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41.
铬(Ⅵ)与谷胱甘肽作用及其中间态配合物形成的电化学表征 总被引:2,自引:0,他引:2
本文采用电化学方法,对谷胱甘肽(GSH)与重铬酸钾的相互作用及其中间态配合物的形成过程进行研究。结果表明:在pH=5.6的HAc-NaAc缓冲溶液中,GSH浓度为Cr(Ⅵ)浓度5倍以上时,Cr(Ⅵ)与GSH作用完全并形成一新的中间态配合物,该中间态配合物于+0.21 V和+0.36 V(vs SCE)处产生一对新的氧化还原峰,UV-Vis的吸收光谱进一步证明了中间态配合物的形成。该配合物不稳定,在一定时间内缓慢分解,其电化学与UV-Vis光谱动力学信息同步。进一步探讨了GSH与Cr(Ⅵ)作用的电极反应机理。当Zn(Ⅱ)存在于该体系时,Zn(Ⅱ)对中间态配合物的生成和分解过程起着双向催化作用。 相似文献
42.
Alexander S. Bondarenko Genady A. Ragoisha 《Journal of Solid State Electrochemistry》2005,9(12):845-849
Potentiodynamic electrochemical impedance spectroscopy provides extraction of potential-dependent space charge layer capacitance
from potentiodynamic impedance spectra of non-stationary semiconductor–electrolyte interface. The new technique has been applied
for acquisition of Mott-Schottky plots of cathodically treated TiO2 anodic films. Cathodic treatment in 1 M H2SO4 increases donor density and flat band potential of TiO2. Freshly doped films show hysteresis in the space charge layer capacitance in cyclic potential scans. The subsequent cycling
eliminates the hysteresis but preserves the greater part of the doping effect.
Presented at the 4th Baltic Conference on Electrochemistry, Greifswald, 13–16 March 2005 相似文献
43.
The mass-transter characteristics of a two-phase system formed by mixing a fixed quantity (20 v/v%) of organic solvent with an aqueous ferricyanide electrolyte solution in an RDE system were studied. The Levich eqution, I1 = 0.62 nFACbD2/3v?1/6ω1/2, was found to be applicable to the two-phase system with only a minor modification in the angular velocity (ω) at Reynolds numbers between 3–5 × 104. The experimental results indicate that the interfacial tension is the most important variable for the two-phase system. One group of organic solvents with smaller interfacial tension, such as benzene or toluene, needs a modification of the Levich equation by replacing the observed angular velocity (ωo) with the true angular velocity (ωt) which was observed to be 1.1 times the observed angular velocity. For the other group with larger interfacial tension, such as n-hexane or cyclohexane, there is no need to modify the observed angular velocity. In other words, the Levich equation may be expressed as I1 = 0.65 nFACbD2/3v?1/6ω1/2 for two-phase solution if the interfacial tension is smaller than 37.0 dyne/cm. 相似文献
44.
The concentration fields, Nusselt number distributions along the electrode, and ratios of concentrations of electrochemically active components at the entrance into and exit out of an electrochemical cell are determined by numerical integration of the convective-diffusion equation for a broad range of rate constants of electrode reactions, Peclet numbers, and geometrical parameters of channels. Three regions of parameter values are revealed. At low reaction rates (K
l
< 0.5), mass transfer is completely determined by electrode kinetics; at high rates (K
l
> 20), it is completely determined by the diffusion in the gas phase; and in the intermediate region of values of K
l
it is necessary to allow for both the diffusion processes and the electrode reactions.Translated from Elektrokhimiya, Vol. 41, No. 3, 2005, pp. 317–324.Original Russian Text Copyright © 2005 by Ezin, Somov. 相似文献
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Introduction Ionchromatography (IC)hasbeenrecognizedasausefulmethodfortheseparationofinorganicanionsandcationssinceitsintroductionbySmalletal .in 1975 .1AsignificanttrendinthedevelopmentofICmethodissearchforsensitiveanduniversaldetectionmethods .Themaindet… 相似文献
48.
Summary A flow-through two electrode wall-jet cell with a platinum measuring electrode and a cell volume of 20 nl has been designed and evaluated. It has been used to detect phenols by reversed phase liquid chromatography using short micro bore columns. The linear dynamic range between the measured current and the concentration is greater than 103 (1.5×10–7–5×10–4 mol/l) and the minimum analyzable amount was found to be 10 pg for pyrocatechol. A negligible broadening in the detector permits the use of micro columns down to 0.5 mm internal diameter, packed with 5 m particles, without any substantial distortion of eluted zones.Presented at the 14th International Symposium on Chromatography London, September, 1982 相似文献
49.
50.
E. I. Zhilyaeva S. A. Torunova R. N. Lyubovskaya R. B. Lyubovskii 《Russian Chemical Bulletin》1996,45(5):1107-1110
Radical cation salts with halide mercurate anions were obtained by the electrochemical oxidation of bis(ethylenedioxo)tetrathiafulvalene (BEDO-TTF), and their conductivity was studied. The compounds (BEDO-TTF)4Hg3X8 (X = Cl or Br), (BEDO-TTF)4Hg3.5I9, and (BEDO-TTF)2HgBr3 possess the conductivity of the metallic type down to helium temperatures.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1167–1170, May, 1996. 相似文献