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141.
Intumescent flame retardant (IFR) has received the considerable attention ascribed to the inherent advantages including non‐halogen, low toxicity, low smoke release and environmentally friendly. In this work, a novel charring agent poly (piperazine phenylaminophosphamide) named as PPTA was successfully synthesized and characterized by Fourier transform infrared spectra (FTIR) and X‐ray photoelectron spectroscopy (XPS). Then, a series of flame‐retardant EP samples were prepared by blending with ammonium polyphosphate (APP) and PPTA. Combustion tests include oxygen Index (LOI), vertical Burning Test (UL‐94) and cone calorimeter testing,these test results showed that PPTA greatly enhances the flame retardancy of EP/APP. According to detailed results, EP containing 10 wt% APP had a LOI value of 30.2%,but had no enhancement on UL‐94 rating. However, after both 7.5 wt% APP and 2.5 wt% PPTA were added, EP‐7 passed UL‐94 V‐0 rating with a LOI value of 33.0%. Moreover, the peak heat release rate (PHRR) and peak of smoke product rate (PSPR) of EP‐7 were greatly decreased. Meanwhile, the flame‐retardant mechanism of EP‐7 was investigated by scanning electron microscopy (SEM), thermogravimetric analysis/infrared spectrometry (TG‐IR) and X‐ray photoelectron spectroscopy (XPS). The corresponding results presented PPTA significantly increased the density of char layer, resulting in the good flame retardancy. 相似文献
142.
采用酸性磷酸酯作为掺杂剂对本征态聚苯胺(EB)进行掺杂,制备了可在聚氨酯丙烯酸酯中进行纳米分散的导电聚苯胺(ES),其分散粒径分布为60~765 nm之间,进而制备了不含重金属的紫外光固化聚苯胺防腐涂料.随着体系中导电聚苯胺含量从0.5 wt%增大5.0 wt%,粒径从60~100 nm增加到190~765 nm.导电聚苯胺含量增大,导致了ES发生团聚,从而粒径增大,进而降低防腐涂层的致密性.当ES含量为1.0wt%时,粒径在110~180 nm之间,防腐涂层在3.5 wt%的Na Cl水溶液中浸泡2400 h后,其0.1 Hz下的绝对阻抗值(|Z|_(0.1 Hz))仍高于1.0×10~8Ωcm~2,同时45~50μm的防腐涂层在划叉中性盐雾试验中,500 h内没有出现起泡现象,且锈蚀宽度小于1 mm,表现出优异的防腐性能. 相似文献
143.
研究了炭纤维织物/环氧(CF/EP)复合材料与45#钢在环-环端面干摩擦状态下的摩擦磨损特性,考查了制备工艺和MoS2与石墨不同配比等对CF/EP复合材料干摩擦性能的影响,采用扫描电子显微镜观察复合材料及其偶件磨损表面形貌.结果表明:半干法制备的环氧树脂体积分数为40%的CF/EP复合材料的摩擦系数稳定;纯CF/EP复合材料主要表现为粘着磨损特性;MoS2与石墨改性后复合材料摩擦磨损性能明显改善,质量比为1.5∶1的MoS2与石墨改性CF/EP复合材料具有最佳的摩擦磨损性能,其稳态摩擦系数为0.14~0.15,磨损量3.15×10-5 mg/r. 相似文献
144.
以松香,环氧氯丙烷,甲醛及苯酚等为主要原料,合成了一种新型的环氧树脂。通过正交实验法确定了环氧化反应的最佳实验条件,即环氧化温度90℃,碱用量13 g,催化剂为cat 1,其最佳用量为0.018 mol,环氧氯丙烷的用量为50 g,碱浓度为30%(以上数值均以松香用量为70 g时计)。在最佳实验条件下合成得到了松香改性酚醛环氧树脂(简称RAPE),并用HPLC、FT-IR、NMR对其进行结构表征。结果表明,得到的RAPE其环氧值为0.28 mol/100g,平均聚合度约为3.4,酚羟基和树脂酸上的羧基基本反应完全,得到一种新型的缩水甘油醚型和缩水甘油酯型的环氧树脂。 相似文献
145.
Shuai Zhao Zhongxin Song Jian Cui Chaoqin Li Yehai Yan 《Journal of polymer science. Part A, Polymer chemistry》2012,50(21):4548-4556
Uniform dispersion and strong interfacial interaction are two critical prerequisites for application of single‐walled carbon nanotubes (SWNTs) in polymer composites. To endow the composites with multifunctional feature, no damage on the chemical/electronic structure of SWNTs is also usually required. With these ends in view, two epoxide‐containing pyrene derivatives (EpPys) were designed, synthesized, and used as reactive noncovalent dispersants for developing multifunctional epoxy/SWNT composites. One having longer chain length between epoxide group and pyrene moiety, that is, EpPy‐16, shows higher dispersing efficiency and provides the nanotube dispersion with better stability, thus picking up for subsequent studies. Systematic characterization on SWNT/EpPy‐16 hybrid demonstrates that 13.2 wt % of EpPy‐16 is adsorbed on the SWNT surface through strong π‐stacking interaction, and intrinsic electronic structure of SWNTs is basically reserved. The solution‐based process adopted here preserves the good SWNT dispersing state in dispersion into the composites. Simultaneously, enhanced interfacial interaction is also realized by using EpPy‐16, which interacts noncovalently with SWNT but connects covalently to epoxy network. As a result, the composites acquire 37 and 22% increments in tensile strength and Young's modulus, respectively, relative to that of neat resin. A low‐electrical percolation threshold of 0.1 wt % SWNTs and improved thermal properties were also observed. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
146.
Yasemin Yuksel Durmaz Marco Sangermano Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):2862-2868
A novel method for surface modification of UV‐cured epoxy network was described. Photoinitiated cationic copolymerization of a bisepoxide, namely 3,4‐epoxy cyclohexylmethyl 3,4‐epoxycyclohexanecarboxylate (EEC) with epibromohydrine (EBH) by using a cationic photoinitiator, [4‐(2‐methylpropyl)phenyl]4‐methylphenyl‐iodonium hexafluorophosphate, in propylene carbonate solution was studied. The real‐time Fourier transform infrared spectroscopic, gel content determination and thermal characterization studies revealed that both EEC and EBH monomers take part in the polymerization and epoxy network possessing bromomethyl functional groups was obtained. The bromine functions of the cured product formed on the glass surface were converted to azide functionalities with sodium azide. Independently prepared alkyne functional poly(ethylene glycol) (PEG) was subsequently anchored to azide‐modified epoxy surface by a “click” reaction. Surface modification of the network through incorporation of hydrophilic PEG chain was evidenced by contact angle measurements. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2862–2868, 2010 相似文献
147.
Ludovic Leymarie Jérôme Dupuy Estelle Villegas Philippe Chaumont Nathalie Sintes‐Zydowicz Etienne Fleury 《Journal of polymer science. Part A, Polymer chemistry》2012,50(19):4145-4154
Novel oligodimethylsiloxane‐based polymers with alkyl side chain were synthesized in bulk by step‐growth polymerization between α,ω‐glycidyl ether oligodimethylsiloxanes and a monoalkylamine in the absence of catalyst and at temperatures ranging between 80 and 180 °C. Matrix assisted laser desorption ionization time of flight results attested for the high reactivity of the amine functions with the glycidyl groups and revealed that the main polymer structure was (A2B2)n type with alkyl moieties as dangling chains. No etherification was observed during the reaction even at high temperatures and the nature of the end groups strongly depended on the molar ratio between glycidyl and amine functions. Polymerization reactions were followed by 1H NMR and the kinetics of the glycidyl‐amine reaction pointed out the dependence of temperature, molar ratio, and the molar mass of the oligodimethylsiloxane. High conversion rates were obtained, especially with the lowest molecular weight oligodimethylsiloxane. An optimized kinetic model derived from the Horie's model was discussed and permitted to correctly fit the experimental data. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
148.
David R. Harding Holly Goodrich Aaron Caveglia Mitchell Anthamatten 《Journal of Polymer Science.Polymer Physics》2014,52(14):936-945
Knowing the mechanical properties of UV‐curable resins at cryogenic conditions is important to ongoing fusion‐energy research and to emerging aerospace applications. The tensile and interfacial shear strengths of two commercially available UV‐curable resins were measured at room‐temperature and cryogenic conditions for both bulk and reduced (subnanoliter) specimen volumes. The tensile properties of cured specimens are remarkably sensitive to both testing temperature and specimen size. For one type of resin, the cold (?150 °C) tensile strength of subnanoliter specimens is ~9× larger (179 ± 19 MPa) than bulk values at room temperature. The interfacial shear strength between SiC fibers and small volumes of resin volumes is comparable to the bulk, room‐temperature tensile strength, but it varies over a wide range at ?150 °C (15–53 MPa). All resins were fully cured, and an analysis of fractured surfaces revealed microstructural features. The enhanced strength in microscopic specimens may be related to inhomogeneous stress fields that develop during cure. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 936–945 相似文献
149.
Shouji Minegishi Tetsurou Otsuka Atsushi Kameyama Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2004,42(8):2031-2042
Divinyl ether monomers containing phosphorous residues were synthesized by the addition reaction of glycidyl vinyl ether (GVE) with various phosphonic dichlorides or dichlorophosphates with quaternary onium salts as catalysts. The reaction of GVE with phenylphosphonic dichloride gave bis[1‐(chloromethyl)‐2‐(vinyloxy)ethyl]phenylphosphonate ( 1a ) in a 77% yield. The polycondensation of 1a with terephthalic acid was also carried out with 1,8‐diazabicyclo[5.4.0]undecene‐7 (DBU) as a condensing agent to afford the corresponding phosphorus‐containing polyester. A multifunctional monomer containing both vinyl ether groups and methacrylate groups was prepared by the reaction of 1a with methacrylic acid with DBU. The photoinitiated cationic polymerization of these vinyl ether compounds proceeded rapidly with bis[4‐(diphenylsulfonio)phenyl]sulfide‐bishexafluorophosphate as the cationic photoinitiator without a solvent upon ultraviolet irradiation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2031–2042, 2004 相似文献
150.
Sincethedevelopmentofmethodslformassproductionoffullerenes,therehasbeengTeatinterestinit-Manyresearchgroups'havepaidgreatattentiontothefiJllerene-dopedpolymersinceWang'discoveredinl992thatfullerene-dopedPVKhasanapparentlyincreasingphotoconductivity.WehavereportedthechendcalattachmentofCcocagestothecarbazolegroupsonpoly(epoxypropylcarbazole)(PEPC)chainsbyFriedel-Craftstypereaction'.Here,theopticalpropertiesoffullerenatedPEPCwereinvestigated,whichwillshowitsgoodphotoconductivepropeFtiesbe… 相似文献