全文获取类型
收费全文 | 5802篇 |
免费 | 560篇 |
国内免费 | 1027篇 |
专业分类
化学 | 6145篇 |
晶体学 | 158篇 |
力学 | 54篇 |
综合类 | 19篇 |
数学 | 136篇 |
物理学 | 877篇 |
出版年
2024年 | 17篇 |
2023年 | 78篇 |
2022年 | 195篇 |
2021年 | 235篇 |
2020年 | 257篇 |
2019年 | 242篇 |
2018年 | 205篇 |
2017年 | 217篇 |
2016年 | 237篇 |
2015年 | 236篇 |
2014年 | 299篇 |
2013年 | 490篇 |
2012年 | 356篇 |
2011年 | 347篇 |
2010年 | 257篇 |
2009年 | 331篇 |
2008年 | 384篇 |
2007年 | 359篇 |
2006年 | 328篇 |
2005年 | 280篇 |
2004年 | 289篇 |
2003年 | 218篇 |
2002年 | 466篇 |
2001年 | 158篇 |
2000年 | 130篇 |
1999年 | 109篇 |
1998年 | 106篇 |
1997年 | 74篇 |
1996年 | 78篇 |
1995年 | 78篇 |
1994年 | 74篇 |
1993年 | 48篇 |
1992年 | 48篇 |
1991年 | 39篇 |
1990年 | 22篇 |
1989年 | 14篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 14篇 |
1985年 | 14篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 6篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1972年 | 1篇 |
排序方式: 共有7389条查询结果,搜索用时 15 毫秒
31.
Mahelet Aweke Tadesse Carlo Galli Patrizia Gentili 《Journal of Physical Organic Chemistry》2011,24(7):529-538
The aminoxyl radical 6‐trifluoromethyl‐benzotriazol‐N‐oxyl (TFNO) has been generated from the parent hydroxylamine 6‐CF3‐1‐hydroxy‐benzotriazole (TFBT) by one‐electron oxidation with a CeIV salt and characterized by spectrophotometry and cyclic voltammetry (CV). Rate constants of H‐abstraction (kH) by TFNO from a number of H‐donor benzylic substrates have been determined spectrophotometrically in MeCN solution at 25 °C. A radical H‐atom transfer (HAT) route of oxidation is substantiated for TFNO by several pieces of evidence. The kinetic data also testify the relevance of stereoelectronic effects upon the HAT reactivity of TFNO. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
32.
In general, both stoichiometric and catalytic reactions of organometallic complexes involve breaking and forming metal–ligand bonds. Therefore, an evaluation of the thermodynamics of such reactions requires the knowledge of metal–ligand bond energies (BDEs). The homolytic Fe? C bond dissociation energies [i.e., ΔHhomo(Fe? C)s] of 12 para‐substituted benzyldicarbonyl(η5‐cyclopentadienyl)iron, p‐G‐C6H4CH2Fp [1,G = NO2, CN, COMe, CO2Me, CF3, Br, Cl, F, H, Me, MeO, NMe2; Fp = (η5‐C5H5)(CO)2Fe] and 12 para‐substituted α‐cyanobenzyldicarbonyl (η5‐cyclopentadienyl)iron, p‐G‐PANFp [2,PAN = C6H4CH(CN)] were studied using Hartree–Fock (HF) and density functional theory (DFT) methods with large basis sets. The results show that BP86 and TPSSTPSS can provide the best price/performance ratio and more accurate predictions in the study of ΔHhomo(Fe? C)s. The B3LYP method satisfactorily predicts the α and remote substituent effects on ΔHhomo(Fe? C)s [ΔΔHhomo(Fe? C)s]. The fair correlations [r = 0.97 (g, 1), 0.99(g, 2)] of ΔΔHhomo(Fe? C)s of series 1 and 2 with the substituent σ constants imply that the para substituent effects on ΔHhomo(Fe? C)s originate mainly from polar effects, but those on radical stability originate from both spin delocalization and polar effects. The molecule stabilization effects (MEs) causes that not only the magnitude of ΔΔHhomo(Fe? C)s(1) varies significantly but also the direction changes from S‐pattern to O‐pattern. ΔΔHhomo(Fe? C)s(2) were found to conform to the Capto‐dative Principle. The detailed knowledge of the factors that determine the Fp? C bond strengths would greatly aid in understanding reactivity patterns in many processes. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
33.
Hui Li Yonggang Yang Dapeng Yang Yufang Liu Jinfeng Sun 《Journal of Physical Organic Chemistry》2014,27(3):170-176
The time‐dependent density functional theory method was performed to investigate the excited‐state hydrogen‐bonding dynamics of N‐(2‐hydroxyethyl)‐1,8‐naphthalimide (2a) and N‐(3‐hydroxyethyl)‐1,8‐naphthalimide (3a) in methanol (meoh) solution. The ground and excited‐state geometry optimizations, electronic excitation energies, and corresponding oscillation strengths of the low‐lying electronically excited states for the complexes 2a + 2meoh and 3a + 2meoh as well as their monomers 2a and 3a were calculated by density functional theory and time‐dependent density functional theory methods, respectively. We demonstrated that the three intermolecular hydrogen bonds of 2a + 2meoh and 3a + 2meoh are strengthened after excitation to the S1 state, and thus induce electronic spectral redshift. Moreover, the electronic excitation energies of the hydrogen‐bonded complexes in S1 state are correspondingly decreased compared with those of their corresponding monomer 2a and 3a. In addition, the intramolecular charge transfer of the S1 state for complexes 2a + 2meoh and 3a + 2meoh were theoretically investigated by analysis of molecular orbital. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
34.
Effects of the structural order of canthaxanthin on the Raman scattering cross section in various solvents: A study by Raman spectroscopy and ab initio calculation 下载免费PDF全文
In this work,we measure the Raman scattering cross sections(RSCSs) of the carbon-carbon(CC) stretching vibrational modes of canthaxanthin in benzene,acetone,n-heptane,cyclohexane,and m-xylene.It is found that the absolute RSCS of CC stretching mode of canthaxanthin reaches a value of 10 24 cm 2 ·molecule 1 ·sr 1 at 8×10 5 M,which is 6 orders of magnitude larger than general RSCS(10 30 cm 2 ·molecule 1 ·sr 1),and the RSCSs of canthaxanthin in various solvents are very different due to the hydrogen bond.A theoretical interpretation of the magnetic experimental results is given,which is introduced in a qualitative nonlinear model of coherent weakly damped electron-lattice vibration in the structural order of polyene chains.In addition,the optimal structure and the bond length alternation(BLA) parameter of canthaxanthin are calculated using quantum chemistry calculation(at the b3lyp/6-31g(d,p) level of theory).The theoretical calculations are in good agreement with the experimental results.Furthermore,the combination of Raman spectroscopy and the quantum chemistry calculation study would be a quite suitable method of studying the structures and the properties of the π-conjugated systems. 相似文献
35.
采用密度泛函B3LYP(Becke,three-parameter,Lee-Yang-PaH)/6-311++G**和HF(Hartree Fock)/6-311++G**方法,从理论上探讨了2-F-环氧丁烷分别与几种常见而重要的生物小分子咪唑(Iminazole)、噻唑(Thiazole)和恶唑(Oxazo1e)等分子间的弱相互作用,发现分子间同时存在N…H常规氢键和C-F…H-C赝氢键结构.弱相互作用能计算表明3个复合物的相对稳定性相当.计算结果表明,在C-F…H-C赝氢键结构中,与电子的直接供体F密切相关的共价键C-F键长增大,伸缩振动的频率红移,而作为电子受体的H-C基团,其C-H键伸缩振动光谱蓝移;另外,电子密度拓扑性质表明C-F…H-C赝氢键的共价性及离子性均与常规氢键相当. 相似文献
36.
Temporal electronic structure of non-resonant Raman excited virtual state of P-nitroaniline by 514 nm excitation via bond polarisabilities 下载免费PDF全文
We have studied the temporal bond polarisabilities of para-nitroaniline from the Raman intensities by the algorithm proposed by Wu et al.in 1987 (Tian B,Wu G,Liu G 1987 J.Chem.Phys.87 7300).The bond polarisabilities provide much information concerning the electronic structure of the non-resonant Raman excited virtual state.At the initial moment by the 514.5 nm excitation,the tendency of the excited electrons (mapped out by the bond polarisabilities) is to spread to the molecular periphery,and the electronic structure of the Raman virtual state is close to the pseudo-quinonoidic state.When the final stage of relaxation is approached,the bond polarisabilities of those peripheral bonds relax faster than those closer to the molecular core,the phenyl ring.The molecule is in the benzenoidic form as demonstrated by the bond polarisabilities after relaxation. 相似文献
37.
38.
高压液态重水的拉曼光谱研究 总被引:1,自引:1,他引:1
应用金刚石压腔结合拉曼光谱技术研究了重水在291 K,0.1~800 MPa条件下的拉曼谱图。结果表明:压力增大的过程中,重水的拉曼伸缩振动光谱向低频方向移动,并且频移和压力基本呈线性相关。频移没有突变,没有发生相的转变。将重水的拉曼谱峰分解为代表分子内O—D振动的高频峰和代表分子间氢键振动的低频峰。研究这两种不同类型谱峰的性质,发现代表分子间氢键的低频峰峰面积在不同的压力范围内呈现出不同的变化特征,压力对分子间氢键的影响并不是持续不变的。拉曼峰的峰面积反映的是产生这种拉曼峰的振动的数目,峰面积的变化反映了特征振动数目的变化。由于分子间氢键的强相互作用,水分子总是倾向于形成对称的空间五分子四面体结构,因此最大峰面积代表了最稳定的五分子团簇结构。 相似文献
39.
N. Pongali Sathya Prabu 《Phase Transitions》2013,86(7):592-607
In this study, complexes belonging to supramolecular hydrogen-bonded liquid crystal homologous series are synthesized and characterized. Hydrogen bond is formed between p-n-alkyloxy benzoic acids (nBAO, where n?=?5–11) and chlorobenzoic acid (ClBAO), respectively. The isolated homologues are characterized by various techniques such as polarizing optical microscopic (POM) studies, differential scanning calorimetry (DSC), and Fourier transform–infrared spectroscopy. Based on the POM and DSC studies, the phase diagram has been constructed and discussed. A new smectic ordering, labeled as smectic R, has been characterized, which exhibits a ribbon-like texture. This phase is observed in the complexes pertaining to the higher homologous series. Tilt angle in this phase has been experimentally deduced and the results are fitted to the power law which concurs with the mean-field theory predicted value. Optical shuttering action in the homologue has been detected in the nematic phase and the results are also discussed. 相似文献
40.
Ariel Fernández 《Annalen der Physik》2017,529(6)
A theory of dielectric response of water under nanoscale confinement was long overdue. This work addresses the problem by establishing a relation between dielectric response and hydrogen‐bond frustration subsumed in a non‐Debye polarization term. The results hold down to the single‐molecule contribution and are validated vis‐à‐vis experimental measurements on a system where dielectric modulation entails removal of a single water molecule. The frustrated dielectric response down to molecular scales is assessed by contrasting two enantiomeric ligands in association with the same protein, with the complexes differing in the removal of a single interfacial water molecule.