全文获取类型
收费全文 | 2671篇 |
免费 | 157篇 |
国内免费 | 524篇 |
专业分类
化学 | 3101篇 |
晶体学 | 8篇 |
力学 | 11篇 |
综合类 | 11篇 |
数学 | 3篇 |
物理学 | 218篇 |
出版年
2024年 | 2篇 |
2023年 | 18篇 |
2022年 | 38篇 |
2021年 | 43篇 |
2020年 | 69篇 |
2019年 | 60篇 |
2018年 | 55篇 |
2017年 | 89篇 |
2016年 | 95篇 |
2015年 | 75篇 |
2014年 | 101篇 |
2013年 | 272篇 |
2012年 | 111篇 |
2011年 | 144篇 |
2010年 | 128篇 |
2009年 | 148篇 |
2008年 | 165篇 |
2007年 | 180篇 |
2006年 | 184篇 |
2005年 | 177篇 |
2004年 | 169篇 |
2003年 | 141篇 |
2002年 | 123篇 |
2001年 | 89篇 |
2000年 | 102篇 |
1999年 | 83篇 |
1998年 | 59篇 |
1997年 | 52篇 |
1996年 | 68篇 |
1995年 | 66篇 |
1994年 | 58篇 |
1993年 | 50篇 |
1992年 | 48篇 |
1991年 | 20篇 |
1990年 | 16篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有3352条查询结果,搜索用时 31 毫秒
61.
Gafarova Yu. T. Dekhtyar" E. F. Dekhtyar" T. F. Fatykhov A. A. Spirikhin L. V. Vostrikova O. S. Zlotskii S. S. Dokichev V. A. 《Russian Chemical Bulletin》2003,52(4):1003-1008
Under mild conditions, trialkylalanes (Et3Al and Bui
3Al) in chlorine-containing solvents (CH2Cl2 or ClCH2CH2Cl) react with cyclic acetals and orthoformates to form glycol monoethers and dialkylacetals, respectively, in high yields. The 1H NMR spectroscopic data demonstrate that CH2Cl2 or ClCH2CH2Cl interacts with Bui
3Al. 相似文献
62.
P. M. Kochergin I. A. Mazur G. K. Rogul'chenko E. V. Aleksandrova B. E. Mandrichenko 《Chemistry of Heterocyclic Compounds》2001,37(2):224-226
Two novel preparative methods have been developed for the synthesis of 2,3-dihydroimidazo[1,2-a]pyrimidine from 2-aminopyrimidine. These are the reaction with 1,2-dibromoethane and also the reaction with ethylene chloro(bromo)hydrin, subsequent treatment of 1--hydroxyethyl-2-imino-1,2-dihydropyrimidine with thionyl chloride, and cyclization of the intermediate 1--chloroethyl-2-imino-1,2-dihydropyrimidine in the presence of sodium hydroxide. 相似文献
63.
A method based on in-tube solid-phase microextraction and capillary zone electrophoresis (CZE) was proposed for simultaneously determining four amphetamines (amphetamine, methamphetamine, 3,4-methylenedioxyamphetamine, and 3,4-methylenedioxymethamphetamine) in urine. A poly(methacrylic acid-ethylene glycol dimethacrylate) monolithic capillary column, which can provide sufficient extraction efficiency, was introduced for the extraction of amphetamines from urine samples. The hydrophobic main chains and acidic pendant groups of the monolithic column make it a superior material for extraction of basic analytes from aqueous matrix. After extraction, the samples were analyzed by CZE. The best separation was achieved using a buffer composed of 0.1 M disodium hydrogen phosphate (adjusted to pH 4.5 with 1 M hydrochloric acid) and 20% methanol v/v, with a temperature and voltage of 25 degrees C and 20 kV, respectively. By applying electrokinetic injection with field-amplified sample stacking, detection limits of 25-34 microg/L were achieved. Excellent method of reproducibility was found over a linear range of 0.1-5 mg/L. Determination of these analytes from abusers' urine sample was also demonstrated. 相似文献
64.
65.
P. Hazot J. P. Chapel C. Pichot A. Elaissari T. Delair 《Journal of polymer science. Part A, Polymer chemistry》2002,40(11):1808-1817
Monodisperse, thermosensitive poly(N‐ethyl methacrylamide) microgel particles were prepared by the batch precipitation/emulsion polymerization of water‐soluble N‐ethyl methacrylamide and the hydrophobic crosslinker ethylene glycol dimethacrylate initiated by potassium persulfate. Particular attention was paid to the effect of the crosslinker agent on the polymerization process (kinetics, conversion, and water‐soluble oligomer content). Particles were characterized in terms of their size distribution and swelling capacity. A polymerization mechanism for the water‐soluble monomer and non‐water‐soluble crosslinker is proposed and discussed on the basis of a combination of both emulsion and precipitation polymerization processes. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1808–1817, 2002 相似文献
66.
67.
The first histidine catalyzed direct aldol reactions of ketones with nitrobenzaldehydes in water and in poly(ethylene glycol) (PEG) were reported. It reveals that histidine is a good aldol catalyst for synthesis of β-hydroxylketones in water and in PEG, giving good to excellent yields of the respective products. Better enantioand regioselectivity were achieved using low molecular weight PEG as the media. The results show that histidine and PEG-200 or -300 may constitute a promising environmentally benign system for asymmetric synthesis of β-hydroxylketones. 相似文献
68.
69.
70.
3类手性配体d-10-樟脑磺酸及其衍生物,α-(-)-羟蒎酮及其衍生物,又恶唑啉6衍生物分别与铜(Ⅱ)形成手性铜配合物,催化重氮乙酸酯与1,1-二苯乙烯或异丁烯的环丙烷化加成反应,得到光学活性环丙羧酸酯,不对称诱导最高可达95%e.e.。 相似文献