on the specific mass-transfer function of the trace involved. The deviation itself may be measured by a simple separate radiotracer experiment. 相似文献
88.
Rolf Appel Nikolaos Siabalis 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):273-274
Abstract Reactions of carbonyl cyclopentadienyl hydrides from molybdenum and tungsten with 1,4-diphosphabuta-1,3-diene yield metalla-diphospha-pentadiene with a metal-phosphorus-double bond. Metalla-diphosphapentadiene mit einer Metall-Phosphor-Doppelbindung werden durch Umsetzung von Carbonylcyclopentadienylhydriden des Molybdäns und Wolframs mit einem 1,4-Diphospha-buta-1,3-dien erhalten. 相似文献
89.
Ying Liang Delong Liu Hou Chen 《Journal of polymer science. Part A, Polymer chemistry》2013,51(9):1963-1968
Well‐defined high oil‐absorption resin was successfully prepared via living radical polymerization on surface of polystyrene resin‐supported N‐chlorosulfonamide group utilizing methyl methacrylate and butyl methacrylate as monomers, ferric trichloride/iminodiacetic acid (FeCl3/IDA) as catalyst system, pentaerythritol tetraacrylate as crosslinker, and L ‐ascorbic acid as reducing agent. The polymerization proceeded in a “living” polymerization manner as indicated by linearity kinetic plot of the polymerization. Effects of crosslinker, catalyst, macroinitiator, reducing agent on polymerization and absorption property were discussed in detail. The chemical structure of sorbent was determined by FTIR spectrometry. The oil‐absorption resin shows a toluene absorption capacity of 21 g g?1. The adsorption of oil behaves as pseudo‐first‐order kinetic model rather than pseudo‐second‐order kinetic model. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
90.
Muhammad Ejaz Bhanukiran Sunkara Lakhinder Kamboj Jibao He Vijay T. John Noshir S. Pesika Scott M. Grayson 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3314-3322
An efficient and novel one‐pot process is developed to immobilize the atom transfer radical polymerization (ATRP) initiators onto the surface of fully pyrolyzed carbon hard spheres (CHSs) via a radical trapping process from the in situ thermal decomposition of bis(bromomethylbenzoyl)peroxide. The CHSs do not require any additional preparative treatment prior to the initiator immobilization. Styrene and methyl methacrylate are polymerized onto initiator‐immobilized CHSs by surface‐initiated atomic transfer radical polymerization (SI‐ATRP). Samples are characterized using Fourier transform infrared, thermogravimetric analysis, scanning electron microscopy, and transmission electron microscopy. These methods of characterization confirmed that all the CHSs are coated with a uniform layer of grafted polymer. This efficient, one‐pot immobilization of ATRP‐initiators represents an exceptionally simple route for the rapid preparation of various polymer‐coated carbon‐based nanomaterials using SI‐ATRP. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3314–3322 相似文献